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1.
TiO2 quantum dots-sensitized Cu2S (Cu2S/TiO2) nanocomposites with varying concentration of TiO2 QDs are synthesized via a facile two-stage hydrothermal-wet impregnation method. X-ray diffraction analysis confirms the formation of Cu2S and TiO2with chalcocite and anatase phases, respectively. The observed shoulder-like absorption peaks indicate the UV–visible light-driven properties of the composite. Morphological analysis reveals that the fabricated Cu2S/TiO2 composite consists of Cu2S with a nano rod-like shape (average length and width of ~856 and ~213 nm, respectively) and nanosheets-like structures (average length and width of ~283 and ~289 nm, respectively), whereas the TiO2 is formed as quantum dots with a size range of 8.2 ± 0.4 nm. Chemical state analysis shows the presence of Cu+, S2?, Ni2+, and O2? in the nanocomposite. The H2 evolution rate over the optimized photocatalyst is found to be ~45.6 mmol h?1g?1cat under simulated solar irradiation, which is around 5 and 2.4-fold higher than that of the pristine TiO2 and Cu2S, respectively. Continuous H2 production for 30 h is achieved during time-on-stream experiments, demonstrating the excellent stability and durability of the Cu2S/TiO2 photocatalyst for large-scale applications.  相似文献   
2.
《Ceramics International》2022,48(9):12209-12216
We report the structural, magnetic, electrical and broadband microwave absorption in La0.7Na0.3MnO3 sample synthesized by microwave (MW) irradiation (Na0.3LMO_MW) and compare them to the sample synthesized by solid-state (SS) reaction method (Na0.3LMO_SS). Single phase Na0.3LMO_MW was synthesized at 800 °C in 30 min, whereas, Na0.3LMO_SS sample was obtained by sintering at 1200 °C for 48 h. Although both these samples show ferromagnetic transition at TC ~324.8 K, the MW-synthesized sample shows distinct physical properties: broad ferromagnetic transition, smaller saturation magnetization, a large difference between the magnetic ordering and metal-insulator transition temperatures, a large high-field magnetoresistance, a table top-like magnetocaloric effect, and a large low-field microwave absorption compared to the solid state synthesized sample. These differences are suggested to arise from magnetic heterogeneity induced by smaller grain size and surface spin disorder in the MW synthesized La0.7Na0.3MnO3.  相似文献   
3.
黏土束缚水是储层测井评价的重要内容之一。采用扩散双电层理论推导出黏土束缚水孔隙度(ϕcw)与阳离子交换量之间的理论公式,通过岩心阳离子交换实验测定ϕcw。依据核磁共振—阳离子交换联测实验,对比分析了传统3ms黏土束缚水T2截止值测定ϕcw的误差,明确了黏土束缚水T2截止值与核磁共振不同截止值计算的ϕcw之间的变化规律,建立了变黏土束缚水T2截止值计算模型,从而实现核磁共振测井精细计算ϕcw的方法并给出具体计算步骤。应用效果表明,相比传统3ms核磁共振测井计算的ϕcw,所提新方法计算结果更合理,与岩心分析结论更匹配,是黏土束缚水评价的一种有效手段。  相似文献   
4.
白酒检测技术在生产中的应用研究进展   总被引:2,自引:0,他引:2  
白酒检测是对白酒进行深层次研究的必备手段,对控制白酒质量、指导生产、维持白酒市场稳定等有着积极作用。该文总结了色谱技术、光谱技术、核磁共振技术以及仿生传感器技术在白酒检测中应用现状及研究成果,分别阐述了不同检测技术在品牌、产地、酒龄鉴别、品质监控,真伪鉴别以及风味物质测定,等级划分等方面的应用情况,并对不同检测技术的建模方法在实际应用中存在的优势与不足进行对比分析。针对目前白酒检测过程中的难点与不足,对白酒检测技术在白酒生产、质量控制、市场维护中的应用发展进行展望,可为白酒的数字化发展以及从业人员的研究工作提供参考。  相似文献   
5.
