Copper–4,4′-dipyridyl coordination compound as solid reagent for spectrophotometric determination of reducing sugar employing a multicommutation approach

In this work a multicommuted flow system employing copper–4,4′- dipyridyl coordination compound as the solid-phase reagent for the spectrophotometric determination of reducing sugar was developed. The coordination compound was synthesized through a reaction of the 4,4′-dipyridyl and copper (II) nitrate, under hydrothermal conditions. The complex was characterized by infrared spectroscopy (FTIR), power X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and thermogravimetric analysis (TGA). Based on the characterization, a multicommuted spectrophotometric procedure for the determination of reducing sugar using copper (II) complex as solid reagent is proposed. The proposed method was based on the redox reaction between a monosaccharide, such as fructose and glucose (reducing sugar) and Cu(II). This reaction, mediated in an alkaline medium, produces a yellow compound that can be determined by absorption electronic spectroscopy (λ_ABS = 420 nm). Under optimum experimental conditions, a linear response ranging from 1.0 to 20.0 g L⁻¹ (R = 0.9978 and n = 5), a detection (3σ criterion) and quantification (10σ criterion) limit estimated at 0.23 and 0.75 g L⁻¹, respectively, a standard deviation relative of 4.7% (n = 7), for a reference solution of 10.0 g L⁻¹ reducing sugar, and a sampling rate of 75 determinations per hour were achieved. The proposed system was applied to the determination of reducing sugars in coconut water and juices. The analysis of ten samples and the application of the t-test to the results found, and those obtained using reference procedures (AOAC), provided no significant differences at a 95% confidence level. This system enabled the analysis of reducing sugar with ease and simplicity, providing a significant economy of the solid reagent (600 μg per determination) and reducing effluent generation.     

对CFG桩质量缺陷的探讨

根据具体工程的概况及水文地质条件，分析了CFG桩在地下水位出现大面积缩颈现象和复合地基载荷试验达不到设计要求的原因，并介绍了地基补强措施，以满足工程质量的要求。     

高导电性原油电脱盐工艺研究

南阳原油中金属含量较高,掺有部分3次采油采出原油,加工时易造成电脱盐装置原油乳化,电导率高,脱盐难度较大。装置投产十几年来脱后含盐一直不合格,经过改造仍然超标,常压塔顶腐蚀严重。为此,对原油进行了电脱盐工艺条件及破乳剂研究,研制出了高效电脱盐设备和生物复合脱盐剂及降电流剂,采用平流弓形电极进行改造,解决了该原油的电脱盐问题,使脱后含盐达到3 mg/L。     

聚苯硫醚复合涂层的耐磨性能

研究了用固体润滑石墨、碳化硅、二硫化钼等填料改性的聚苯硫醚 (PPS)涂层的耐磨性能。实验结果表明 ,聚苯硫醚复合涂层具有优良的耐磨性 ;加入适量 ( 3 0 % )的石墨、碳化硅等固体润滑剂 (石墨 :碳化硅 =2∶3 ) ,可以有效提高涂层的耐磨性能 ,而二硫化钼和三氧化二铬的减摩效果更佳     

超分子主体化合物在分析化学中的应用研究进展

综述了近年来超分子主体化合物在分析化学领域的应用研究与进展。分别以冠醚、环糊精、杯芳烃、卟啉4类超分子为主体功能化合物的研究进行了详细的评述，并对这几类主体化合物在分析化学中的应用研究进行了展望。     

新型复合弹簧的研究

提出一种金属圆锥弹簧与橡胶圆锥弹簧复合而成的弹簧．分析表明：它可以应用于弹性耦合激励振动筛和座式直线振动筛。     

聚合物复合材料填充剂的改性

在前人研究的基础之上，归纳总结了聚合物复合材料填充剂的种类，综述了对其进行表面改性的目的、条件、方法、工艺以及对改性结果的表征等。文章还分析了影响填充聚合物复合材料性能的因素，指出了今后发展的方向。     

Centrifugal Casting of High Speed Steel/Nodular Cast Iron Compound Roll Collar

Ｈｉｇｈ ｓｐｅｅｄｓｔｅｅｌ (ＨＳＳ) ,ｉｓｃｈａｒａｃｔｅｒｉｚｅｄｂｙｅｘ ｃｅｌｌｅｎｔｈａｒｄｎｅｓｓ ,ｗｅａｒｒｅｓｉｓｔａｎｃｅ ,ａｎｄ ｇｏｏｄｒｅｄｈａｒｄｎｅｓｓ .Ｒｅｃｅｎｔｌｙ ,ＨＳＳｉｓａｐｐｌｉｅｄｔｏｍａｎｕｆａｃｔｕｒｅｈｏｔｒｏｌｌｉｎｇｒｏｌｌｓｔｏｐｒｏｄｕｃｅｓｔｒｉｐｓｏｆｇｏｏｄｓｈａｐｅａｎｄｓｍａｌｌｃｒｏｗｎｗｉｔｈｅｘｔｅｎｄｅｄｒｏｌｌｓｅｒｖｉｃｅｌｉｆｅ[1,2 ] .ＴｈｅＨＳＳｉｓａｐｐｌｉｅｄｔｏｍａｎｕｆａｃｔｕｒｅｒｏｌｌｃｏｌｌａｒｆｏｒ…     

Extracting Electron Densities in N-Type GaAs From Raman Spectra: Theory

In this paper, we present the theory for calculating Raman line shapes as functions of the Fermi energy and finite temperatures in zinc blende, n-type GaAs for donor densities between 10¹⁶ cm⁻³ and 10¹⁹ cm⁻³. Compared to other theories, this theory is unique in two respects: 1) the many-body effects are treated self-consistently and 2) the theory is valid at room temperature for arbitrary values of the ratio R = (Q²/α), where Q is the magnitude of the normalized wave vector and α is the normalized frequency used in the Raman measurements. These calculations solve the charge neutrality equation self-consistently for a two-band model of GaAs at 300 K that includes the effects of high carrier concentrations and dopant densities on the perturbed densities of states used to calculate the Fermi energy as a function of temperature. The results are then applied to obtain the carrier concentrations from Fermi energies in the context of line shapes in Raman spectra due to the coupling between longitudinal optical phonons and plasmons. Raman measurements have been proposed as a non-destructive method for wafer acceptance tests of carrier density in semiconductor epilayers. The interpretation of Raman spectra to determine the majority electron density in n-type semiconductors requires an interdisciplinary effort involving experiments, theory, and computer-based simulations and visualizations of the theoretical calculations.     

Preparation of Compound Ultrafine CeO2 by Wet-Solid-Phase Mechanochemical Modification

To satisfy practical requirements from industrial applications, an alternate route for synthesis compound ultrafine CeO2 powders by wet-solid-phase mechanochemical modification using industrial grade hydrated cerium carbonate as raw material was proposed.The effect of modifier reaction percentage, reaction time, calcining temperature and modifier amount on particle size, density, suspensibility, and hardness of compound CeO2 powder was investigated.The phase evolutions of preparation process were characterized by XRD.SEM micrograph of the final product shows that compound CeO2 powders obtained are well-dispersed, spherically-shaped, uniformly-sized and submicron-sized particles.The method is readily available in raw material, low in cost, simple in process, and has great potential for industrialization.The compound CeO2 powders of different physical properties can be synthesized by controlling the above-mentioned influence factors in preparation process.