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1.
Within the framework of the effective-mass approximation and the dipole approximation, considering the three-dimensional confinement of the electron and hole and the strong built-in electric field(BEF) in strained wurtzite Zn O/Mg0:25Zn0:75O quantum dots(QDs), the optical properties of ionized donor-bound excitons(D+, X)are investigated theoretically using a variational method. The computations are performed in the case of finite band offset. Numerical results indicate that the optical properties of(D+, X) complexes sensitively depend on the donor position, the QD size and the BEF. The binding energy of(D+, X) complexes is larger when the donor is located in the vicinity of the left interface of the QDs, and it decreases with increasing QD size. The oscillator strength reduces with an increase in the dot height and increases with an increase in the dot radius. Furthermore, when the QD size decreases, the absorption peak intensity shows a marked increment, and the absorption coefficient peak has a blueshift. The strong BEF causes a redshift of the absorption coefficient peak and causes the absorption peak intensity to decrease remarkably. The physical reasons for these relationships have been analyzed in depth. 相似文献
2.
The influence of the environment on the excited state transitions of meso-tetrakis(p-sulfonatophenyl) porphyrin (TPPS) is reported. TPPS was investigated in protonated and non-protonated forms, and in the presence of the cationic cetyltrimethylammonium bromide (CTAB) micelles. The singlet excited-state absorption spectra were measured by using the white-light continuum Z-scan technique and the triplet–triplet absorption spectra were acquired employing an association of laser flash photolysis and Z-scan techniques. Our results show that the perseveration of the molecular symmetry, upon excitation, depends on the state of multiplicity of the molecules, as well as on the environment and structural characteristics of the porphyrin. Additionally, it was observed that for excited molecules, the ring distortion caused by the protonation of porphyrin ring has great influence on the changes observed for the symmetry and vibronic structure. The results clearly show that the porphyrin investigated is a promising candidate for optical limiting applications for all investigated environments. 相似文献
3.
Enhancement of the dissolution rate of the poorly water-soluble hypoglycemic agent, gliclazide, by the aid of lyophilization was investigated. Mannitol, sodium lauryl sulfate (SLS) and polyvinyl pyrrolidone (PVP-k-30) were employed in different weight ratios (43%, 56% and 64% w/w, respectively) as water-soluble excipients in the formulation. Lyophilized systems were found to exhibit extremely higher in vitro dissolution rate compared to the unprocessed drug powder. Solid state characterization of the lyophilized systems using X-ray powder diffraction, Fourier transform infrared spectroscopy and differential scanning calorimetry techniques revealed that dissolution enhancement was attributable to transformation of gliclazide from the crystalline to an amorphous state in the solid dispersion formed during the lyophilization process. The gastrointestinal absorption and hypoglycemic effect of the lyophilized gliclazide/SLS system were investigated following oral administration to Albino rabbits. Cmax and area under the plasma concentration–time curve of gliclazide (AUC0–12) after administration of the lyophilized formulations were significantly higher than those obtained after administration of the unprocessed gliclazide. 相似文献
4.
选取具有代表性的碳钢、不锈钢、镀锌碳钢、铝、钛和铜挂片,在某企业不同部位投放后进行为期半年的大气腐蚀试验,得出了在半年期中的腐蚀规律。在此基础上,对每种金属材料的腐蚀特点进行总结,并对大气腐蚀的各种影响因素进行分析,提出了行之有效的防护措施。 相似文献
5.
6.
S V Bhat 《Bulletin of Materials Science》1994,17(7):1271-1285
When examined using continuous wave electron paramagnetic resonance and nuclear magnetic resonance spectrometers, the highT
c superconductors give rise to intense, low field, ‘non-resonant’ absorption signals in the superconducting state. This phenomenon
can be used as a highly sensitive, contactless technique for the detection and characterization of superconductivity even
in samples containing only minute amounts of the superconducting phase. Further, it can also be applied to the determination
of material parameters of interest such asJ
c andH
c2 in addition to being a powerful way of distinguishing between weak-link superconductivity and bulk superconductivity. The
details of these aspects are discussed. 相似文献
7.
油田污水中咪唑啉缓蚀剂浓度检测技术研究 总被引:5,自引:0,他引:5
研究评价了油田污水中咪唑啉缓蚀剂浓度检测的七种方法 ,其中紫外光分析法和显色反应法适合于低浓度咪唑啉缓蚀剂检测 ,且方法简便、速度快、成本低 ,检测浓度范围 2~ 5 0mg/L。 相似文献
8.
Ramazan Kahraman 《Journal of Materials Engineering and Performance》2002,11(1):46-50
The objective of this study was to evaluate the effectiveness of sodium benzoate as an inhibitor to slow down or prevent atmospheric
corrosion/discoloration of the local mild steel during storage in the Arabian Gulf region. Test specimens were prepared from
locally produced reinforcing steel products. The inhibitor solution was applied on steel specimens at a concentration of 100
mM for 1 day at room temperature. Wooden exposure racks were used to hold as-received and inhibitor-treated specimens during
atmospheric exposure for different periods. Corrosion was evaluated through weight loss determination and electrochemical
technique. As expected, the Arabian Gulf atmosphere was corrosive on the as-received local mild steel. On the other hand,
treatment of steel with sodium benzoate lowered its corrosion rate during initial days of its exposure to atmosphere. However,
atmospheric corrosion inhibition performance of sodium benzoate deteriorated with exposure time after 30 or more days of atmospheric
exposure, and the corrosion rates of sodium benzoate-treated specimens reached that of the unprotected specimens at the end
of 90 days of atmospheric exposure. 相似文献
9.
用原子吸收次灵敏线法塞曼效应扣除背景测定土壤中Fe、Mn,实验结果表明:此方法有较好的准确度,精密度,操作简单,适合一般土壤中Fe、Mn的测定。 相似文献
10.