《Ceramics International》2022,48(11):14987-14992
The ceramic compound CaMoO4 is synthesized via a solid-state reaction technique. Rietveld refinement studies were done on the powder X-ray diffraction data of CaMoO4 and revealed that the compound is crystallized in the tetragonal Scheelite structure with I41/a space group. The differential scanning calorimetry (DSC) studies on CaMoO4 divulged an anomaly around 440 °C. This anomaly is further probed using the temperature-dependent Raman and dielectric spectroscopic measurements and are corroborating with the results obtained from DSC. A detailed investigation on the temperature-dependent Raman spectroscopic data revealed that the A1g mode of CaMoO4 showed a soft phonon behavior up to the phase transition temperature. It is observed that the A1g mode displayed phonon hardening behavior with further increasing the temperature. The anomaly is attributed to an isostructural phase transition (IPT), a rarely observed phenomenon in the compounds with Scheelite structure. The IPT in CaMoO4 is elucidated with a phonon softening mechanism.  相似文献   
6.
王娜  粟雯  张谛  江游  方向  岳磊 《质谱学报》2022,43(5):635-642
离子光谱结合了质谱的高灵敏度和光谱的分子结构特异性的优势,可对蛋白质、多肽、糖类、寡核苷酸等复杂体系进行结构表征和鉴定。但当存在同分异构体时,离子光谱难以从叠加的谱图中得到单个异构体的光谱信息。离子淌度质谱技术可通过区分待测离子质荷比和分子空间尺寸差异来实现异构体的分离。离子淌度可以对异构体分离后分别引入到后续的光谱和质谱分析中,减少了由异构体引起的光谱叠加问题,光谱可以进一步验证离子淌度的分离效果,因此质谱、光谱、离子淌度谱的有机结合在得到异构体精确光谱的同时,也为离子淌度质谱分析带来了新的维度和深度。本文概述了近20年来基于各类离子淌度质谱技术的光谱仪器发展和应用情况,总结目前存在的问题,并展望多维度结构质谱的新需求。  相似文献   
7.
张欣欣  李跑  余梅  蒋立文  刘霞  单杨 《食品科学》2022,43(1):260-268
柑橘是世界第一大水果,中国是柑橘生产和销售大国。现阶段我国柑橘产业存在各环节分离、加工技术粗糙、采后品质分级落后等问题,导致我国柑橘在国际市场上缺乏竞争力。对柑橘产品进行检测与分级是提高竞争力的有效手段,然而传统的柑橘品质检测手段如肉眼识别法、图像识别法、化学滴定法等存在费时费力、精度不高等缺陷,且化学滴定法等对样品具有破坏性,因此,开发快速、无损的柑橘品质检测新方法成为现阶段研究的热点和难点。近年来,基于近红外光谱技术的无损检测手段已在环境、医药、食品领域中得到了广泛应用。但是柑橘近红外光谱无损检测依旧存在机理不明、精度不够等问题,因此国内外科研工作者对其进行了大量研究。本文对国内外柑橘近红外光谱无损检测研究进行了归纳和总结,重点从近红外光谱技术检测柑橘类水果的可行性、光谱仪种类及参数的选择、化学计量学方法的优化等方面阐述了近红外光谱技术在柑橘类水果无损检测中的应用,并对其存在的问题提出了相关建议,以期为柑橘类水果无损检测提供一定的参考依据。  相似文献   
8.
