The radiation crosslinking and scission of ethylene-propylene copolymers studied by solid-state nuclear magnetic resonance

Methyl groups from chain scission and H-crosslinks have been identified by solid-state nuclear magnetic resonance in amorphous ethylene-propylene copolymers containing 23 and 36 mole % propylene after γ-irradiation to 10 MGy at 30°C. G (scission) and G (crosslink) values determined from the n.m.r. spectra and by extraction are in agreement, which suggests that the crosslinks are not clustered. This may differ from the situation in polyethylene where there is a substantial crystalline content. G(S). G(X) and the ratio G(S)/G(X) increase with increasing propylene content of the copolymers.     

Analogy and duality of texture analysis by harmonics or indicators

According to the classic harmonic approach, an orientation density function (odf)f is expanded into its corresponding Fourier orthogonal series with respect to generalized spherical harmonics, and a pole density function (pdf) into its corresponding Fourier orthogonal series with respect to spherical harmonics. While pdfs are even (antipodally symmetric) functions, odfs are generally not. Therefore, the part of the odf which cannot be determined from normal diffraction pdfs can be mathematically represented as the odd portion of its series expansion. If the odff is given, the even part can be mathematically represented explicitly in terms off itself. Thus, it is possible to render maps ofharmonic orientation ghosts, and to evaluatevariants of mathematical standard odfs resulting in identical pdfs independent of pdf data. However, if only normal diffraction pdfs are known, the data-dependentvariation width of feasible odfs remained unaccessible, and within the harmonic approach a measure of confidence in a solution of the pdf-to-odf inversion problem does not exist.According to any discrete approach, an odff defined on some setG of orientations is expanded into its corresponding Fourier orthogonal series with respect to indicator functions of the elements of a partition ofG, and a pdf defined on the upper (lower) unit hemisphereS ₊ ^{3 3} into its corresponding Fourier orthogonal series with respect to indicator functions of the elements of a partition ofS ₊ ³ . The ambiguity of the pdf-to-odf inversion problem is discussed in terms of column-rank deficiency of the augmented projection matrix. The implication of the harmonic approach to split an odf into auniquely determined and anundetermined part does no longer seem to be reasonable. However, it is possible to numerically determine data-dependent confidence intervals for the Fourier coefficients with respect to the indicator functions which can be immediately interpreted as mean orientation densities within the elements of the partition ofG. Doing so for all Fourier coefficients in the finite series expansion, i.e. for all elements of the partition of the setG, eventually results in the data-dependent variation width of odfs feasible with respect to given pdf data, and to the partitions ofG andS ₊ ³ .Thus it is confirmed that the appearance of orientation ghosts, in particular correlations oftrue andghost orientation components, depends on the representation of an odf. It may be questioned whether in practical applications the implicit assumption of the harmonic method that the even part can be determined uniquely and free of error is generally a reasonable initial condition to develop ghost correction procedures.     

Towards inverse modeling of turbidity currents: The inverse lock-exchange problem

A new approach is introduced for turbidite modeling, leveraging the potential of computational fluid dynamics methods to simulate the flow processes that led to turbidite formation. The practical use of numerical flow simulation for the purpose of turbidite modeling so far is hindered by the need to specify parameters and initial flow conditions that are a priori unknown. The present study proposes a method to determine optimal simulation parameters via an automated optimization process. An iterative procedure matches deposit predictions from successive flow simulations against available localized reference data, as in practice may be obtained from well logs, and aims at convergence towards the best-fit scenario. The final result is a prediction of the entire deposit thickness and local grain size distribution. The optimization strategy is based on a derivative-free, surrogate-based technique. Direct numerical simulations are performed to compute the flow dynamics. A proof of concept is successfully conducted for the simple test case of a two-dimensional lock-exchange turbidity current. The optimization approach is demonstrated to accurately retrieve the initial conditions used in a reference calculation.     

应用于Template框架的SVG Tiny创作工具的设计与实现

通过对Template框架的研究,对在该框架中引入SVG Tiny技术进行了研究,并为该框架设计和实现了SVG Tiny创作工具。     

湿法相分离不对称超滤膜形成机理

本文选择了憎水的极怀非普质子性聚砜和亲水的极性质子怀聚砜酰胺两种膜材料，从铸膜液组成和凝胶过程两方面，用气相色谱和高效液相色谱研究了表征膜材料－溶剂－添加剂－水作用力的混合自由焓，平衡分配常数，及其与膜性能，不同溶剂特性粘度，雾点值和溶解度参数的关系，提出了铸膜液中有机溶剂的作用机理，及不对称超滤膜形成的一些规律。     

铝电解槽热平衡测试计算中的几点问题

由于缺乏正规的标准，铝电解槽能量平衡测试中存在着一些概念混淆、计算方法和公式错误的情况，应引起测试工作者的注意，在测试计算前应认真制订方案，多查一些参考资料，核实所用公式、数据，避免发生失误。同时对于类似计算，由于计算机的应用，应尽可能采取精确算法。没必要采取一些非常粗糙的近似算法和经验值。     

3G网络基站电磁环境影响分析

通过资料收集、理论预测、数据监测与分析,讨论了辽宁某市3G网络基站中典型基站的电磁环境。结果表明,理论预测与实际监测结果差距不大,各典型基站的电磁辐射功率密度均低于国家标准限值8μW/cm2,对该地区的电磁环境影响不大。对保护环境提出了相应的对策措施.     

铁尾矿为原料微波法制备介孔分子筛

以鞍山铁尾矿为硅源,CTAB为模板剂,采用微波辐照法合成出全硅介孔分子筛MCM-41。用N2低温吸附、FT-IR、XRD和TEM等表征手段考察了其比表面积、孔径分布、晶体形貌等特性。结果表明:微波辐射法合成的MCM-41分子筛诱导期极短,晶化速度很快,具有典型的按六方对称性排列的孔道结构,FT-IR证明了分子筛具有硅氧四面体骨架。     

Recombination luminescence from defects in boron-ion implantation-doped diamond using low fluences

 Two identical, high purity, natural type IIa diamonds, which displayed the ubiquitous blue cathodoluminescence (CL) band at ≈ 2.9 eV, as well as an indication of the corresponding green band at ≈ 2.4 eV, have been equivalently doped by using extremely low dose B⁺- and C⁺-ion CIRA-implantations respectively. Comparative CL measurements showed changes in the intensities of the 2.9 and 2.4 eV bands and the generation of bands at ≈ 4 eV, as well as at ≈ 3.5 and ≈ 4.6 eV (the latter two in the B⁺-CIRA diamond). The results are commensurate with the model (proposed previously) in which the 2.9 and 4 eV bands are generated respectively by electron-hole recombinations at negatively charged acceptor- and positively charged donor-like, intrinsic defects. The present results indicate that Coulomb interactions between the latter defects and (at least partially) compensated, negatively charged, boron acceptors, generate the 3.5 and 4.6 eV bands, which may be considered as higher energy (≈ 0.6 eV) replicas of the 2.9 and 4 eV bands. In both cases, two electrons and a hole interact just before the hole combines with an electron. Such a configuration of charges seems related to, and could possibly be described as, a type of ”ionised exciton molecule”, where the ”bonding” of two negative ”nuclei” is facilitated by the presence of the hole. The CL measurements further indicate that the 2.4 eV band forms when a high enough density of, in this case, neutral acceptors are present. These neutral acceptors compete with the valence band to supply holes for recombination at the negatively charged, acceptor-type, intrinsic defects which are, in the absence of the boron, responsible for the generation of the blue, 2.9 eV band. Received: 5 December 1997 / Accepted: 13 December 1997