全文获取类型
收费全文 | 231730篇 |
免费 | 30781篇 |
国内免费 | 24761篇 |
专业分类
电工技术 | 19628篇 |
技术理论 | 8篇 |
综合类 | 15682篇 |
化学工业 | 46270篇 |
金属工艺 | 12841篇 |
机械仪表 | 14598篇 |
建筑科学 | 9054篇 |
矿业工程 | 2725篇 |
能源动力 | 7299篇 |
轻工业 | 16760篇 |
水利工程 | 2600篇 |
石油天然气 | 4820篇 |
武器工业 | 2469篇 |
无线电 | 45157篇 |
一般工业技术 | 28962篇 |
冶金工业 | 5366篇 |
原子能技术 | 4204篇 |
自动化技术 | 48829篇 |
出版年
2024年 | 505篇 |
2023年 | 4010篇 |
2022年 | 6228篇 |
2021年 | 8358篇 |
2020年 | 8186篇 |
2019年 | 7196篇 |
2018年 | 6591篇 |
2017年 | 8883篇 |
2016年 | 9265篇 |
2015年 | 10949篇 |
2014年 | 11497篇 |
2013年 | 15128篇 |
2012年 | 17655篇 |
2011年 | 19741篇 |
2010年 | 14063篇 |
2009年 | 13937篇 |
2008年 | 15333篇 |
2007年 | 17288篇 |
2006年 | 16421篇 |
2005年 | 13915篇 |
2004年 | 11979篇 |
2003年 | 9659篇 |
2002年 | 7476篇 |
2001年 | 5760篇 |
2000年 | 4541篇 |
1999年 | 3838篇 |
1998年 | 3126篇 |
1997年 | 2585篇 |
1996年 | 2274篇 |
1995年 | 1955篇 |
1994年 | 1847篇 |
1993年 | 1415篇 |
1992年 | 1189篇 |
1991年 | 972篇 |
1990年 | 747篇 |
1989年 | 516篇 |
1988年 | 395篇 |
1987年 | 245篇 |
1986年 | 222篇 |
1985年 | 284篇 |
1984年 | 244篇 |
1983年 | 170篇 |
1982年 | 233篇 |
1981年 | 111篇 |
1980年 | 110篇 |
1979年 | 31篇 |
1978年 | 22篇 |
1977年 | 28篇 |
1976年 | 26篇 |
1959年 | 22篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
《Advanced Powder Technology》2022,33(9):103722
Through a facile hydrothermal method, we have successfully prepared Ti3C2/Bi2.15WO6 (TC/BWO) composite, and systematically investigated their reactivity for the photocatalytic reduction of Cr(VI) under visible light. X-ray diffraction and Raman analysis confirm the formation of heterostructure between Bi2.15WO6 and Ti3C2. The resultant 7TC/BWO composite exhibits enhanced photoactivity toward Cr(VI) reduction. After 120 min irradiation, the conversion of Cr(VI) reaches 92.5% with the quasi-first-order kinetic constant of k = 0.0145 min?1, which is higher than that of pure BWO (30% and k = 0.0005 min?1). The electrochemical and photoluminescent characterization confirm that the introduction of Ti3C2 is conducive to the separation of carriers, thus significantly improves the photocatalytic performance of TC/BWO. Furthermore, the radical capture experiments verify that the electrons are important for enhancing reduction of Cr(VI) to Cr(III). As a result, this research provides a comprehensive understanding of the reduction of Cr(VI) by TC/BWO composite under visible light. 相似文献
2.
3.
《International Journal of Hydrogen Energy》2022,47(85):36216-36231
The fuel cell/battery durability and hybrid system stability are major considerations for the power management of fuel cell hybrid electric bus (FCHEB) operating on complicated driving conditions. In this paper, a real time nonlinear adaptive control (NAC) with stability analyze is formulated for power management of FCHEB. Firstly, the mathematical model of hybrid power system is analyzed, which is established for control-oriented design. Furthermore, the NAC-based strategy with quadratic Lyapunov function is set up to guarantee the stability of closed-loop power system, and the power split between fuel cell and battery is controlled with the durability consideration. Finally, two real-time power management strategies, state machine control (SMC) and fuzzy logic control (FLC), are implemented to evaluate the performance of NAC-based strategy, and the simulation results suggest that the guaranteed stability of NAC-based strategy can efficiently prolong fuel cell/battery lifespan and provide better fuel consumption economy for FCHEB. 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(67):28782-28793
Highly-efficient and stable non-noble metal electrocatalysts for overcoming the sluggish kinetics of oxygen evolution reaction (OER) is urgent for water electrolysis. Biomass-derived biochar has been considered as promising carbon material because of its advantages such as low-cost, renewable, simple preparation, rich structure, and easy to obtain heteroatom by in-situ doping. Herein, Ni2P–Fe2P bimetallic phosphide spherical nanocages encapsulated in N/P-doped pine needles biochar is prepared via a simple two-step pyrolysis method. Benefiting from the maximum synergistic effects of bimetallic phosphide and biochar, high conductivity of biochar encapsulation, highly exposed active sites of Ni2P–Fe2P spherical nanocages, rapid mass transfer in porous channels with large specific surface area, and the promotion in adsorption of reaction intermediates by high-level heteroatom doping, the (Ni0.75Fe0.25)2P@NP/C demonstrates excellent OER activity with an overpotential of 250 mV and a Tafel slope of 48 mV/dec at 10 mA/cm2 in 1 M KOH. Also it exhibits a long-term durability in 10 h electrolysis and its activity even improves during the electrocatalytic process. The present work provides a favorable strategy for the inexpensive synthesis of biochar-based transition metal electrocatalysts toward OER, and improves the water electrolysis for hydrogen production. 相似文献
5.
