全文获取类型
收费全文 | 518261篇 |
免费 | 55807篇 |
国内免费 | 38995篇 |
专业分类
电工技术 | 45059篇 |
技术理论 | 27篇 |
综合类 | 44584篇 |
化学工业 | 77827篇 |
金属工艺 | 22431篇 |
机械仪表 | 35561篇 |
建筑科学 | 38179篇 |
矿业工程 | 13733篇 |
能源动力 | 18665篇 |
轻工业 | 39065篇 |
水利工程 | 13720篇 |
石油天然气 | 22595篇 |
武器工业 | 5755篇 |
无线电 | 56154篇 |
一般工业技术 | 51646篇 |
冶金工业 | 16891篇 |
原子能技术 | 7231篇 |
自动化技术 | 103940篇 |
出版年
2024年 | 517篇 |
2023年 | 7541篇 |
2022年 | 13335篇 |
2021年 | 17607篇 |
2020年 | 16868篇 |
2019年 | 14350篇 |
2018年 | 13558篇 |
2017年 | 16706篇 |
2016年 | 18753篇 |
2015年 | 21496篇 |
2014年 | 29195篇 |
2013年 | 32766篇 |
2012年 | 37758篇 |
2011年 | 41583篇 |
2010年 | 30962篇 |
2009年 | 32115篇 |
2008年 | 32279篇 |
2007年 | 37939篇 |
2006年 | 35224篇 |
2005年 | 29761篇 |
2004年 | 24532篇 |
2003年 | 20877篇 |
2002年 | 16149篇 |
2001年 | 12532篇 |
2000年 | 10134篇 |
1999年 | 8297篇 |
1998年 | 6486篇 |
1997年 | 5290篇 |
1996年 | 4672篇 |
1995年 | 4216篇 |
1994年 | 3666篇 |
1993年 | 2849篇 |
1992年 | 2402篇 |
1991年 | 1766篇 |
1990年 | 1479篇 |
1989年 | 1251篇 |
1988年 | 942篇 |
1987年 | 639篇 |
1986年 | 577篇 |
1985年 | 603篇 |
1984年 | 623篇 |
1983年 | 487篇 |
1982年 | 469篇 |
1981年 | 298篇 |
1980年 | 248篇 |
1979年 | 144篇 |
1978年 | 120篇 |
1977年 | 115篇 |
1976年 | 96篇 |
1962年 | 83篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
深凹露天矿山由于其特殊的结构,爆破产生的炮烟扩散稀释较为困难,严重危害生产作业人员的生命安全与健康。基于实际矿山构建了深凹露天矿山的二维物理及数学模型,采用非稳态数值分析方法研究了不同爆破位置下,深凹露天矿山采坑内爆破炮烟的扩散规律。研究结果表明:不同爆破位置下,露天采坑内均出现复环流,爆破点位置是影响露天采坑内风流结构特征的重要因素;露天采坑内的炮烟最高浓度均随着时间变化而逐渐下降,但下降的速率逐步减小,呈现三个阶段的下降趋势;爆破位置位于背风侧时露天采坑内的炮烟最高浓度和降至安全浓度所需时间远高于迎风侧三个爆破位置;随着背风侧爆破点距采坑底部距离的减小,炮烟最高浓度及降至安全浓度所需时间先降低后增加,炮烟最高浓度及降至安全浓度所需时间随着迎风侧爆破位置距采坑底部距离的减小而增加。研究结果对于指导深凹露天矿山企业合理组织爆破后的生产作业和保障作业人员安全具有重要意义。 相似文献
3.
