Good dielectric performance and broadband dielectric polarization in Ag,Nb co-doped TiO2

Due to the demand of miniaturization and integration for ceramic capacitors in electronic components market, TiO₂-based ceramics with colossal permittivity has become a research hotspot in recent years. In this work, we report that Ag⁺/Nb⁵⁺ co-doped (Ag_1/4Nb_3/4)_xTi_1−xO₂ (ANTOx) ceramics with colossal permittivity over a wide frequency and temperature range were successfully prepared by a traditional solid–state method. Notably, compositions of ANTO0.005 and ANTO0.01 respectively exhibit both low dielectric loss (0.040 and 0.050 at 1 kHz), high dielectric permittivity (9.2 × 10³ and 1.6 × 10⁴ at 1 kHz), and good thermal stability, which satisfy the requirements for the temperature range of application of X9R and X8R ceramic capacitors, respectively. The origin of the dielectric behavior was attributed to five dielectric relaxation phenomena, i.e., localized carriers' hopping, electron–pinned defect–dipoles, interfacial polarization, and oxygen vacancies ionization and diffusion, as suggested by dielectric temperature spectra and valence state analysis via XPS; wherein, electron-pinned defect–dipoles and internal barrier layer capacitance are believed to be the main causes for the giant dielectric permittivity in ANTOx ceramics.     

双螺旋结构电容式棒位测量传感器偏心性能研究

控制棒棒位测量传感器是低温核供热堆控制棒步进和落棒测量的关键设备，其精度和可靠性直接关系到反应堆的安全性。对于双螺旋结构电容式棒位测量传感器，完成了传感器静态特性实验，利用有限元分析方法建立了传感器的计算模型，模型计算结果与实验结果符合良好。在此基础上，采用有限元模型结合正交试验方法分析了极板张角、极板螺距、陶瓷管壁厚度等设计参数对传感器偏心性能的影响，获得了传感器设计参数的优化组合。研究结果表明，减小极板张角、增大极板螺距、增大陶瓷管壁厚度、减小陶瓷管相对介电常数有助于减小传感器偏心误差，由正交试验方法获得的参数组合能实现棒位测量不失步的要求。研究成果为双螺旋结构电容式棒位测量传感器的设计和优化奠定了基础。     

高地压严重突出区域下向穿层钻孔预抽消突技术

利用工作面高抽巷施工掩护顺槽掘进工作面下向穿层条带预抽钻孔,通过对钻场底板深、浅孔注浆封堵围岩裂隙解决了孔内返水不畅难题;采取了"两堵一注"封孔方式确保封孔严密不漏气;孔内全程下吹水管,实现了单孔、分组、定时吹水工作目标,提高了下向消突钻孔抽采效果,形成了一套高效、快速的下向穿层钻孔消突管理模式,实现了高地压严重突出区域煤层高效消突以及技术经济一体化目标,安全经济效益显著。     

基于信息熵抑制的大数据特征隐匿性加密仿真

针对传统大数据特征加密方法中大数据精度较差、加密耗时较长的问题,提出基于信息熵抑制的大数据特征隐匿性加密方法。分析信息熵抑制相关理论,采用信息熵映射函数对大数据分类,将信息熵抑制过程转化为计算2个文件相似性的过程,并根据余弦相似度公式以及Hamming距离值计算数据相似度,完成数据消冗。在完成数据消冗的基础上,分析分组密码方法和ECC加密方法,结合两种方法得到大数据特征隐匿性加密处理计算公式,实现基于信息熵抑制的大数据特征隐匿性加密。实验研究结果表明,所提方法能够有效去除冗余数据,提升大数据精度,加快数据加密的处理速度,高效完成大数据加密过程。     

Study of pass band resonance characteristics of aperture type FSS

In this paper, the resonance characteristics of aperture type frequency selective surface (FSS) is presented. A systematic investigation is carried out to design the compact FSS. The optimized structure consists of rectangular Archimedean spiral with inter-digital capacitance. Resonance characteristics is verified in both single-layer as well as the double-layer approach by embedding FSS on one side of the dielectric substrate. The performances of the dual-layer are observed by varying air-gap between two FSS layers. The structure offers satisfactory resonance (transmission and reflection) characteristics at optimum air-gap of 7 mm between two layers with the 3 dB cutoff region over a frequency range (3.66–4.66 GHz). Finally, an array of 31 × 31 FSS elements of two layers is fabricated for experimental characterization. A close agreement between simulated and measured results is observed.     

A low power and low phase-noise 91~96 GHz VCO in 90 nm CMOS

This paper reports a 94 GHz CMOS voltage-controlled oscillator (VCO) using both the negative capacitance (NC) technique and series-peaking output power and phase noise (PN) enhancement technique. NC is achieved by adding two variable LC networks to the source nodes of the active circuit of the VCO. NMOSFET varicaps are adopted as the required capacitors of the LC networks. In comparison with the conventional one, the proposed active circuit substantially decreases the input capacitance (C_in) to zero or even a negative value. This leads to operation (or oscillation) frequency (OF) increase and tuning range (TR) enhancement of the VCO. The VCO dissipates 8.3 mW at 1 V supply. The measured TR of the VCO is 91~96 GHz, close to the simulated (92.1~96.7 GHz) and the calculated one (92.2~98.2 GHz). In addition, at 1 MHz offset from 95.16 GHz, the VCO attains an excellent PN of – 98.3 dBc/Hz. This leads to a figure-of-merit (FOM) of ?188.5 dBc/Hz, a remarkable result for a V- or W-band CMOS VCO. The chip size of the VCO is 0.75 × 0.42 mm², i.e. 0.315 mm².     

