Assessment via the modified gompertz-model reveals new insights concerning the effects of ionic liquids on biohydrogen production

Lignocellulosic biofuel, in particular hydrogen gas production is governed by successful feedstock pretreatment, hydrolysis and fermentation. In these days, remarkable attention is paid to the use of ionic liquids to make the fermentable regions of lignocellulose biomass more accessible to the biocatalysts. Although these compounds have great potential for this purpose, their presence during the consecutive fermentation stage may pose a threat on process stability due to certain toxic effects. This, however, has not been specifically elaborated for dark fermentative biohydrogen generation. Hence, in this work, two common imidazolium-type ionic liquids (1-butyl-3-methylimidazolium acetate, ([bmim][Ac]) and 1-butyl-3-methylimidazolium chloride, ([bmim][Cl])) were employed in mixed culture biohydrogen fermentation to investigate the possible impacts related to their presence and concentrations. The batch assays were evaluated comparatively via the modified Gompertz-model based on the important parameters characterizing the process, namely the biohydrogen production potential, maximum biohydrogen production rate and lag-phase time.     

Thermal conductivity of natural rubber nanocomposites with hybrid fillers

Natural rubber nanocomposites filled with hybrid fillers of multi-walled carbon nanotubes(CNTs) and carbon black(CB) were prepared. CNTs were ultrasonically modified in mixture of hydrogen peroxide(H_2O_2) and distilled water(H_2O). The functional groups on the surface of CNTs, changes in nanotube structure and morphology were characterized by Fourier transform infrared spectroscopy(FT-IR), Raman Spectroscopy, and transmission electron microscopy(TEM). It shows that hydroxyl(OH·) is successfully introduced. The surface defects of modified CNTs were obviously higher than those of original CNTs, and the degree of agglomeration was greatly reduced. Thermal conductivity of the composites was tested by protection heat flow meter method. Compared with unmodified CNTs/CB filling system, the thermal conductivity of hybrid composites is improved by an average of 5.8% with 1.5 phr(phr is parts per hundred rubber) of hydroxyl CNTs and 40 phr of CB filled. A three-dimensional heat conduction network composed of hydroxyl CNTs and CB, as observed by TEM, contributes to the good properties. Thermal conductivity of the hybrid composites increases as temperature rises. The mechanical properties of hybrid composites are also good with hydroxyl CNTs filled nanocomposites; the tensile strength, 100% and 300% tensile stress are improved by 10.1%, 22.4% and 26.2% respectively.     

Removal of lead(Pb(Ⅱ))and zinc(Zn(Ⅱ))from aqueous solution using coal fly ash(CFA)as a dual-sites adsorbent

Coal fly ash(CFA)is composed of minerals containing some oxides in crystalline phase(i.e.,quartz and mullite),as well as unburned carbon as mesoporous material,thus enabling CFA to act as a dual-sites adsorbent with unique properties.This work focused on the adsorption of Pb(Ⅱ)and Zn(Ⅱ)from binary system,a mixture containing two metal ion solutions present simultaneously,onto NaOH-modified CFA(MCFA).Several adsorption tests were conducted to evaluate the effect of several parameters,includ-ing pH and contact times.The experiment results indicated that chemical treatment of CFA with NaOH increased pore volume from 0.021 to 0.223 cm3 g-1.In addition,it could also enhance the availability of functional groups on both minerals and unburned carbon,resulting in almost 100％Pb(Ⅱ)and 97％Zn(Ⅱ)adsorbed.The optimum pH for adsorption system was pH=3 and quasi-equilibrium occurred in 240 minutes.Equilibrium data from the experimental results were analyzed using Modified Extended Langmuir(MEL)and Competitive Adsorption Langmuir-Langmuir(CALL)isotherm models.The analysis results showed that the CALL isotherm model could better describe the Pb(Ⅱ)and Zn(Ⅱ)adsorption pro-cess onto MCFA in binary system compared with MEL isotherm model.     

Attitude control of spacecraft simulator without angular velocity measurement

In this paper the attitude control of a spacecraft simulator using Reaction Wheels (RW) as the actuators is investigated. The main goal of the current study is to bring the RWs to the rest at the end of the maneuver without angular velocity measurement. A modified feedback linearization controller is applied by considering the Euler angles of the simulator as the output and the RWs angular momentums as the internal state variables. The stability of the proposed controller and the internal dynamics is analyzed using Lyapunov theory. Two modified sliding mode observers are designed to estimate the angular velocities of the spacecraft attitude control subsystem simulator. The proposed observers do not use the control input and the detailed knowledge of the model and thus it can be implemented easily. The global stability of the system is proved. The proposed controller and observers are finally evaluated numerically and experimentally on an attitude spacecraft simulator.     

Enhancing optical absorption in visible light of ZnO co-doped with europium and promethium by first-principles study through modified Becke and Johnson potential scheme

By using first-principles calculations we studied the electronic, optical and magnetic properties of ZnO co-doped with Eu and Pm. In this calculation, we used Wien2k code based on full potential linearized augmented plane waves (FP-LAPW) method with the modified Becke-Johnson (mBJ) approximation. This correction gives good band gap compared to experimental band gap. The introduction of Eu and Pm codoping leads to an increase in the band gap. Electrons can transit easily from the valence band to the conduction band, which results in an enhancement of visible light absorption in a wider absorption range. Absorption spectra reach a high value in visible and infrared light regions. With the significance of the obtained results, the studied compounds may potentially find spintronic and optoelectronic applications.     

用修正淬透性系数法对反应堆压力容器锻件RTNDT数值的预估

分析反应堆压力容器（RPV）锻件制造过程中关键化学元素含量及基准无塑性转变温度（RTNDT）数值，通过引入修正淬透性系数，建立了反映RTNDT变化规律的修正淬透性系数函数表达式，并给出了实例验证，结果表明，通过本文建立的修正淬透性系数函数式可以比较精确地预估RPV锻件的RTNDT值。      

生物质石墨烯改性黏胶长丝制备与性能研究

采用湿法纺丝技术将生物质石墨烯浆料与黏胶原液共混纺丝,制备生物质石墨烯改性黏胶长丝,并对其横截面形态、红外光谱、力学性能、抗菌性能、远红外性能进行测试。结果表明,当石墨烯添加量为2.5%时,纤维的干、湿断裂强度分别为1.85、0.90 cN/dtex,干断裂伸长率为22.33%,达到国家标准一等品要求;纤维对大肠杆菌、白色念珠菌和金黄色葡萄球菌的抑菌率均大于99%,远红外辐射升温值为3.2℃,远红外发射率为0.89。生物质石墨烯改性黏胶长丝光滑舒适、柔软亲肤、绿色可降解,是纺织面料的优选原料。     

A directional control method for interface flow considering static voltage stability

A directional control method (DCM) for power flows on a set of interface lines between two regions of power system considering static voltage stability margin is developed in this paper. A surface approximation approach is firstly used to obtain the relationship between the interface flow solution and the generation direction of generator (the portion of generation variation in each participating generator to satisfy the desired power increase on the interface and the system loss). Then, an optimization model is built to determine the optimum dispatching scheme of generators. This method not only can control the total power on the interface to satisfy the power demand but also can realize the directional control of power on each interface line based on the needs of operation. The proposed DCM is further extended to determine the optimum dispatching scheme of generators for maximizing the interface flow margin (IFM), which is the active power margin of the key transmission lines between two regions of power system constrained by static voltage stability. A modified continuation power flow (MCPF) is used to show and evaluate the impacts of the DCM on the IFM. The New England 39-bus system and the IEEE 300-bus system have been employed to verify the effectiveness of the DCM.