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排序方式: 共有134条查询结果,搜索用时 15 毫秒
1.
Ozkan Bayram 《Ceramics International》2018,44(17):20635-20640
In this study, synthesis and characterization of plasma polymerized Thiophene/ Nickel doped Zinc Oxide (PTNZO) bilayer nanocomposite films were carried out. Nickel doped zinc oxide (NZO) thin films were obtained by magnetron sputtering technique on glass substrates at 40 W Radio Frequency (RF) power. Plasma polymerized Thiophene (PT) thin films were deposited on the NZO thin films obtained on the glass substrate by Radio Frequency (RF) plasma polymerisation technique. X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), FTIR and Photoluminescence (PL) analyzes were performed for the characterization of PTNZO hetero bilayer nanocomposite films. In the XRD spectra of PTNZO bilayer nanocomposite thin films, (002) planes were determined as the most basic peak, and it was determined that the intensity of this peak, changed depending on the RF power of polymer thin films. Optical properties of nanocomposite thin films such as transmittance, absorbance and optical band gap were determined by UV–Vis spectroscopy. Optical band gap for PTNZO nanocomposites were 2.72?eV, 2.34?eV, and 2.45?eV, respectively, with increasing RF power. For NZO thin films, this value is 3.12?eV. The optical band gaps calculated from the absorption and transmittance spectra obtained using UV–visible spectroscopy had a good compatibility with those of the optical band spectra calculated from the PL spectra. The tetragonal wurtzite structure of the NZO thin films was examined by SEM analysis. The grain size of NZO nanostructure was found to be approximately 59?nm. 相似文献
2.
Recently, new researches on van der Waals (vdW) two-dimensional bilayer heterostructures have been carried out owing to their unique properties different from single-layer materials. Herein, three types of bilayer heterostructures, phosphorene/graphene, phosphorene/silicene and phosphorene/germanene are constructed and their electronic transport properties are calculated based on the first-principle method. The results show that their I-V curves are totally different that the phosphorene/graphene devices have higher electron transmission probability, resulting in higher current values. Furthermore, we calculate their band structures to explore the internal mechanism of current difference. The graphene-like Dirac cones are found in the bilayer phosphorene/graphene heterostructures. However, the positions of their Dirac cones in the Brillouin zone are markedly different from that of graphene. But when the silicene or germanene is combined with the phosphorene together, the Dirac cones of the silicene or germanene disappear, instead, there are band gaps of about 0.2?eV around the Fermi level. Our results suggest that the Dirac cone can be mainly retained by the weak hybridization between monolayer phosphorus and 2D Dirac materials. Due to the existence of the Dirac cone, the overlap between the source and drain electrodes increases, which leads to a larger current value. This discovery of the Dirac cones in the bilayer heterostructures is applicable in designing Dirac materials and understanding their electronic transport properties. 相似文献
3.
Yongli Jiang Chenjun Zhuang Yanyun Zhao Yun Deng Haiyan Gao 《International Journal of Food Properties》2018,21(1):867-877
The composite bilayer film based on polyvinyl alcohol, sodium alginate, and chitosan were developed in this study, and the effects of the related coating on internal-quality changes of salted duck eggs (SDEs) during storage were determined. The results showed that the overall properties of the bilayer film were better than those of monolayer films, including storage stability. Coatings could significantly (p < 0.05) reduce quality deterioration of SDEs such as water loss, oil exudation, and gritty. The bilayer coating was more effective in inhibiting the increase of egg yolk pH and total bacterial counts than monolayer coatings. After storage for 60 days, water content of bilayer coated SEDs was 19.7% higher than that of the control SDEs, oil exudation was 38% higher, and gritty texture was 27.9% higher. Moreover, bilayer coating could prolong the shelf life of SDEs to more than 60 days at 25°C and 50% relative humidity according to the results of total bacterial count experiment, while the shelf life of control SDEs was less than 45 days. This study indicated the potential application of bilayer composite coating for preservation of SDEs. 相似文献
4.
Both charge recombination and degradation in sequential solution processed polymer/fullerene bilayer organic photovoltaics (OPV) are effectively reduced by the insertion of a TiO2 inter-layer between the bilayer and Al electrode. The polymer/fullerene bilayer composed of a poly(3-hexylthiophene) (P3HT) bottom-layer and a [6,6] phenyl C61-butyric acid methyl ester (PCBM) top-layer shows significant change in morphology due to the substantial inter-penetration of P3HT and PCBM during the thermal annealing process. Consequently, the bilayer surface becomes P3HT rich resulting in significant charge recombination at the bilayer/Al interface of the bilayer OPV. The charge recombination rate of the bilayer OPV is reduced by one order of magnitude upon the insertion of a TiO2 nanoparticle inter-layer between the bilayer and the Al electrode after the thermal annealing process. In contrast, when the thermal annealing process is conducted after insertion of the inter-layer, the effect of the TiO2 inter-layer becomes insignificant. The VOC and efficiency of the bilayer OPV is greatly enhanced from 0.37 to 0.66 V and 1.2% to 3.7%, respectively by utilizing the properly constructed TiO2 inter-layer in the bilayer OPV. Additionally, insertion of the TiO2 inter-layer significantly improves the stability of the bilayer OPV. The bilayer OPV with a TiO2 inter-layer maintains 51% of its initial PCE after storage under dark ambient conditions for 700 h without encapsulation, whereas the bilayer OPV without a TiO2 inter-layer did not show any solar cell performance after 200 h under the same conditions. 相似文献
5.