Hydrogen is among a few promising energy carriers of the future mainly due to its zero-emission combustion nature. It also plays an important role in the transition from fossil fuel to renewable. Hydrogen technology is relatively immature and serious knowledge gaps do exist in its production, transport, storage, and utilization. Although the economical generation of hydrogen to the scale required for such transition is still the biggest technical and environmental challenge, unlocking the large-scale but safe storage is similarly important. It is difficult to store hydrogen in solid and liquid states and storing it in the gaseous phase requires a huge volume which is just available in subsurface porous media. Sandstone is the most abundant and favourable medium for such storage as carbonate rock might not be suitable due to potential geochemical reactions.It is well established in the literature that interaction of the host rock-fluid and injected gas plays a crucial role in fluid flow, residual trapping, withdrawal, and more generally storing capacity. Such data for the hydrogen system is extremely rare and are generally limited to contact angle measurements, while being not representative of the reality of rock-brine-hydrogen interaction(s). Therefore, we have conducted, for the first time, a series of core flooding experiments using Nuclear Magnetic Resonance (NMR) to monitor hydrogen (H2) and Nitrogen (N2) gas saturations during the drainage and imbibition stages under pressure and temperature that represent shallow reservoirs. To avoid any geochemical reaction during the test, we selected a clean sandstone core plug of 99.8% quartz (Fontainebleau with a gas porosity of 9.7% and a permeability of 190 mD).Results show significantly low initial and residual H2 saturations in comparison with N2, regardless of whether the injection flow rate or capillary number were the same or not. For instance, when the same injection flow rate was used, H2 saturation during primary drainage was 4% and it was <2% after imbibition. On other hand, N2 saturation during the primary drainage was 26% and it was 17% after imbibition. However, when the same capillary number of H2 was utilised for the N2 experiment, the N2 saturation values were ~15% for initial gas saturation and 8% for residual gas saturation. Our results promisingly support the idea of hydrogen underground storage; however, we should emphasise that more sandstone rocks of different clay mineralogy should be investigated before reaching a conclusive outcome.  相似文献   
9.
This study investigated the effect of 5 freeze–thaw cycles (freezing at −18°C for 12 h and then thawing at 4°C for approximately 12 h) on the meat quality, proximate composition, water distribution and microstructure of bovine rumen smooth muscle (BSM). As the number of freeze–thaw cycles increased, BSM pH, shear force, water content and protein content decreased by 3.06%, 35.50%, 14.49% and 21.11%, respectively, whereas BSM thawing loss, cooking loss, pressing loss, total aerobic count (TAC), ash content and fat content increased by 108.12%, 47.75%, 78.33%, 90.99%, 105% and 35.20%, respectively. The freeze–thaw cycles resulted in greater protein and lipid oxidation, as evidenced by a 36.46% reduction in the sulfhydryl content and a 209.06% and 338.46% increase in the carbonyl and malondialdehyde contents, respectively. Ice crystal formation disrupted the structural integrity of the muscle tissue. Low-field nuclear magnetic resonance results showed that the freeze–thaw cycles prolonged the relaxation times (T2b, T21 and T22), indicating that immobile water shifted to free water, and consequently, free water mobility increased. After 3 freeze–thaw cycles, the decline in shear force slowed, the increase in thawing loss became accelerated, and the TAC approached the domain value (6 log colony-forming units/g). Therefore, the number of freeze–thaw cycles of smooth muscle during transport, storage and distribution should be controlled to 3 or fewer. The current results provide a theoretical basis and data support for the further utilisation and culinary processing of smooth muscle.  相似文献   
10.
To prevent the adulteration of agricultural resources and provide a solution to enhance the green coffee bean supply chain, authentication using the near-infrared spectroscopy (NIRS) technique was investigated. Partial least square with discrimination analysis (PLS-DA) models combined with various preprocessing methods were built from NIR spectra of 153 Vietnamese green coffee samples. The model combined with the standard normal variate and the first order of derivative yielded excellent performance in predicting coffee species with the error cross-validation of 0.0261. PLS-DA model of mean centre and first-order derivative spectra also yielded good performance in verifying geographical indication of green coffee with the error of 0.0656. By contrast, the predicting abilities of post-harvest methods were poor. The overall results showed a high potential of the NIRS in online authentication practices.  相似文献   
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