Kinetics of two-step anionic polymerization

This article deals with the kinetics of two-step anionic polymerization by way of a non-steady state method. Several molecular parameters can be evaluated using the formulae developed. A bimodal molecular weight distribution function for the resulting polymer is derived from the set of kinetic differential equations, which is in agreement with the experimental data reported.     

Practical method for generation expansion planning based on dynamic programming

This paper presents an efficient method which provides the optimal generation mix and the optimal generation construction process. The approximation method in which the dynamic programming technique and gradient method are combined is applied to determine the optimal generation mix with hydropower generation technologies. The successive approximations dynamic programming (SADP) technique, which is very suitable for high-dimensional multistage decision process problems, is used for obtaining the optimal generation construction process. The effectiveness and feasibility of the developed technique are demonstrated on a practical power system model which has five types of generation technologies including a hydropower generation technology.     

Cationic ring-opening polymerization of hexamethylcyclodisilazane: General aspects and tentative mechanisms

The ring-opening polymerization of hexamethylcyclodisilazane (D_2NMe), initiated by methyl triflate in 1,2-dichloroethane, forms in the first, fast kinetic step both linear polymer and cyclic dimer (D_4NMe). Subsequently a slow depolymerization process occurs leading to exclusively cyclotrisilazane (D_3NMe). On the basis of kinetic measurements carried out using an adiabatic calorimetric technique and complementary experiments, mechanisms of both propagation, cyclization and back-biting reactions are proposed. The influence of the reaction temperature was also studied; it is demonstrated that, at low temperature, polymerization does not lead to cyclic oligomer formation. In such conditions, the polymerization presents a ‘living’ character.     

Modelling diffusion-controlled kinetics in equilibrium and driven alloys

Summary We introduce a very simple model for thermally activated atomic migration on a lattice, and several techniques to handle it. For thermodynamical systems, the model can be used for simulating decomposition paths taking into account relevant metallurgical features. Close to equilibrium, the simplest mean-field approximation of the model can be linearized with respect to the departure from equilibrium; one then gets a microscopic interpretation of classical phenomenological coefficients, such as mobility, interfacial transfer coefficient, rate constants for the coupled relaxation of concentration and order fields. Further away from the equilibrium, the nonlinearities can be taken into account in a consistent way. For driven alloys, i.e. alloys submitted to external forcing, forced atomic migration is added to the model and new features emerge: the model is supported by several experimental results some of which confirmed its predictions a posteriori.     

Damage and deterioration mechanism and curing technique of concrete structure in main coal cleaning plants

Concrete structures in main coal cleaning plants have been rebuilt and reinforced in the coal mines of the Shanghai Da-tun Energy Sources Co. Ltd., the first colliery of the Pingdingshan Coal Co. Ltd. and the Sanhejian mine of the Xuzhou Mining Group Co. Ltd. In these projects, the operating environment and reliability of concrete structures in the main plants of the three companies were investigated and the safety of the structures inspected. Qualitative and quantitative analyses were made on the spe-cial natural, technological and mechanical environments around the structures. On the basis of these analyses, we discuss the long-term, combined actions of the harsh natural (corrosive gases, liquids and solids) and mechanical environments on concrete structures and further investigated the damage and deteriorating mechanisms and curing techniques of concrete structures in the main coal cleaning plants. Our study can provide a theoretical basis for ensuring the reliability of concrete structures in main coal cleaning plants.     

国内外聚乙烯醇工业的进展及市场展望

简述了国内外聚乙烯醇工业情况，介绍了聚乙烯醇及其衍生物的应用领域，展望了聚乙烯醇的发展形势和市场状况。     

巧用Vlookup函数完成信息核对--在招生工作中学生信息核对的应用

Excel软件功能强大,操作简便,其提供的函数可用于处理和分析复杂的数据。介绍了Excel中查找函数Vlookup的语法格式及功能,并通过工作中的具体实例来阐述利用Vlookup函数解决核对数据匹配问题,提高了工作效率,节省了大量的人力。     

浅谈计算机信息技术在图书馆中的应用

在社会日益发展的今天,传统的图书馆服务模式已经无法适用新形势的发展要求,数字化、网络化等计算机信息技术的出现并应用,促使图书馆从传统功能模式向开放式、网络式的信息服务模式转变,由单一功能向多功能转变,从根本上推动了图书馆事业的发展。     

A computer-enabled solution procedure for food wholesalers’ distribution decision in cities with a circular transportation infrastructure

This paper addresses the food distribution decision from a wholesaler's perspective, as the wholesalers are often faced with thorny issues such as when, where, how to deliver products at the lowest costs to best satisfy the retailers’ changing needs. This research relies on a distribution problem encountered at Northern Grocery Company in Beijing as an example to develop a two-stage solution procedure and subsequent computer-enabled programs for identifying efficient vehicle routing alternatives. The solution process, which integrates heuristic search algorithms and an integer programming model, can be applied to a wide range of distribution problems with specified route durations and a circular transportation network structure as exemplified by City of Beijing.     

LIGA技术及其在制造可动微结构件中的应用

介绍了将LIGA技术及其与牺牲层技术相结合 ,制造可动微结构的工艺方法。并给出了可实现摆动、转动的可动微结构———微执行器、微传感器和三维加速度传感器的制造过程等应用实例