Eu3+掺杂Na2La2Ti3O10红色荧光粉的光谱性质

采用传统高温固相法制备了不同Eu³⁺浓 度掺杂的Na₂(La1－xEux) ₂Ti₃O10荧光粉,研究了Eu³⁺浓度 对样品结构及发光性质的影响。X射线衍射(XRD)结果表明Eu³⁺掺杂浓度不大于40%的 样品为四方相Na₂La₂Ti₃O10;当 Eu³⁺浓度达到60%时,出现了正交相NaEuTiO₄。对样品进行 激发、发射光谱的 测试发现,样品可被较 宽波段的紫外光有效激发,获得明亮的红橙色光发射,且Na₂La₂Ti₃O₁₀到Eu 3+存在有效的能量传递。利用 Van模型,证实了Eu³⁺间的交换相互作用是引发浓度猝灭的主要原因。利用Auzel模型 ,解释了Eu³⁺发光的自猝 灭行为。测试了样品在不同温度下的发射光谱和时间衰减曲线,确定样品发光产生 温度猝灭的主 要机理是Crossover过程。利用Arrhenius公式对实验数据进行拟合,确定激活能值约为0.26eV,说明Na₂(La1－xEux)₂Ti₃O₁₀荧光粉具有较好的发光热稳定性。     

Composition-dependent optical transitions and 2.0 μm emission properties of Ho~(3+) in xGeO_2-(80-x)TeO_2-9.5ZnF_2-10NaF-0.5Ho_2O_3 glasses

Ho3+ doped glasses with various compositions xGeO2-(80-x)TeO2-9.5ZnF2-10NaF-0.5Ho2O3(x=0,10,20,30,40,50,60,70 and80) were prepared by a melt-quenching technique.The composition-dependent optical transition properties of Ho3+ were investigated in theframework of Judd-Ofelt theory.The emission cross sections for 5I7→5I8 transition of Ho3+ in these glasses were calculated according toMcCumber theory,and their compositional dependence was discussed.A simple method was proposed in calculating the emission cross ...     

基于计算机视觉的肉色量化研究

猪肉的颜色是判断其食用安全性非常重要的指标。肉的变质程度与颜色的变化呈现密切的关系。目前,肉色的分级判断通常是在自然光下,依据标准肉色等级图,靠人眼观察进行对比感官评定,这种主观评价方法存在着一定的人为误差,难免使判定结果不够客观和准确。因此,采用先进的方法、技术和仪器,通过对食用肉的颜色和颜色变化进行定量化测定和计算,可以获得客观评价。依据颜色理论,建立了一套用于猪肉颜色量化的计算机视觉系统,光源选择CIE推荐的标准照明体A,该系统能对猪肉的颜色、色差进行采集、处理、显示和评价,此方法具有操作简单、无损伤、测试速度快和费用低等特点,摆脱了颜色检测的主观性和模糊性,实现了蔬菜颜色评定和控制的客观化和定量化。     

纳米Y2O3:Eu3+的内量子效率和表面钝化效应

采用化学自燃烧方法制备了Eu3 掺杂的Y2O3纳米晶粉末材料,并在制备过程中引入了少量的Ag 离子.计算了Eu3 的5D0能级的发光的内量子效率,发现Ag 离子的加入可以使发光的量子效率最大增加12%.通过发射光谱的测量发现荧光最大可增强约50%,通过X射线衍射(XRD)、透射电子显微镜(TEM)、荧光激发和发射光谱研究证实Ag 离子的引入产生两个方面的作用:(1)是能够部分地消除表面的无辐射中心,使量子效率提高,发光增强;(2)是使激发光能够更有效地到达发光中心,提高激发效率,从而使荧光产额提高.     

Flux and concentration effect on Eu^3＋ doped Gd2（MoO4）3 phosphor

A novel red emitting phosphor Gd2（MoO4）3：Eu^3＋ was prepared by solid reaction, using Gd2O3, Eu2O3 and WO3 as starting matedals and NH4F as flux. The effects of flux content and Eu^3＋ concentration on the crystal structure, morphology and luminescent properties were investigated using XRD, SEM and fluorescent spectrum measurement. The XRD patterns showed that the resultants had the monoclinic structure. With the increase in flux amount, their crystallization significantly improved. The SEM images indicated that the mean size of the phosphor particles was around 2 μm, and agglomeration of the phosphor particles appeared while introducing higher flux amount. The excitation spectra exhibited more intense f-f transitions originating from ground state 7^F0 to upper states 5^L6 and 5^D2 than the charge transfer band. The concentration quenching of Eu^3＋ emission indicated that energy transfer from Eu^3＋ to molybdate host existed even at lower Eu^3＋ concentration.     

Er~(3+)离子掺杂浓度对碲酸盐玻璃光学跃迁及上转换发光性质的影响

采用高温熔融淬火法制备了Er3+掺杂碲酸盐玻璃。测量了不同Er3+浓度掺杂的碲酸盐玻璃的吸收光谱,应用Judd-Ofelt理论计算了J-O参数Ωλ(λ=2,4,6),讨论了Er3+离子浓度对碲酸盐玻璃性质的影响。在980 nm激发下,测量了样品的上转换荧光发射谱,在室温下观察到绿光(525 nm)和红光(655 nm)发射,其分别对应于Er3+的2H11/2→4I15/2和4F9/2→4I15/2跃迁到Er3+/Yb3+,通过分析变激光功率激发下上转换发光光谱强度的变化,得到绿光和红光发射都是双光子过程。此外,还研究了样品的浓度猝灭机制,给出了交叉弛豫的路径。