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1.
The Nd-doped and Er-doped LuF3 single crystals were grown by the micro-pulling-down method to study their scintillation properties in the vacuum-ultraviolet (VUV) region. The doubly Nd–Er codoped single crystal was grown to study possibility of scintillation performance improvement by energy transfer from Er3+ to Nd3+ ions. The LiF flux was to avoid phase transition below melting temperature. The 1%Nd-doped sample showed the highest overall scintillation efficiency under X-ray excitation which was 7 times as high as that of the LaF3:Nd 8% standard. The leading Nd3+ 5d–4f emission was situated at 176 nm, while the Er3+ 5d–4f emission for Er-doped samples was observed at 163 nm, which better matches the sensitivity of some VUV-sensitive photodetectors. The optimum Er concentration was determined to be around 1–3 mol%. No Er3+ 5d–4f emission was observed for the doubly Er,Nd-codoped sample due to energy transfer from the Er3+ to Nd3+ ions. Slight improvement of the light yield was observed in the doubly-doped sample with respect to the Nd-only doped one. 相似文献
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针对车用柴油酸度等性质测定过程繁琐,采用衰减全反射样品池测定车用柴油的红外光谱,用偏最小二乘法(PLS)建立红外光谱测定车用柴油酸度、密度、闪点和凝点的4个校正模型,验证标准误差分别为0.46 mg/(100 mL),0.77kg/m3,2.60 ℃,2.77 ℃,该方法符合标准方法再现性要求。与标准方法相比,该方法具有无需预处理、操作简单、测量快速、重复性好等优点。 相似文献
4.
TeMxMo1.7O mixed oxides (M = V and/or Nb; x = 0-1.7) have been prepared by calcination of the corresponding salts at 600 °C in an atmosphere of N2. A new crystalline phase, with a Te/V/Mo atomic ratio of 1/0.2-1.5/1.7, has been isolated and characterised by XRD and IR spectroscopy. This phase is observed in the TeVMo or TeVNbMo mixed oxide but not in the TeNbMo mixed oxide. The new crystalline phase shows an XRD pattern similar to Sb4Mo10O31 and probably corresponds to the M1 phase recently proposed by Aouine et al. (Chem. Commun. 1180, 2001) to be present in the active and selective MoVTeNbO catalysts. Although these catalysts present a very low activity in the propane oxidation, they are active and selective in the oxidation of propene to acrolein and/or acrylic acid. However, the product distribution depends on the catalyst composition. Acrolein or acrylic acid can be selectively obtained from propene on Nb-free or Nb-containing TeVMo catalysts, respectively. The presence of both V and Nb, in addition to Mo and Te, appears to be important in the formation of acrylic acid from propene. 相似文献
5.
Colour Centres and Energy Transfer in BaF2-xClx:Eu2+ Phosphors 总被引:1,自引:1,他引:0
The optical absorption spectra of BaF2-xClx:Eu2 after ultraviolet (UV) light excitation were investigated.The differences between the absorption spectra after and before excitation (DAS) were observed.The DAS increase at both the high and the low energy side of F band in BaF2-xClx:Eu2 after 245 nm UV light excitation.The bleach effect of UV light and the absorption of electrons in the valence band may account for the former and the formation of Fa centres (association of F(Cl-) centres), whose absorption band matches the HeNe laser better, may explain the latter.In the write-in process, the transfer of electrons is via tunneling.In the readout process, the transfer of electrons captured in F(F-) and Fa centres is more likely via tunneling, and that of F(Cl-) centres is more likely via conduction band. 相似文献
6.
Chun Yang Yin Sharifah Aishah Syed Abdul KadirYing Pei Lim Sharifah Nawirah Syed-AriffinZurinawati Zamzuri 《Fuel Processing Technology》2008
Ash derived from combustion of Malaysian oil palm biomass (empty fruit bunches consisting of fibers) was physically and chemically characterized in order to provide a comprehensive understanding of its specific properties in terms of toxicity, compositions and reusability. Principal analyses conducted include particle size distribution, scanning electron microscopy, elemental dispersive X-ray, elemental analysis, toxicity characteristic leaching procedure (TCLP) as well as thermogravimetric, X-ray diffractometry and Fourier-transform infrared analyses. TCLP result indicated that the oil palm ash (OPA) should not be classified as toxic wastes in terms of heavy metal leachability since leachable copper, cadmium, lead and nickel concentrations were detected below the stipulated leachability limits. It was determined that the OPA contained high amount of potassium as well as presence of silica which implied its suitability to be reused as crude fertilizer or cement replacement material. 相似文献
7.
本文介绍红外热象技术在工程热物理研究中某些应用的探索。作为实例,通过热象技术,实验研究了具有水平凸台离散热源的倾斜板的散热,在研究它的自然对流换热部份结合利用激光全息干涉技术。此间着重于分析倾斜角对散热的影响。 相似文献
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A new microstructure, thornball, of zinc oxide (ZnO) was synthesized by a very simple solid vapor deposition process under lead oxide (PbO) atmosphere. The microthornballs consist of numerous needles, which extend outwards in all directions symmetrically. They have dimensions of 120 μm in diameter, while the average diameter of the needles is about 100-200 nm. The needles on the balls grow along the 〈0 0 0 1〉 orientation and have gradient compositions along radial. Control experiments proved that PbO played an important role in the growth. Additionally, photoluminescence property was observed and provided the evidence that PbO did not deteriorate the optical properties of ZnO thornballs. This kind of microstructures has potential applications in the field of photochemical catalysis. 相似文献
10.
Porous alumina films can be found in a wide variety of materials, including filters, thermal insulation components, dielectrics, biomedical and catalyst supports, coatings and adsorbents. Production methods for these films are as equally diverse as their applications. In this work, a hybrid process based upon chemical vapor deposition and gas-to-particle conversion is presented as an alternative technique for producing porous alumina films, with the main advantages of solvent-free, low substrate-temperature operation. In this process, nanoparticles were produced in the vapor phase by reaction of aluminum acetylacetonate in the presence of oxygen. Downstream of this reaction zone, these nanoparticles were collected via thermophoresis onto a cooled substrate, forming a porous film. Some deposited films were subjected to post-processing in the form of annealing in air. Fourier-transform infrared spectra and X-ray energy-dispersive spectroscopy analysis confirmed the production of alumina at processing temperatures above 973 K. X-Ray diffraction revealed that the films were amorphous. Film thickness, ranging from 30 to 250 μm, and the average deposition rate were determined from scanning electron microscopy results. From transmission electron microscopy, the average primary particle size was determined to be approximately 18 nm and the formation of nanoparticle aggregates was evident. Annealing of the films at temperatures ranging from 523 to 1173 K in the presence of air did not have an effect on particle size. The specific surface area of the powder composing the films ranged from 10 to 185 m2 g−1, as determined from nitrogen gas adsorption by the Brunauer–Emmett–Teller method. 相似文献