Phase equilibria of quasi-binary systems consisting of multicomponent polymers 1 and 2. IV: Poly(ethylene oxide)/poly(propylene oxide) systems

To confirm the reliability of the theory of phase equibria of multicomponent polymer 1/multicomponent polymer 2 systems (i.e. quasi-binary systems) and the method of computer experiment based on this theory (Brit. Polym. J., 23 (1990)285; 23 (1990)299; Polym. Int., 29 (1992)219), could point curves (CPC), two-phase volume ratios ( R ) and critical solution points (CSP) have been determined experimentally for the quasi-binary mixtures of poly(ethylene oxide) (M¯_w = 647, M¯_w/M¯_n = 1.15; M¯_w and M¯_n, the weight-average and numberaverage molecular weights, respectively) and poly(propylene oxide) (M¯_w = 2028, M¯_w/M¯_n = 1.08; and M_w = 2987, M_w/M_n = 1.13). The hydroxyl end groups of both polymers were methoxylated in advance by the Cooper & Booth method (Polymer, 18 (1977)164). The thermodynamic interaction parameter between both polymers, χ₁₂, and the concentration dependence parameters for the above quasi-binary systems were determined by the method proposed in a previous paper (Brit. Polym. J., 23 (1990)299). CPC, R and CSP values calculated on the basis of the theory are in good agreement with the values determined experimentally.     

VARIATIONS IN ALFALFA JUICE SOLUTE CONCENTRATIONS AS WATER IS EVAPORATED

Alfalfa juice was extracted from plants during the graving phases of the first and second crops. The alfalfa juice was dried and solute concentrations were measured periodically during the process using freezing point depression (FPD) as an indicator. Solute/solvent weight ratios were calculated from the freezing point depression of fresh unconcentrated 'uice extracted from both firsc and second crops. At the time of harvest, tie FPD was a function of this ratio. The first and second crops behaved distinctively different during the drying process, with the second having a larger soluce concentration and a greater FPD at a given moisture content. The appearance of preci itate during the drying process and the general1 large FPD makes this materiay a questionable product for drying vitg low temperature processes.     

Alekseevskii-Tate revisited:An extension to the modified hydrodynamic theory of long rod penetration

The modified hydrodynamic theory of long rod penetration into semi-infinite targets was established independently by Alek-seevskii and Tate over forty years ago and since then many investigators contributed much to the development of the high speed penetration mechanics.However,in all the models proposed so far,the target resistance Rt is not well defined and usually determined by adjusting it until the predicted depth of penetration comes to an agreement with experimental data.In this paper,assumptions are...     

Molecular simulation of phase coexistence: Finite-size effects and determination of critical parameters for two- and three-dimensional Lennard-Jones fluids

Abstact The subject of this paper is the investigation of finite-size effects and the determination of critical parameters for a class of truncated Lennard-Jones potentials. Despite significant recent progress in our ability to model phase equilibria in multicomponent mixtures from direct molecular simulations, the accurate determination of critical parameters remains a difficult problem. Gibbs ensemble Monte Carlo simulations with systems of controlled linear system size are used to obtain the phase behavior in the near-critical region for two- and three dimensional Lennard-Jones fluids with reduced cutoff radii of 3, 3.5, and 5. For the two-dimensional systems, crossover of the effective exponent for the width of the coexistence curve from mean field ( = 1/2 in the immediate vicinity of the critical point to Ising-like (= 1/8) farther away is observed. Critical parameters determined by fitting the data that follow Ising-like behavior are in good agreement with literature values obtained with finite-size scaling methods. For the three-dimensional systems, no crossover to mean field-type behavior was apparent. Extrapolated results for the critical parameters are consistent with literature estimates for similar fluids. For both two- and three-dimensional fluids, system size effects on the coexistence curves away from the critical point are small, normally within simulation statistical uncertainties.Invited paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder. Colorado, U.S.A.     

Influence of ions on the critical behavior of a binary mixture near the consolute point

The lower critical point of stratification of a 3-methylpyridine (MP)+heavy water (D₂O) mixture in the presence of Na⁺ and CI^– ions has been studied by the Toepler shadow method. Addition of 0.3% ions lowered the critical temperature and reduced the equilibration time and the gradient of the refractive index (compressibillity). The analysis of the form of the near-critical isotherm demonstrated the ionic mixture to be described by the index = 3.05 ± 0.15. which corresponds to the classical mean-field theory. The results obtained provide evidence that even small admixtures of charged particles result in a substantial suppression of fluctuations near the critical point by the long-range Coulomb interaction.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder, Colorado, U.S.A.     

An inexact hybrid projection-proximal point algorithm for solving generalized mixed variational inequalities

In this paper, we investigate an inexact hybrid projection-proximal method for solving a class of generalized mixed variational inequalities in Hilbert spaces. We construct a general inexact hybrid projection-proximal point algorithm, in which an inexact relaxed proximal point step is followed by a suitable orthogonal projection onto a hyperplane. Under some suitable conditions concerned with the pseudomonotone set-valued mapping T, the nonsmooth convex function f and the step size λ_k, we prove the convergence of the inexact hybrid projection-proximal point algorithm for solving generalized mixed variational inequalities in Hilbert spaces.     

Existence and uniqueness of strictly nondecreasing and positive solution for a fractional three-point boundary value problem

In this paper, we consider the following nonlinear fractional three-point boundary value problem

     

基于C—V模型的目标检测与提取

在目标检测与提取中,传统的蛇模型和基于活动轮廓的局部区域检测方法受到初始条件或者自身的收敛性约束的影响,不仅时间花费多,而且不具备鲁棒性。本文提出一种基于C V模型的变分水平集的目标检测与提取方法,通过大量实验验证,在花费时间和鲁棒性上得到了显著的改善。     

计算机辅助外科手术空间配准技术的研究

医学图像和实际手术空间的配准问题是计算机辅助外科手术技术的一个重要的研究热点,它能够帮助医生选择最佳手术路径和减小手术损伤,实现手术的方便快捷和微创,提高手术成功率。主要研究了一种基于ICP算法的计算机辅助外科手术中空间配准技术,通过获取实验模型的空间坐标信息,进行点集配准,找到最优旋转矩阵和最优平移向量。并通过仿真实验给出了模拟的配准结果,仿真试验结果表明,ICP算法配准精度高,适用于计算机辅助外科手术。