全文获取类型
收费全文 | 52347篇 |
免费 | 3875篇 |
国内免费 | 2926篇 |
专业分类
电工技术 | 1742篇 |
综合类 | 2301篇 |
化学工业 | 14993篇 |
金属工艺 | 5002篇 |
机械仪表 | 2050篇 |
建筑科学 | 623篇 |
矿业工程 | 1010篇 |
能源动力 | 4830篇 |
轻工业 | 2260篇 |
水利工程 | 119篇 |
石油天然气 | 1181篇 |
武器工业 | 157篇 |
无线电 | 6135篇 |
一般工业技术 | 11815篇 |
冶金工业 | 3116篇 |
原子能技术 | 709篇 |
自动化技术 | 1105篇 |
出版年
2024年 | 39篇 |
2023年 | 934篇 |
2022年 | 1231篇 |
2021年 | 1761篇 |
2020年 | 1742篇 |
2019年 | 1606篇 |
2018年 | 1490篇 |
2017年 | 1809篇 |
2016年 | 1565篇 |
2015年 | 1569篇 |
2014年 | 2414篇 |
2013年 | 2912篇 |
2012年 | 3258篇 |
2011年 | 4284篇 |
2010年 | 3153篇 |
2009年 | 3187篇 |
2008年 | 2777篇 |
2007年 | 3356篇 |
2006年 | 3036篇 |
2005年 | 2490篇 |
2004年 | 2211篇 |
2003年 | 1979篇 |
2002年 | 1624篇 |
2001年 | 1452篇 |
2000年 | 1285篇 |
1999年 | 1009篇 |
1998年 | 883篇 |
1997年 | 683篇 |
1996年 | 634篇 |
1995年 | 532篇 |
1994年 | 493篇 |
1993年 | 385篇 |
1992年 | 332篇 |
1991年 | 243篇 |
1990年 | 193篇 |
1989年 | 156篇 |
1988年 | 107篇 |
1987年 | 66篇 |
1986年 | 31篇 |
1985年 | 43篇 |
1984年 | 38篇 |
1983年 | 24篇 |
1982年 | 39篇 |
1981年 | 23篇 |
1980年 | 16篇 |
1979年 | 15篇 |
1978年 | 5篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1959年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 16 毫秒
1.
静压气悬浮轴的悬浮技术,是利用多孔质材料做成的轴承,对高压气体节流降压,在轴承和轴之间形成一层薄的气膜,使轴悬浮,实现轴的无接触式工作,从而达到降低摩擦提高工作效率的目的。本论文基于的50冷吨的气悬浮离心制冷机组,名义工况的制冷量为170 kW,制冷能效5.6,IPLV值7.3,通过对该系统及测试数据进行分析,用理论计算制热量和实测制热量之间的差值,得出从100%负荷到25%负荷工况,悬浮轴的供气量的流量,大约在6 g/s~9 g/s,占系统制冷剂循环量的0.82%~2.2%。 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(95):40407-40414
The present work addresses the potentialities of Pt–Ru nanoparticles deposited on a graphene oxide (RGO) and TiO2 composite support towards electrochemical oxidation of ethanol in acidic media relevant for fuel cell applications. To immobilize platinum–ruthenium bimetallic nanoparticles on to an RGO-TiO2 nanohybrid support a simple solution-phase chemical reduction method is utilized. An examination using electron microscopy and energy dispersive X-ray spectroscopy (EDS) indicated that Pt–Ru particles of 4–8 nm in diameter are dispersed on RGO-TiO2 composite support. The corresponding Pt–Ru/RGO-TiO2 nanocomposite electrocatalyst was studied for the electrochemical oxidation of ethanol in acidic media. Compared to the commercial Pt–Ru/C and Pt/C catalysts, Pt–Ru/RGO-TiO2 nanocomposite yields higher mass-specific activity of about 1.4 and 3.2 times, respectively towards ethanol oxidation reaction (EOR). The synergistic boosting provided by RGO-TiO2 composite support and Pt–Ru ensemble together contributed to the observed higher EOR activity and stability to Pt–Ru/RGO-TiO2 nanocomposite compared with other in-house synthesized Pt–Ru/RGO, Pt/RGO and commercial Pt–Ru/C and Pt/C electrocatalysts. Further optimization of RGO-TiO2 composite support provides opportunity to deposit many other types of metallic nanoparticles onto it for fuel cell electrocatalysis applications. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(87):36926-36952
