Identifying model pollutants to investigate biodegradation of hazardous XOCs in WWTPs

Xenobiotic organic compounds (XOCs) in wastewater treatment plant (WWTP) effluents might cause toxic effects in ecosystems. Several investigations have emphasized biodegradation as an important removal mechanism to reduce pollution with XOCs from WWTP effluents. The aim of the study was to design a screening tool to identify and select hazardous model pollutants for the further investigation of biodegradation in WWTPs. The screening tool consists of three criteria: The XOC is present in WWTP effluents, the XOC constitutes an intolerable risk in drinking water or the environment, and the XOC is expected to be biodegradable in WWTPs. The screening tool was tested on bisphenol A (BPA), carbamazepine (CBZ), di(2ethylhexyl)-phthalate (DEHP), 17beta-estradiol (E2), estrone (E1), 17alpha-ethinyloetradiol (EE2), ibuprofen, naproxen, nonylphenol (NP), and octylphenol (OP). BPA, DEHP, E2, E1, EE2, and NP passed all criteria in the screening tool and were selected as model pollutants. OP did not pass the filter and was rejected as model pollutant. CBZ, ibuprofen, and naproxen were not finally evaluated due to insufficient data.     

Non-dioxin-like PCBs: a survey on fishery and aquaculture from the Mediterranean area

A sampling campaign from 21 sites in Italy was conducted: 15 species from fishery and three species from aquaculture, for a total of 40 determinations, were considered. A careful sample preparation preceded the instrumental analysis that was carried out by means of GC–ECD and GC–MS. Good laboratory practice was achieved by the participation in proficiency tests, by the use of certified reference materials and by applying other directives recommended by international organisations. Concentrations measured in this work were compared with a TDI proposed by some international bodies: for a person weighing 70 kg one-third of the samples from fishery, when consumed, lead to exceed this TDI if the average fish daily consumption per capita is considered. Based on the data obtained here some hypotheses on environmental spreading and influence of PCBs on human health are made. Some suggestions about the preparation of fish for consumption are also given.     

基于辐射亮度反演的TDI CCD相机的响应非均匀性校正

分析了TDI CCD的各种噪声,重点研究了响应非均匀性和固定图形噪声对成像质量的影响,通过辐射亮度反演的方法对响应非均匀性进行了校正。实验结果表明,该校正方法能够有效去除响应非均匀性造成的条纹,得到清晰的图像。     

TDI的生产现状和研究进展

介绍了甲苯二异氰酸酯（TDI）的生产现状、需求及不同生产工艺的优缺点;评述了TDI的发展前景和今后的研究工作。     

红外光谱法测定固化剂中HDI和TDI三聚体含量

采用红外光谱法对固化剂中HDI三聚体与TDI三聚体进行定量分析,作出了相关的工作曲线,并通过对未知样品的红外分析结果对比,确认了其可靠性.     

Rv470残渣浓缩器的设计

介绍了TDI残渣浓缩器的应用及特点,通过对该设备运行情况的调查,对其设计过程提出了一些建议。     

线列TDI型红外焦平面读出电路低功耗设计

摘要：基于对具有TDI功能的红外线列读出电路工作原理的分析,通过改变电路的工作电流及工作时间进行低功耗设计,最后分别对优化前后的读出电路进行直流仿真,仿真结果显示优化后读出电路功耗较原始电路降低了49.5%,验证了低功耗设计方案的可行性。     

TDI型红外探测器空间校正方法的设计与实现

时间延迟积分(TDI)型红外探测器作为第二代红外探测器,具有更高的温度灵敏度和更大的扫描成像视场.和面阵成像探测器相比,TDI型红外探测器必须在装置中加入扫描机构进行扫描成像,由于TDI型红外探测器光敏元在空间的位置交错排列,为了保证奇偶像元对同一目标成像,这就涉及到扫描方向与探测器奇偶像元空间匹配的问题.以480×6红外探测器为例,详细介绍了TDI型红外探测器光敏元的排列结构、工作方式以及空间校正的原理,给出了空间校正的算法和FPGA实现方法,并通过仿真和实验验证了方法的正确性.     

空间TDICCD相机的便携式图像检测设备

空间TDICCD相机的研发过程中多数图像检测设备采用基于采集卡、海量存储器、PC服务器的结构从而限制了其使用环境,不能适应所有的检测任务。对其检测原理、关键技术和实现进行了详细的讨论。进而提出了一种便携式的图像检测设备。该设备的物理尺寸为320 mm×250 mm×100 mm,采用锂电池供电方式最长可工作3 h,本设备功能完善适应了80%的空间TDICCD相机的图像检测任务。     

TDI三聚体溶液的合成及其在高回弹泡沫中的应用

采用先氨酯改性再三聚的方法合成了TDI三聚体溶液,并将其用于高回弹泡沫的制备。讨论了聚醚多元醇种类、预聚体NCO含量及三聚催化剂用量对TDI三聚体溶液的影响,并考察了TDI三聚体溶液对高回弹泡沫阻燃性、黄变性等的影响。结果表明,采用复配多元醇对TDI进行氨酯改性,预聚体NCO质量分数为38.0%,每100份TDI预聚体添加0.0375~0.0500份三聚催化剂时,可获得粘度为100~250mPa·s的TDI三聚体溶液,该三聚体溶液可稳定贮存6个月以上,0℃不结晶。TDI三聚体溶液可有效提高泡沫的阻燃性,并在一定程度上改善泡沫的耐黄变性。