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1.
In this study, Ca/Tb co-doped HfO2 coatings were prepared by atmosphere plasma spraying. The chemical composition, morphology and infrared property of the coatings were characterized. The coatings possessed a layer-stacked morphology. When the Ca/Tb doping atomic ratio was 1:1, the phase of the coatings gradually changed from monoclinic to cubic with increasing the doping mass. The CTH2 coating had the highest emissivity which was 0.820 in 0.75–6.5 µm and 0.902 in 6.5–15 µm respectively. The enhancement in short band was mainly due to the introduction of Ca2+ and Tb3+ ions that generated oxygen vacancies in the lattice forming impurity levels within the forbidden band, moreover, the transfer of Tb3+ to Tb4+ increased the concentration of free electrons, which promoted the absorption of free carriers. The increase in long band attributed to the lattice distortion that reduced the lattice symmetry and strengthened the absorption of lattice polar vibration.  相似文献   
2.
《Ceramics International》2022,48(5):6372-6384
Sm2O3-HfO2 series ceramics were synthesized at high temperature using the solid-state reaction. The phase stability, thermo-physical and infrared emission properties of Sm2Hf2O7 (SHO) and Sm2Hf2O7-44.83 wt%HfO2 (25S/H) composite ceramics were comparatively investigated. Furthermore, their calcium magnesium aluminosilicate (CMAS) corrosion was conducted at 1250°C for different times. The results reveal that both SHO and 25S/H ceramics have excellent phase stability at 1600°C as well as excellent sintering resistance. SHO still exhibits slightly lower thermal conductivity and lower hardness and Young's modulus, higher thermal expansion coefficient (CTE) and fracture toughness as well as higher infrared emittance (0.899 at 800°C) than 25S/H composite with the excessive HfO2 inside. Both SHO and 25S/H ceramics react with CMAS to form a relatively compact reaction layer, which can effectively prevent the penetration of CMAS. These results preliminarily indicate that SHO ceramic can be proposed as an alternative material of the traditional YSZ for high-temperature thermal protective applications thanks to its compatible performance of low thermal conductivity and high infrared radiation, etc.  相似文献   
3.
华龙一号反应堆探测器组件拆除过程中,首先需对待拆除探测器组件进行定位。本文首先提出探测器组件拆除过程中的定位要求,然后结合探测器组件拆除工艺对定位系统进行分析,提出全闭环视觉伺服定位方法,该方法定位精度高,满足拆除装置定位精度要求;同时可保证探测器组件在提升过程中偏斜角度较小,减少对机械密封接头的磨损。   相似文献   
4.
《Ceramics International》2022,48(4):4658-4664
Two garnet-structured Ca3MgBGe3O12 (B = Zr, Sn) ceramics with tetravalent cations at B-site were prepared by conventional solid state reaction. The crystal structure, microstructure evolution, and microwave dielectric performance were investigated using X-ray powder diffraction, Rietveld refinement, scanning electron microscopy, Raman spectroscopy, and infrared spectroscopy techniques. Dense Ca3MgZrGe3O12 and Ca3MgSnGe3O12 ceramics were obtained at sintering temperatures of 1420 and 1400 °C, respectively. The dielectric constant, unloaded quality factor, and temperature coefficient of resonance frequency of Ca3MgZrGe3O12 were 10.80 ± 0.2; 79,600 ± 1000 GHz (f = 12.61 GHz); and ?66.8 ± 1 ppm/°C, respectively, and the corresponding values for Ca3MgSnGe3O12 were 9.68 ± 0.2; 83,400 ± 1000 GHz (f = 14.19 GHz); and ?57.9 ± 1 ppm/°C, respectively. The dielectric performances of the two ceramics were compared by analyzing the ionic polarizability, packing fraction, and bond valence. The intrinsic dielectric properties were predicted by fitting the infrared reflectivity spectra.  相似文献   
5.
以带正电的碳酸钙纳米颗粒和阳-非离子双子表面活性剂为原料,制备了一种纳米活性流体。通过Zeta电位、红外光谱(IR)、石英晶体微天平(QCM)、接触角测量和自发渗吸实验等方法研究了制得纳米活性流体中碳酸钙纳米颗粒和阳-非离子双子表面活性剂协同改变油湿性砂岩表面润湿性的机理。结果表明,纳米活性流体处理后的油湿性砂岩表面红外光谱中,原油的羰基吸收峰强度低于阳-非离子双子表面活性剂处理后的砂岩表面羰基吸收峰强度;当阳-非离子双子表活剂质量分数均较高时(>0.003%),纳米活性流体中的碳酸钙颗粒促进了双子表面活性剂和原油羧基离子对的形成和解吸附过程,使得纳米活性流体处理过的砂岩表面共振频率变化量(Δf)比阳-非离子双子表面活性剂处理过的砂岩表面Δf小;接触角测定结果进一步确认,纳米活性流体改变油湿性砂岩表面润湿性的效果比单一阳-非离子双子表面活性剂和碳酸钙纳米颗粒效果更好,纳米活性流体中的两种组分起到协同效应。  相似文献   
6.