《Advanced Powder Technology》2022,33(6):103595
Ceria (CeO2) particles are prevalent polishing abrasive materials. Trivalent lanthanide ions are the popular category of dopants for enriched surface defects and thus improved physicochemical properties, since they are highly compatible with CeO2 lattices. Herein, a series of dendritic-like mesoporous silica (D-mSiO2)-supported samarium (Sm)-doped CeO2 nanocrystals were synthesized via a facile chemical precipitation method. The relation of the structural characteristics and chemical mechanical polishing (CMP) performances were investigated to explore the effect of Sm-doping amounts on the D-mSiO2/SmxCe1?xO2?δ (x = 0–1) composite abrasives. The involved low-modulus D-mSiO2 cores aimed to eliminate surface scratch and damage, resulting from the optimized contact behavior between abrasives and surfaces. The trivalent cerium (Ce3+) and oxygen vacancy (VO) at CeO2 surfaces were expected to be reactive sites for the material removal process over SiO2 films. The optimal oxide-CMP performances in terms of removal efficiency and surface quality were achieved by the 40% Sm-doped composite abrasives. It might be attributed to the high Ce3+ and VO concentrations and the enhancement of tribochemical reactivity between CeO2SiO2 interfaces. Furthermore, the relationship between the surface chemistry, polishing performance as well as the actual role in oxide-CMP of the D-mSiO2/SmxCe1?xO2?δ abrasives were also discussed. 相似文献
4.
《Advanced Powder Technology》2022,33(9):103722
Through a facile hydrothermal method, we have successfully prepared Ti3C2/Bi2.15WO6 (TC/BWO) composite, and systematically investigated their reactivity for the photocatalytic reduction of Cr(VI) under visible light. X-ray diffraction and Raman analysis confirm the formation of heterostructure between Bi2.15WO6 and Ti3C2. The resultant 7TC/BWO composite exhibits enhanced photoactivity toward Cr(VI) reduction. After 120 min irradiation, the conversion of Cr(VI) reaches 92.5% with the quasi-first-order kinetic constant of k = 0.0145 min?1, which is higher than that of pure BWO (30% and k = 0.0005 min?1). The electrochemical and photoluminescent characterization confirm that the introduction of Ti3C2 is conducive to the separation of carriers, thus significantly improves the photocatalytic performance of TC/BWO. Furthermore, the radical capture experiments verify that the electrons are important for enhancing reduction of Cr(VI) to Cr(III). As a result, this research provides a comprehensive understanding of the reduction of Cr(VI) by TC/BWO composite under visible light. 相似文献
5.
6.
《International Journal of Hydrogen Energy》2022,47(85):36216-36231
The fuel cell/battery durability and hybrid system stability are major considerations for the power management of fuel cell hybrid electric bus (FCHEB) operating on complicated driving conditions. In this paper, a real time nonlinear adaptive control (NAC) with stability analyze is formulated for power management of FCHEB. Firstly, the mathematical model of hybrid power system is analyzed, which is established for control-oriented design. Furthermore, the NAC-based strategy with quadratic Lyapunov function is set up to guarantee the stability of closed-loop power system, and the power split between fuel cell and battery is controlled with the durability consideration. Finally, two real-time power management strategies, state machine control (SMC) and fuzzy logic control (FLC), are implemented to evaluate the performance of NAC-based strategy, and the simulation results suggest that the guaranteed stability of NAC-based strategy can efficiently prolong fuel cell/battery lifespan and provide better fuel consumption economy for FCHEB. 相似文献
7.
通过耦合零维等离子动力学求解器和燃烧动力学求解器,建立了交流放电等离子体助燃模型,研究了交流放电非平衡等离子体对C2H4/空气的助燃路径,并与自燃过程进行了对比。该模型使用电子能量分布函数计算电子碰撞反应速率,并得到贫燃条件下连续放电过程中温度、组分浓度、放热速率、关键组分的生成/消耗速率随时间的变化。研究表明,等离子体助燃增加了新的反应路径,生成了更多的自由基和激发态组分,缩短滞燃期近两个数量级。氧气、氮气激发态的弛豫和淬熄过程促使电能—化学能—热能的转化,放电结束后的总放热量增加,最高燃烧温度比自燃条件下高约400 K。同时,电子碰撞O2、N2激发态与O2的退激反应、单态氧原子O(1D)的弛豫等过程促进了氧原子的生成。此外,H原子的生成间接提高了O原子的物质的量分数(主要通过H+O2———→OH+O),加速C2H4氧化生成HCO、CO等,缩短了点火延迟时间,有助于燃烧效率的提高。 相似文献
8.