The ohmic resistance in solid oxide fuel cells (SOFCs) mainly comes from the electrolyte, which can be reduced by developing novel electrolyte materials with higher ionic conductivity and/or fabricating thin-film electrolytes. Among various kinds of thin-film fabrication technology, the physical vapor deposition (PVD) method can reduce the electrolyte thickness to a few micrometers and mitigate the issues associated with high-temperature sintering, which is necessary for wet ceramic methods. This review summarizes recent development progress in thin-film electrolytes fabricated by the PVD method, especially pulsed laser deposition (PLD) and magnetron sputtering. At first, the importance of the substrate surface morphology for the quality of the film is emphasized. After that, the fabrication of thin-film doped-zirconia and doped-ceria electrolytes is presented, then we provide a brief summary of the works on other types of electrolytes prepared by PVD. Finally, we have come to the summary and made perspectives. 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(63):27279-27292
This study assesses a sustainable solution to greenhouse gases (GHGs) mitigation using constructed wetland-microbial fuel cells (CW-MFC). Roots of wetland plant Acorus Calamus L. are placed in biological anode to better enable anode microorganisms to obtain rhizosphere secretion for power improvement. Three selected cathode materials have a large difference in GHG emissions, and among them, carbon fiber felt (CFF) shows the lowest emissions of methane and nitrous oxide, which are 0.77 ± 0.04 mg/(m2·h) and 130.78 ± 13.08 μg/(m2·h), respectively. The CFF CW-MFC achieves the maximum power density of 2.99 W/m3. As the influent pH value is adjusted from acidic to alkaline, the GHGs emissions are reduced. The addition of Ni inhibits GHGs emission but decreases the electricity, the power density is reduced to 1.09 W/m3, and the methane and nitrous oxide emission fluxes decline to 0.20 ± 0.04 mg/(m2·h) and 15.49 ± 1.86 μg/(m2·h), respectively. Low C/N ratio reduces methane emission, while high C/N ratio effectively inhibits nitrous oxide emission. At the influent pH 8 and C/N = 5:1, the methane emission flux is approximately 10.60 ± 0.27 mg/(m2·h), and the nitrous oxide emission flux is only 10.90 ± 1.10 μg/(m2·h). Based on the above experimental results by controlling variable factors, it is proposed that CW-MFC offers an environment-friendly solution to regulate GHG emissions. 相似文献
5.
超临界机组高温合金管氧化膜剥落问题是困扰机组安全与经济运行的难题,严重制约了机组蒸汽参数和效率的提高。特别是,在超临界机组采用给水加氧处理方式(OT)后,奥氏体不锈钢管内壁氧化膜大面积剥落事故屡见不鲜,尤以TP347H合金管为甚。本文总结了近年来国内外针对超临界机组合金管氧化膜研究的进展及相关成果,首先介绍了超临界蒸汽环境中合金管氧化机理和原子迁移机制,综述了铁素体和奥氏体合金表面氧化膜的形貌特征,分析了蒸汽溶氧对氧化膜生长速率、形貌和缺陷的影响。氧化膜完整性是决定合金抗腐蚀性能的重要因素,但在机组运行过程中氧化膜应力破坏了氧化膜完整性。进一步总结了国内外氧化膜应力和剥落研究的数值分析及实验研究情况,为我国超临界机组氧化膜剥落故障诊断研究提供参考。 相似文献
6.
7.
层状氧化物正极材料具有良好的结构稳定性和较高的充放电比容量,是一类理想的钠离子电池正极材料。本工作研究了层状氧化物正极材料NaNi1/3Fe1/3Mn1/3O2表面修饰对其电化学性能的影响,采用固相球磨法在正极材料表面包覆一层纳米ZrO2,采用形貌、结构、电化学方法等研究了包覆后性能改进机理。研究结果表明,ZrO2在NaNi1/3Fe1/3Mn1/3O2表面形成一层惰性保护层,有效隔开了电解液与正极材料的接触,缓解了电解液的分解速度,抑制了金属离子的溶出速度,从而显著改善了电池的循环性能以及高温性能。在ZrO2包覆修饰后,55℃下正极材料相比于未包覆的正极材料有明显提升,100次循环后容量保持率达到83.6%,高于未包覆的75.2%。此外,包覆后的NaNi1/3Fe1/3Mn1/3O2正极材料在空气环境存储后,稳定性得到明显提高。 相似文献
8.
