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1.
TiO2 quantum dots-sensitized Cu2S (Cu2S/TiO2) nanocomposites with varying concentration of TiO2 QDs are synthesized via a facile two-stage hydrothermal-wet impregnation method. X-ray diffraction analysis confirms the formation of Cu2S and TiO2with chalcocite and anatase phases, respectively. The observed shoulder-like absorption peaks indicate the UV–visible light-driven properties of the composite. Morphological analysis reveals that the fabricated Cu2S/TiO2 composite consists of Cu2S with a nano rod-like shape (average length and width of ~856 and ~213 nm, respectively) and nanosheets-like structures (average length and width of ~283 and ~289 nm, respectively), whereas the TiO2 is formed as quantum dots with a size range of 8.2 ± 0.4 nm. Chemical state analysis shows the presence of Cu+, S2?, Ni2+, and O2? in the nanocomposite. The H2 evolution rate over the optimized photocatalyst is found to be ~45.6 mmol h?1g?1cat under simulated solar irradiation, which is around 5 and 2.4-fold higher than that of the pristine TiO2 and Cu2S, respectively. Continuous H2 production for 30 h is achieved during time-on-stream experiments, demonstrating the excellent stability and durability of the Cu2S/TiO2 photocatalyst for large-scale applications.  相似文献   
2.
《Ceramics International》2022,48(6):8069-8080
Homogeneous thin films of Molybdenum oxide (MoO3) were grown on quartz and glass substrates using the thermal evaporation method. XRD results showed that the MoO3 powder has a polycrystalline structure with an orthorhombic crystal system whereas the MoO3 thin films have amorphous nature. SEM images showed that the MoO3 thin films have a nearly uniform surfaces with worm-like shape grains. The film thickness influences on the linear and nonlinear optical characteristics of MoO3 thin films that were examined using spectrophotometric measurements and from which, the linear optical constants of the MoO3 thin films were estimated. The electronic transition type was determined as a direct allowed one. The values of the optical band gap were obtained to be in the range of 3.88–3.72 eV. The dispersion parameters, third-order nonlinear optical susceptibility, and the nonlinear refractive index of the MoO3 thin films were determined and interpreted in the light of the single oscillator model. The temperature dependence of the DC electrical conductivity and the corresponding conduction mechanism for the MoO3 films were investigated at temperatures ranging from 303 to 463 K.  相似文献   
3.
As a new type of material for civil engineering projects, the rubber and sand mixture is widely used in roadbed fillers, offering environmental benefits over traditional tyre disposal methods. This study uses a large-scale direct shear apparatus to examine the interface shear properties of the geogrid-reinforced rubber and sand mixture, considering different particle size ratios (r), rubber contents, and normal stresses. Based on indoor tests, direct shear models of the mixture with different values of r are established in PFC3D, revealing the meso-mechanical mechanism of the mixture in the direct shear process. The results show that when r is greater than 1, incorporating a certain amount of rubber particles can increase the shear strength of the mixture. The r values of 15.78, 7.63, and 3.98 correspond to an optimal rubber content of 30%, 10%, and 20%, respectively. When r is less than 1, mixing rubber particles can only reduce the shear strength of the mixture. When the rubber content is low, the smaller the value of r, the greater is the thickness of the shear band. Furthermore, the normal and tangential contact forces are greater. The fabric anisotropy evolution law of the mixture is consistent with the change in the contact force distribution.  相似文献   
4.
袁睿  潘中德  武会宾 《金属热处理》2021,46(10):112-116
利用扫描电镜、激光共聚焦显微镜、室温拉伸、低温冲击测试等试验方法,采用了正火、强化正火、正火+400 ℃回火的热处理工艺,研究了不同正火工艺对420 MPa级海洋风电用钢板组织和性能的影响。结果表明:通过正火处理后,正火态试验钢的平均晶粒尺寸由轧态试验钢的8 μm细化至6 μm,带状组织得到改善,强度与低温冲击性能均得到提升,屈服强度提升至442 MPa,-50 ℃下的冲击吸收能达到120 J;通过正火+400 ℃回火处理后,平均晶粒尺寸为7 μm,虽然大幅度提升了钢的低温冲击性能,-50 ℃下的冲击吸收能量达到194 J,但是钢的屈服强度降低为422 MPa。强化正火后组织为铁素体+珠光体+少量贝氏体,平均晶粒尺寸为5.6 μm,屈服强度提升至460 MPa,断后伸长率和低温冲击吸收能量相较于正火后试验钢有所降低但仍能满足EN10025性能标准,达到强韧性的最佳匹配,是生产420 MPa级海上风电用钢的最佳热处理工艺。  相似文献   
5.
漏磁检测广泛应用于铁磁性材料设备的在线检测当中,是一种有效的缺陷检测方法。如何利用缺陷漏磁信号进行三维不规则缺陷轮廓重构是漏磁检测中的关键问题。然而,三维不规则缺陷漏磁检测的有限元模型计算量大,因此难以快速获得精确的漏磁信号,并且由于缺陷重构的不适定性,研究中不容易获得不规则缺陷的精确轮廓。本文提出了一种用于计算三维不规则缺陷漏磁信号的单元磁偶极带叠加模型,并验证了使用该正演模型进行漏磁计算的有效性,针对三维缺陷轮廓重构的高维优化问题,提出了一种带边界约束的基于信赖域的投影Levenberg-Marquart算法,实现了三维不规则缺陷轮廓的重构。实验结果表明:该三维不规则缺陷重构方法不仅不需要大量的漏磁检测数据,并且相对于群智能算法,重构误差降低了90.1%,最大深度误差降低了53.9%,耗费时间减少了96.1%,实现了高精度的缺陷重构。  相似文献   
6.