正电子湮没研究Al、Nb共掺CaCu3Ti4O12陶瓷高介电常数机理

关于CaCu₃Ti₄O₁₂陶瓷的高介电常数机理，目前广泛接受的是非本征的内阻挡层电容模型。该模型认为在多晶中元素变价、缺陷和非化学计量比等导致的半导化晶粒被绝缘晶界层，即内阻挡层所包围。其中内阻挡层的厚度对材料的介电性能影响较大，而扫描电子显微镜（SEM）测试表明样品晶界呈稀烂的果酱状，SEM难以测量晶界区域绝缘内阻挡层厚度。本文采用正电子湮没技术表征其厚度，通过对CaCu₃Ti₄O₁₂陶瓷共掺不同浓度的Al、Nb（CaCu₃Ti_4-xAl_0.5xNb_0.5xO₁₂，x=0.2%、0.5%、5.0%）改变其晶粒和晶界的微观结构，研究CaCu₃Ti₄O₁₂陶瓷高介电常数机理。正电子湮没结果显示，掺杂样品符合多普勒展宽谱S参数的变化趋势与平均寿命的变化趋势一致。x=0.5%掺杂样品的介电常数最高，其平均寿命、S参数和湮没长寿命成分均最小，阻挡层最薄。实验结果验证了描述CaCu₃Ti₄O₁₂陶瓷高介电常数机理的内阻挡层电容模型的预测。     

Chemical Recycling of Carbon Fiber Reinforced Epoxy Composites Using Mild Conditions

The increased use of carbon fiber reinforced thermosets generates more waste and end-of-life products. However, an efficient recycling method for the expensive carbon fibers has not yet been developed. The selective decomposition of amine-cured epoxy resin under mild conditions is presented. A two-step method was investigated to decompose the epoxy resin. The optimum parameters were initially determined using a model compound. By analysis of the reaction products, a cleavage of the C–N bond according to the Cope elimination could be proven. Therefore, the Cope elimination is suggested as the main step of the decomposition of amine-cured epoxy resins in presence of hydrogen peroxide. By dissolving the resin, it is possible to recover resin-free fibers with unimpaired mechanical properties.     

Evidence for alternative exhaled elimination profiles of disinfection by-products and potential markers of airway responses to swimming in a chlorinated pool environment

Chlorine-based disinfectants protect pool water from pathogen contamination but produce potentially harmful halogenated disinfection by-products (DBPs). This study characterized the bioaccumulation and elimination of exhaled DBPs post-swimming and investigated changes in exhaled breath profiles associated with chlorinated pool exposure. Nineteen participants provided alveolar-enriched breath samples prior to and 5, 90, 300, 510, and 600 minutes post-swimming. Known DBPs associated with chlorinated water were quantitated by thermal desorption-gas chromatography-mass spectrometry. Two distinct exhaled DBP elimination profiles were observed. Most participants (84%) reported peak concentrations immediately post-swimming that reduced exponentially. A sub-group exhibited a previously unobserved and delayed washout profile with peak levels at 90 minutes post-exposure. Metabolomic investigations tentatively identified two candidate biomarkers associated with swimming pool exposure, demonstrating an upregulation in the hours after exposure. These data demonstrated a hitherto undescribed exhaled DBP elimination profile in a small number of participants which contrasts previous findings of uniform accumulation and exponential elimination. This sub-group which exhibited delayed peak-exhaled concentrations suggests the uptake, processing, and immediate elimination of DBPs are not ubiquitous across individuals as previously understood. Additionally, non-targeted metabolomics highlighted extended buildup of compounds tentatively associated with swimming in a chlorinated pool environment that may indicate airway responses to DBP exposure.     

白云凹陷陆架—陆坡区多次波压制技术

白云凹陷位于中国南海北部陆架—陆坡区，由于水深变化剧烈，目标区地震资料中发育的表面多次波周期变化大，较难压制。传统的预测反褶积、SRME、Radon技术及其组合，压制这种水深变化剧烈的多次波效果不佳。为此，对近年发展的一种浅水表面多次波压制技术即确定性水层多次波压制技术DWD进行了研究，提出将其与SRME和Radon传统方法联合的多次波压制思路。DWD方法是先从水速动校后的最小炮检距的自相关剖面上拾取水底双程反射时间，然后在近道外推后将t-x域地震数据变换到τ-p域，再在τ-p域通过波场外推预测出多次波模型，最后与原始数据进行自适应匹配相减压制多次波。处理结果表明，DWD+SRME+Radon方法组合能有效地压制白云凹陷目标区多次波。与原处理剖面相比，此次处理后的成果剖面品质明显提高，降低了解释风险；同时，用此次处理得到的偏移道集进行叠前波阻抗反演，结果较好地刻画了目标砂体的特征和边界。