In this paper, a bilayer hole extraction layer (HEL) with solution-processed molybdenum trioxide (MoO3) and two-dimensional (2D) material of antimonene was developed to achieve high performance nonfullerene organic solar cells (NF–OSCs). The application of antimonene facilitates effective charge extraction and lowered recombination loss, achieving improved photovoltaic performance. By inserting the antimonene layer, power conversion efficiency (PCE) of devices with MoO3 HEL was increased from 8.92% to 11.30% in OSCs with non-fullerene systems of PBDB-T-2F:IT-4F, which was even much higher than that of the devices with PEDOT:PSS HEL (10.59%). Results make it clear that the solution-processed bilayer MoO3/antimonene HEL shows great potential for application in high performance PEDOT:PSS-free NF–OSCs. 相似文献
6.
We address the optical conductivity of doped AA-stacked bilayer graphene in the presence of a finite bias voltage at finite temperature. The effect of scattering by dilute charged impurities is discussed in terms of the self-consistent Born approximation. Green's function approach has been implemented to find the behavior of optical conductivity of bilayer graphene within linear response theory. We have found the frequency dependence of optical conductivity for different values of concentration and scattering strength of dopant impurity. Also the dependence of optical conductivity on the impurity concentration and bias voltage has been investigated in details. A peak appears in the plot of optical conductivity versus impurity concentration for different values of chemical potential. Furthermore we find optical conductivity reduces with frequency for any impurity concentration and scattering strength. 相似文献
7.
Gaofeng Zhao Yue Li Chunsheng Liu Yinliang Wang Jianmin Sun Yuzong Gu Yuanxu Wang Zhi Zeng 《International Journal of Hydrogen Energy》2012
By using first-principles methods, we perform a theoretical investigation of adsorption of hydrogen molecules between bilayer solid matrix layers (bilayer boron nitride sheets (BBN) and graphene/boron nitride heterobilayers (GBN)) with variable interlayer distance (ILD). We find that the H2 adsorption energy has a minimum by expanding the interlayer spacing, along with further interlayer expansion, arising from many H2 binding states and electrostatic interaction induced by the polar nature of B–N bonds. To determine if successive addition of H2 molecules is indeed possible using the minimal H2 adsorption energy as the reference state, we then simulate the hydrogen storage capacity of BBN and GBN with different stacking types, and find that the GBN with Bernal stacking is superior for reversible hydrogen storage. Up to eight H2 molecules can be adsorbed with the average adsorption energy of −0.20 eV/H2, corresponding to ∼7.69 wt % hydrogen uptake. 相似文献
8.
Sangmoo Choi Canek Fuentes-HernandezMinseong Yun Amir DindarTalha M. Khan Cheng-Yin WangBernard Kippelen 《Organic Electronics》2014,15(12):3780-3786
We report on a reverse stamping method to produce via-holes in circuits comprising acene-based top-gate organic field-effect transistors (OFETs) having a CYTOP/Al2O3 (by atomic layer deposition) bilayer gate dielectric. This method relies on the weak adhesive force that exists between a small molecule acene film and a polymer to enable easy delamination of the bilayer gate dielectric by using a PDMS stamp. We demonstrate the effectiveness of this method by fabricating simple circuits using top-gate triisopropylsilylethynyl pentacene (TIPS-pentacene)/poly (triarylamine) (PTAA) OFETs. 相似文献
9.
《Digital Communications & Networks》2017,3(3):176-179
Bilayer low-density parity-check (LDPC) codes are an effective coding technique for decode-and-forward relaying, where the relay forwards extra parity bits to help the destination to decode the source bits correctly. In the existing bilayer coding scheme, these parity bits are protected by an error correcting code and assumed reliably available at the receiver. We propose an uncoded relaying scheme, where the extra parity bits are forwarded to the destination without any protection. Through density evolution analysis and simulation results, we show that our proposed scheme achieves better performance in terms of bit erasure probability than the existing relaying scheme. In addition, our proposed scheme results in lower complexity at the relay. 相似文献
10.
H. Fritzsche W.P. Kalisvaart B. Zahiri R. Flacau D. Mitlin 《International Journal of Hydrogen Energy》2012
We examined the deuterium absorption and desorption of 55 nm thick Mg films alloyed with Fe and Cr using in-situ neutron reflectometry. The Mg alloy films were covered with bimetallic catalyst layers and could be fully absorbed at room temperature at a pressure of 8 mbar. The NR experiments revealed a deuterium gradient within the Mg alloy layers during absorption and a large deuterium uptake up to a D/M ratio of about 0.45 before the layer started to expand and form magnesium deuteride (MgD2). Our NR data suggest that the catalytic effect of the Fe–Cr alloy is based on the avoidance of the formation of a blocking MgD2 layer in the early stages of the absorption process leading to a fast hydrogen absorption kinetics. 相似文献