通过溶剂热法制备BiOCl纳米片,共沉淀法制备Ag_2CO_3和复合催化剂Ag_2CO_3/BiOCl,研究各材料可见光催化降解罗丹明B的效果,确定Ag_2CO_3与BiOCl的最佳配比,并通过表征分析复合材料的结构和异质结光催化降解机理。结果表明,当Ag_2CO_3与BiOCl的质量比为50%时,Ag_2CO_3/BiOCl异质结催化剂的可见光催化效率最高,其一级动力学反应速率常数是BiOCl和Ag_2CO_3的6.79和12.58倍。紫外可见漫反射分析证明,Ag_2CO_3的加入使Ag_2CO_3/BiOCl对可见光的吸收增加,拓宽了光响应范围。XPS价带谱证明,调控后的BiOCl纳米片能带位置上移。通过自由基捕获实验和电子顺磁共振(ESR)证明,其主要活性物种是·O~-_2、h~+和·OH,从而推断Ag_2CO_3与BiOCl构成Z型异质结,相比Ⅱ型异质结拥有较高的氧化还原能力,可充分利用水中的溶解氧(O_2)和OH~-,大大提升了光催化效率。  相似文献   
7.
Undoped and Er3+-doped Bi2O3 thin films were sputter-deposited on Si(100) substrates. Sufficiently oxidized Bi2O3 films with refractive indices between 2.17?2.23 were obtained at a wavelength of 633 nm; these values are comparable to those of bulk Bi2O3 crystals. While the film composition was stable for deposition temperatures between room temperature (RT) and 450 °C, the refractive index steeply decreased above 450 °C and reached 1.4 at 600 °C. The lowering of the optical transmittance spectra indicated aggregation of metallic Bi and darkening of the film. All films exhibited X-ray diffraction patterns of α-Bi2O3. The direct and indirect bandgap energies derived from the Tauc plots were 3.4–3.7 eV and 1.9–2.5 eV, respectively, depending on the O2 flow rate and deposition temperature. Upon excitation of Er3+-doped Bi2O3 films at 532 nm, Er3+ emissions peaking at 1537 and 1541 nm appeared, and the photoluminescence spectra included fine structures reflecting crystal-field splitting. Resonant excitation of Er3+ 4f levels and indirect excitation via the defect levels of Bi2O3 followed by energy transfer to Er3+ contributed to the emission. The films deposited at RT with Er concentrations of 2 at.% had the emission intensity of Er3+, but concentration quenching strongly suppressed the Er3+ emission because the doped Er3+ ions stayed inside the Bi2O3 crystals. At deposition temperatures above 400 °C, the concentration quenching was mitigated possibly because out-diffusion of Er3+ ions reduced the effective number of Er3+ ions in the Bi2O3 crystalline domains.  相似文献   
8.
《Ceramics International》2022,48(8):10592-10600
Zinc oxide is widely used in gas sensors, solar cells, and photocatalysts because of its wide bandgap and exciton binding energy of 60 meV in various metal oxides. To use ZnO as a gas sensor, it is necessary to synthesize it with surface defects and a large specific surface area. In this study, hydrothermal synthesis without surfactants was employed to obtain organic-additive-free ZnO. For morphology control, we varied the ratio of the hydroxide ion concentration to the zinc ion concentration. To confirm the growth mechanism of ZnO, we performed X-ray diffraction, scanning electron microscopy, and transmission electron microscopy analyses. Raman spectroscopy and photoluminescence measurements were performed to analyze the surface properties. The Brunauer–Emmett–Teller method and probe stations were used to measure the specific surface area and sensitivity of the gas sensor, respectively. The results confirmed that flower-shaped ZnO is the most suitable gas-sensing material.  相似文献   
9.
鉴于金属光子晶体结构在滤波、极化、传感、成像等领域的重要作用,研究了基于三角形晶格的金属光子晶体的超常透射、光子能带和表面波特性。采用三维时域有限差分法对金属光子晶体结构建模,同时解释超常透射机理;推导和讨论光子能带沿着ΓK和ΓM晶格方向的能带图,分析不同的表面波特征,并解释非对称入射下观察到的三角形的两个晶格方向模式分裂效应;建立了描述这种模式分裂效应的精确的表面模式谐振频率公式,并对金属光子晶体的色散进行了定量分析。研究结果可为太赫兹功能器件的研究提供参考。  相似文献   
10.
利用液晶可调谐滤波器(LCTF)和CMOS相机组合的多光谱成像系统,在波长400~720nm内以5nm为间隔对莲花白叶片进行多光谱成像。首先根据图像亮度信息法的原理,计算得到各波段莲花白叶片的可识别度;然后对莲花白叶片的可识别度进行大小排序,综合图像的信息特征和可识别度,得出555nm、715nm、710nm、575nm、535nm、520nm、720nm、605nm和650nm 9个波段有较好的识别度;最后根据欧氏距离法和光谱角度匹配法分别对莲花白叶片的特征波段的分类精度予以统计,得到两种方法的分类精度分别为95.56%和93.13%。实验证明,选取的9个波段对莲花白叶片具有较好的分类精度,可作为莲花白叶片的特征波段。  相似文献   
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