6.
双玻光伏组件以其抗PID性强、防隐裂、防水汽透过、抗蜗牛纹、可靠性优异、轻量化等诸多优点,在晶硅太阳能组件市占比逐步提高。双玻光伏组件用背板玻璃一般需要预留出线孔,光伏背板玻璃的出线孔主要有两种打孔方式:金钢钻上下同步钻孔的模式和激光打孔。激光打孔以其易维护、可异形孔加工、效率高、生产成本低等优势得到各大玻璃厂的认可。通过分析在实际生产中激光打孔出现的打孔缺陷问题,提出了改善措施,有助于工厂的降本增效。 相似文献
7.
This work describes facile synthesis of a porous polymeric material ( T-HCP ) using readily available reagents. Specifically, T-HCP is a thermally stable and hypercrosslinked polymer (HCP) that is essentially microporous with a high BET specific surface area (940 m2 g?1). Triptycene based polymers are known to feature internal free volume. Thus, the incorporation of triptycene units and extensive crosslinking by an external cross-linker in T-HCP makes it a promising adsorbent for small gas capture applications. Experimental results show that T-HCP demonstrated good CO2 capture capacity of 132 mg g?1 (273 K, 1 bar). Molecular hydrogen storage capacity of T-HCP is estimated to be 17.7 mg g?1 (77 K, 1 bar). T-HCP revealed high CO2/N2 selectivity (up to 63) as well as promising CO2/CH4 (up to 9.1) selectivity suggesting its potential applicability for CO2 separation from flue and natural gases. 相似文献
8.
建立高效液相色谱法测定化妆品中依克多因的分析方法,采用Agilent Poroshell 120 EC-C18色谱柱(100 mm×3.0 mm,2.7μm)分离,以甲醇和p H为3.0的40 mmol/L磷酸二氢钠-10 mmol/L 1-庚烷磺酸钠缓冲溶液梯度洗脱,流速0.8 m L/min,柱温30℃,检测波长210 nm。采用外标法定量测定化妆品中的依克多因含量。结果表明,依克多因在5~800 mg/L的质量浓度范围内呈现良好线性关系,相关系数为0.999 8,方法的检出限和定量限分别为0.3和1.0 mg/L。该方法具有分离效率高、分析时间短、节省溶剂等优点,解决了依克多因在C18色谱柱上保留弱的问题。 相似文献
9.
《Ceramics International》2022,48(15):21268-21282
Mullite-Al2O3-SiC composites were in-situ synthesized through carbothermal reduction reaction of fly ash (FA) with a high alumina content and activated carbon (AC). The effects of sintering temperature, holding time, and amount of AC on the β-SiC yield, microstructure, dielectric properties, and electromagnetic (EM) absorption performance of the composites in the 2–18 GHz frequency range were studied. The results show that increasing the AC improves the porosities of the composites, with the highest porosity of 56.17% observed. The β-SiC yield varies considerably as the sintering parameters were altered, with a maximum yield of 23% achieved under conditions of 12 wt% AC, 1400 °C sintering temperature, and 3 h holding time. With a thickness of 3.5 mm, this composite has excellent EM absorption performance, exhibiting a minimum reflection loss (RLmin) of -51.55 dB at 7.60 GHz. Significantly, the maximum effective absorption bandwidth (EAB) reaches 3.39 GHz when the thickness is 3.0 mm. These results demonstrate that the composite prepared under ideal conditions can absorb 99.99% of the waves passing through it. Because of the interfacial polarization, conductive loss, and impedance matching of the heterostructure, the synthesized mullite-Al2O3-SiC composites with densities ranging from 1.43 g/cm3 to 1.62 g/cm3 demonstrate outstanding EM attenuation capabilities. Therefore, this study presents a remarkable way of utilizing fly ash to fabricate inexpensive, functional ceramic materials for EM absorption applications. 相似文献
10.
目的 了解近年来传统纺织服饰图案的研究动态及发展趋势,归纳学术研究成果并进行评价,总结研究传统服饰图案的意义和对现代设计的启示。方法 基于史论视角、社会文化视角、工艺美术视角和设计艺术视角梳理相关文献,结合现有研究分析中国传统服饰图案的资料来源及其特色、传统服饰图案的研究热点、新时代传统服饰图案的生存策略及中国传统服饰图案创新设计的应用领域。结果指出传统服饰图案的研究史料取材丰富、研究类型呈现多元;当前传统服饰图案的传承与创新体现了数字化发展、美育引导、政策支持的特点;传统服饰图案在服装设计、公共空间、文创产品中大放异彩。结论 中国传统纺织服饰图案研究多点开花,但缺乏系统整体的“中国传统纺织服饰图案知识谱系”用于指导相关研究和实践,对中国传统纺织服饰图案的研究多处于实证分析的层面且欠缺深入独到的理论,通过综述与价值阐述,提出研究的不足之处,纵深学术研究,同时为中国传统纺织服饰图案的现代设计提供新思路。 相似文献