采用磁控溅射法制备出以ITO为基底的纯Cu薄膜,考察溅射时间和基底温度等工艺条件对生长Cu薄膜的影响。用电子扫描显微镜(SEM)、X射线衍射仪(XRD)对薄膜的形貌、厚度和结构进行表征。实验结果表明:在一定范围内调控衬底温度和溅射时间,可获得不同形貌、尺寸和厚度的Cu薄膜,所得薄膜的晶体结构为面心立方结构,均沿(111)方向择优生长。时间是控制晶粒尺寸的重要因素,溅射时间为40 min,所得薄膜粒子较小,结晶度好,且薄膜致密均匀,随着镀膜时间的增加,膜厚与之成线性关系增加,沉积速率为0.242μm/min;温度对薄膜形貌影响显著,100℃时可获得由小粒子堆积成的类柱状结构组成的薄膜,200℃时可获得由小粒子堆积成的球形团簇组成的薄膜,随着镀膜温度的增加,膜厚与之不呈线性关系,沉积速率随温度的增加而增大;该方法所制备铜薄膜在催化、传感器等领域有潜在的应用价值。 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(11):7403-7414
BaCe0.7Zr0.1Y0.2O3-δ (BCZY) is one of the promising electrolytic candidate for solid oxide fuel cell (SOFC) due to its good proton conductivity and better stability. Herein, the effect of dual sintering aids such as CuO-Bi2O3 upon the sinterability at low temperature, improved electrochemical properties, and thermo-chemical changes about proton-conducting BaCe0.7Zr0.1Y0.2O3-δ electrolyte were investigated in detail. FESEM micrographs and shrinkage curves revealed significant improvement in sinterability and densifications of BCZY electrolyte. The dense pellets were sintered with CuO-Bi2O3 (2–3 mol %) as sintering aids at a temperature of 1150 °C for 5 h. The perfectly uniform distribution of sintering aids increased the linear shrinkage of BCZY from 5% till 19–21%. The crystallite size and grain growth within the structure was enhanced due to the formation of the melting phase of Bi2O3 and Cu2+ incorporation in the perovskite structure. The elevated and improved electrochemical measurement for BCZY with 2 mol% of CuO-Bi2O3 as sintering aid categorized it well suited for solid oxide fuel cells. 相似文献
10.
《International Journal of Hydrogen Energy》2022,47(66):28645-28654
The introduction of catalyst on anode of solid oxide fuel cell (SOFC) has been an effective way to alleviate the carbon deposition when utilizing biogas as the fuel. A series of La0.6Sr0.4Co1-xNixO3-δ (x = 0, 0.2, 0.4, 0.6, 0.8) oxides are synthesized by sol-gel method and used as catalysts precursors for biogas dry reforming. The phase structure of La0.6Sr0.4Co1-xNixO3-δ oxides before and after reduction are characterized by X-ray diffraction (XRD). The texture properties, carbon deposition, CH4 and CO2 conversion rate of La0.6Sr0.4Co1-xNixO3-δ catalysts are evaluated and compared. The peak power density of 739 mW cm?2 is obtained by a commercial SOFC with La0.6Sr0.4Co0.4Ni0.6O3-δ catalyst at 850 °C when using a mixture of CH4: CO2 = 2:1 as fuel. This shows a great improvement from the cell without catalyst for internal dry reforming, which is attributed to the formation of NiCo alloy active species after reduction in H2 atmosphere. The results indicate the benefits of inhibiting the carbon deposition on Ni-based anode through introducing the La0.6Sr0.4Co0.4Ni0.6O3-δ catalyst precursor. Additionally, the dry reforming technology will also help to convert part of the exhaust heat into chemical energy and improve the efficiency of SOFC system with biogas fuel. 相似文献