为研究高面板堆石坝的地震易损性,基于增量动力分析(IDA)与支持向量机(SVM)相结合的方法,首先利用拉丁超立方抽样(LHS)方法从人工生成的100条地震动中随机选取30条,选定PGA为地震动强度指标,坝顶竖向位移为性能指标,通过对每条地震动进行等间距调幅,对面板坝进行有限元计算及对结果进行IDA分析,提取各条地震动在所选性能指标不同极限状态下的PGA;然后引入SVM,以代表地震动特性的参数为输入,以PGA为输出,训练并测试SVM模型;最后利用SVM模型做快速预测,在考虑不同地震动数目的条件下,分析面板坝的地震易损性,并绘制地震易损性曲线。研究结果表明,IDA-SVM方法在分析大坝易损性的问题上具有可行性和有效性,且考虑不同地震动数目所得的地震易损性曲线不尽相同。 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(65):28152-28164
The combustion characteristics of ammonia/methanol mixtures were investigated numerically in this study. Methanol has a dramatic promotive effect on the laminar burning velocity (LBV) of ammonia. Three mechanisms from literature and another four self-developed mechanisms constructed in this study were evaluated using the measured laminar burning velocities of ammonia/methanol mixtures from Wang et al. (Combust.Flame. 2021). Generally, none of the selected mechanisms can precisely predict the measured laminar burning velocities at all conditions. Aiming to develop a simplified and reliable mechanism for ammonia/methanol mixtures, the constructed mechanism utilized NUI Galway mechanism (Combust.Flame. 2016) as methanol sub-mechanism and the Otomo mechanism (Int. J. Hydrogen. Energy. 2018) as ammonia sub-mechanism was optimized and reduced. The reduced mechanism entitled ‘DNO-NH3’, can accurately reproduce the measured laminar burning velocities of ammonia/methanol mixtures under all conditions. A reaction path analysis of the ammonia/methanol mixtures based on the DNO-NH3 mechanism shows that methanol is not directly involved in ammonia oxidation, instead, the produced methyl radicals from methanol oxidization contribute to the dehydrogenation of ammonia. Besides, NOx emission analysis demonstrates that 60% methanol addition results in the highest NOx emissions. The most important reactions dominating the NOx consumption and production are identified in this study. 相似文献
10.
《International Journal of Hydrogen Energy》2022,47(67):28782-28793
Highly-efficient and stable non-noble metal electrocatalysts for overcoming the sluggish kinetics of oxygen evolution reaction (OER) is urgent for water electrolysis. Biomass-derived biochar has been considered as promising carbon material because of its advantages such as low-cost, renewable, simple preparation, rich structure, and easy to obtain heteroatom by in-situ doping. Herein, Ni2P–Fe2P bimetallic phosphide spherical nanocages encapsulated in N/P-doped pine needles biochar is prepared via a simple two-step pyrolysis method. Benefiting from the maximum synergistic effects of bimetallic phosphide and biochar, high conductivity of biochar encapsulation, highly exposed active sites of Ni2P–Fe2P spherical nanocages, rapid mass transfer in porous channels with large specific surface area, and the promotion in adsorption of reaction intermediates by high-level heteroatom doping, the (Ni0.75Fe0.25)2P@NP/C demonstrates excellent OER activity with an overpotential of 250 mV and a Tafel slope of 48 mV/dec at 10 mA/cm2 in 1 M KOH. Also it exhibits a long-term durability in 10 h electrolysis and its activity even improves during the electrocatalytic process. The present work provides a favorable strategy for the inexpensive synthesis of biochar-based transition metal electrocatalysts toward OER, and improves the water electrolysis for hydrogen production. 相似文献