Using ion implantation to adjust the transition temperature of superconducting films

We summarize a continuing investigation into using ion implantation to alter the transition temperature of superconducting thin films. The primary motivation for the work presented here was to study the feasibility of using magnetic ion doping to replace the bi-layer T_c control process currently used for certain cryogenic detector applications at National Institute for Standards and Technology. The results from work with various ion species implanted into aluminum, molybdenum, titanium and tungsten host films are presented.     

Residual stresses and transformation toughening in MoSi2 composites reinforced with partially stabilized zirconia

The results of study of the effects of yttria stabilization (0–6 mol.%) on the room-temperature fracture behavior and toughening mechanisms in zirconia-reinforced MoSi₂ are presented in this paper. Transformation toughening is shown to occur only in composites reinforced with zirconia particles stabilized with 2 mol.% yttria. However, the fracture toughness levels are comparable in the other composites with yttria levels between 0 and 6 mol.%. Toughening in the other composites is attributed to the combined effects of residual stress, microcrack shielding/anti-shielding and/or crack deflection. A rigorous micromechanics-based model is presented for the estimation of residual stress levels in brittle materials reinforced with phases that can transform during cooling or under stress. The model is applied successfully to the rationalization of the observed fracture and toughening phenomena.     

钼酸盐阻燃抑烟剂研发现状

简要地叙述了钼酸盐类阻燃抑烟剂 ,如八钼酸铵、钼酸锌、钼酸钙、钼酸钴和三氧化钼等阻燃抑烟剂的研发现状     

Ф16mm、Ф18mm钼棒的研制

采用等静压制法，压制钼圆棒坯，经中频高温烧结，制得尺寸适合、用户满意的钼电极棒。     

硝酸溶液中钼和锆溶解度的测定

一、前言在核裂变过程中,钼和锆是高产额的裂变产物元素,所以在乏燃料中钼和锆的含量较高。核燃料水法后处理工艺的常用介质是硝酸,因此测定硝酸溶液中钼和锆的溶解度是有意义的。对于裂变产物的过程化学的研究工作,溶解度数据也是必要的。关于硝酸溶液中钼和锆的溶解度,前人研究得很少,数据也不全。为此,我们测定了不同浓度的硝酸中不同温度下钼和锆溶解度;还观测了硝酸根和铀浓度对钼和锆的溶解度的影响;获取的数据较全面。     

Kinetic study of the deep hydrodesulfurization of dibenzothiophene over molybdenum carbide supported on a carbon black composite: Existence of two types of active sites

Hydrodesulfurization (HDS) is part of the hydrotreating process, which is an ensemble of several reactions (HDN, HDO, HDS, etc.) taking place simultaneously at the industrial scale. Only sulfur is currently submitted to drastic Europeans specifications and conventional commercial catalysts cannot reach the specifications at low cost. This paper presents the behavior of a potential substitute catalyst tested for the deep HDS of a model molecule such as the dibenzothiophene (DBT). The substitute is molybdenum carbide supported on a mesoporous carbon black composite of surface area 240 m² g⁻¹. A global kinetic study of the deep HDS of DBT (300 ppm S) was performed at 623 K and 5.0 MPa and a global kinetic model was proposed as well as global rate constants were calculated to obtain theoretical plots of concentration versus contact time to compare with the experimental data. The kinetic model and global kinetic orders were confirmed as an acceptable correlation was found between calculated and experimental data. Furthermore, the determination of the global kinetic orders indicated that two types of active sites must be present on the surface in order to explain the observed results.     

二硅化钼用于钼基的耐热涂层

介绍ＭｏＳｉＯ２用于钼基的耐热涂层，进行涂层的动力、金相学和添加剂的分析。     

整体成型钼园舟研究

本研究采用特殊的方法制取钼园舟，研究结果表明，获得了满意的结果。     

钼的高灵敏显色反应及其应用

本文提出了钼的高灵敏显色反应[Mo（Ⅵ）－SCN－Morin－BPR－Twwen80体系]和在测定微量钼的应用。研究了Mo（Ⅵ）、SCN、桑色素（Morin）、溴邻苯三酚红（BPR）和吐温80（Tween80）显色配位体系的特性，该体系的最大吸收峰为565nm，最佳酸度为0．10～0．35mol／LH2SO4介质中，摩尔吸光系数ε＝3．5×106L·mol(-1)·cm(-1)，在565nm波长处空白值最低。配合物的组成比为Mo（Ⅵ）：SCN：Morin－BPR－1：6：3（在Tween80存在下）。0～2．50μgMo(6 )／50mL范围内，服从郎伯－比尔定律。回收率为98％～102％。应用此法测定土壤和头发中微量钼，获得满意的结果。