Core–rim structures were observed as common features in Y-α-SiAlON ceramics hot-pressed between 1550?1950 °C. We found most dopants were taken into α’-rims, and a transition layer grown first on α-cores from liquid-phase over-saturated with metal solutes. Elongated β’-grain were formed as minor phase with α’- or AlN-cores thus only after the α’ matrix had consumed up all Y solutes, revealing that the α’ → β’ transformation is controlled by the transient liquid-phase and similar defects and dangling bonds could be detected in both SiAlON phases by cathodoluminescence. Quantitative assessment of Ym/3Si12?(m+n)Alm+nOnN16?n demonstrates the multiphase evolution, initiated by over-saturation of Y solutes at low temperatures thus retaining α-phase as cores to lower the infra-red transmittance, dictated by homogenization of Al solutes at higher temperature. The elimination of those phase boundaries leads to better dopant and sintering design for achieving transparent and high-performance SiAlON ceramics.  相似文献   
7.
介绍涤纶长丝面料分散染料热转移印花工艺,包括工艺流程、主要技术创新、产品应用等方面。阐述涤纶长丝面料阻燃涂层整理技术,并讨论阻燃剂用量、涂层增重量对整理效果的影响。总结防热红外侦察整理、防雷达波侦察整理、多功能迷彩面料生产及要点。文章表明,化纤长丝纺织产品的发展与国防建设是密切相关、相互促进、相辅相成的。以化纤长丝为基材生产的系列化军用产品是建设强大国防的重要保障。不断深化化纤长丝面料的功能性深度加工具有非常重要的意义。  相似文献   
8.
遥感信息定量化要求高精度的光谱辐射定标技术支撑,使传感器获取数据可比较性、测量精度和长期稳定性得到保证,溯源于低温绝对辐射计的定标技术是发展趋势.为提高红外绝对光谱响应率定标精度,在一种薄膜热电堆传感器上加装镀金反射半球,研制了红外陷阱探测器作为标准传递探测器.利用电替代技术,测试了红外陷阱探测器光谱响应线性、空间响应均匀性和稳定性.通过溯源于低温绝对辐射计的光谱辐射定标系统,标定了其在1. 1~3. 0μm短波红外波段的绝对光谱响应率,合成不确定度小于1%.将红外陷阱探测器应用于红外光谱辐射定标,可缩短低温绝对辐射计的红外光谱功率标准传递链路并提高定标精度.  相似文献   
9.
针对航空发动机压气机叶片复杂载荷环境下的超高周疲劳问题,开展了TC4钛合金三点弯曲超高周疲劳试验,研究其在弯曲加载下的超高周疲劳破坏行为。疲劳试验结果表明:在两种应力比(R=0.3、0.5)下,当循环次数超过107次时,试件仍发生疲劳断裂,S-N曲线均呈现双线性特征;SEM断口分析表明,随着最大应力的降低,裂纹萌生位置由试件表面向次表面转移,疲劳裂纹萌生是表面滑移和内部解理断裂之间相互竞争的结果;基于疲劳寿命建立模型分析了应力比对2种裂纹萌生机制之间竞争行为的影响。采用红外热像仪监测试件表面的温度,高周疲劳试件的温度变化分为四个阶段:稳定升高、稳定降低、快速升高和快速降低阶段,而超高周疲劳试件的温度变化分为三个阶段:稳定升高、快速升高和降低阶段。最后,阐述了疲劳过程中热产生和传热的特点,并分析了温度变化与应力分布的关系。  相似文献   
10.
《Ceramics International》2019,45(11):14312-14315
In this work, an Al powder was coated with antimony-doped tin oxide (ATO) to obtain an infrared-laser compatible stealth material. The composites are prepared via a coprecipitation method, characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), and measured by ultraviolet spectrophotometer and dual band infrared emissometer. The morphology and microstructure show that the flaky Al powder was coated by the ATO nanoparticles and doped into the SnO2 rutile structure by an Sb5+ ion. The optimal Al content was 20%, and the optimized Sn/Sb molar ratio was 10: 1. Meanwhile, the reflectivity of the composites was 43.454%, and the infrared emissivity in 8–14 μm far infrared waveband range was 0.708. It may shed light on a new material design orientation to obtain high performance laser-infrared compatible stealth materials.  相似文献   
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