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1.
《International Journal of Hydrogen Energy》2022,47(95):40379-40390
TiO2 quantum dots-sensitized Cu2S (Cu2S/TiO2) nanocomposites with varying concentration of TiO2 QDs are synthesized via a facile two-stage hydrothermal-wet impregnation method. X-ray diffraction analysis confirms the formation of Cu2S and TiO2with chalcocite and anatase phases, respectively. The observed shoulder-like absorption peaks indicate the UV–visible light-driven properties of the composite. Morphological analysis reveals that the fabricated Cu2S/TiO2 composite consists of Cu2S with a nano rod-like shape (average length and width of ~856 and ~213 nm, respectively) and nanosheets-like structures (average length and width of ~283 and ~289 nm, respectively), whereas the TiO2 is formed as quantum dots with a size range of 8.2 ± 0.4 nm. Chemical state analysis shows the presence of Cu+, S2?, Ni2+, and O2? in the nanocomposite. The H2 evolution rate over the optimized photocatalyst is found to be ~45.6 mmol h?1g?1cat under simulated solar irradiation, which is around 5 and 2.4-fold higher than that of the pristine TiO2 and Cu2S, respectively. Continuous H2 production for 30 h is achieved during time-on-stream experiments, demonstrating the excellent stability and durability of the Cu2S/TiO2 photocatalyst for large-scale applications. 相似文献
2.
渤中13-2大型潜山地区是渤海海域发现的首个亿吨级深层变质岩潜山油藏。通过已钻井的岩心、薄片、测试、测井等资料,从构造演化、成岩作用、古地貌特征等方面,阐述了研究区潜山储集空间类型、裂缝发育主控因素及分布规律,为研究区的高效开发奠定基础。研究结果表明:①多期次构造运动是导致裂缝形成的主控因素,风化淋滤和裂缝充填是造成储层纵向差异的主要原因。②利用结构张量场与绕射波耦合属性可以有效指导研究区储层平面预测,根据最大似然属性体能够较好地预测潜山裂缝走向。③平面上靠近大断层附近裂缝发育较好,纵向上风化带裂缝好于内幕带裂缝,渤中13-2地区主力层段风化带储层可划分为4类,Ⅰ类储层最好,主要位于构造高部位;Ⅱ类储层次之,主要位于构造腰部; Ⅲ类储层较差,主要位于距离断层较近区域的构造翼部; Ⅳ类储层最差,主要位于距离大断层较远处。 相似文献
3.
《Ceramics International》2022,48(3):3362-3367
The influence of high-energy ball milling on structural, microstructural, and optical properties of TiO2 by modifying the nanoparticle size was studied. Five samples were extracted at different milling times (0, 2, 4, 8, and 13 h). The average particle sizes estimated by dynamic light scattering (DLS) were 205, 155.8, 116.8, 82.9, and 82.7 nm at 0, 2, 4, 8, and 13 h, respectively. X-ray diffraction analysis confirmed progressive broadening of the peaks as the milling time elapsed. Besides, a correlation was found between d spacing and the average crystal size. The UV–Vis diffuse reflectance spectra of TiO2 revealed a decrease in reflectance due to particle size reduction. Similarly, an alteration of the bandgap transition energy was presented, whose values gradually decreased from 2.966 eV to 2.861 eV for the sample without and with the maximum duration milling performed (13 h), respectively. Likewise, the SEM analysis showed a distribution in nanoparticle size that became more homogeneous and smaller average grain size as the milling duration was longer. 相似文献
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为了探究GH4169合金低周疲劳试样加工过程中表面残余应力的变化及残余应力对低周疲劳性能的影响,采用X射线衍射法对“车 磨 抛”不同加工工艺的试样表面残余应力进行表征及对成品试样进行残余应力层深度测试,通过中子衍射法对试样内部进行残余应力测试。采用电液伺服万能试验机进行了低周疲劳试验。结果表明:GH4169合金低周疲劳试样加工表面残余应力随着切削量的增加由表面残余压应力变为残余拉应力。根据残余应力层深度测试,机加工对试样表面造成残余应力层深度小于0.01 mm,内部残余拉应力减小;根据疲劳试验结果,GH4169合金疲劳寿命与表面轴向残余压应力呈正相关关系。 相似文献
7.
为加深对四烷基-3-氧杂-戊二酰胺(TRDGA)类配体与三价锕/镧离子配位的认识,利用光谱及单晶X射线衍射分析技术,分别在含水辛醇溶液、水溶液、晶体及液-液萃取体系中对比研究了脂溶性N,N′-二甲基-N,N′-二辛基-3-氧杂-戊二酰胺(DMDODGA,L)以及水溶性四甲基-3-氧杂-戊二酰胺(TMDGA,L′)与Pr(Ⅲ)的配位。光谱滴定实验结果表明,两配体在溶液中均可与Pr(Ⅲ)形成金属离子与配体比值为1∶1、1∶2及1∶3的配合物,并获得了配合物稳定常数及标准吸收光谱。配合物中金属离子与配体比值相同时,L和L′与Pr(Ⅲ)形成的每对配合物中Pr(Ⅲ)特征吸收峰的位置及形状均几乎完全相同,说明每对配合物的内配位层结构相同或相近。PrL′3(ClO4)3晶体漫反射光谱与PrL3+3及PrL′3+3标准吸收光谱的特征也相同,说明1∶3配合物均为三帽三棱柱配位构型。与加入硝酸根的光谱滴定实验相结合,通过有机相吸收光谱与已知固体/溶液配合物的漫反射/吸收光谱对比,确定了液-液萃取萃合物中,Pr(Ⅲ)至少有PrL2(NO3)(H2O)2+和PrL3+3 2种化学形态。 相似文献
8.
《Ceramics International》2022,48(2):1765-1770
Perovskite lattice was tailored by introducing site vacancies and mixed anion composition, to produce Sr0.83Li0.17Ta0.83O1.88N0.74 (Li02N). Further, Li02N was converted to a defect oxide Sr0.83Li0.17Ta0.83O3 (Li02O) by applying an optimized treatment: heating in air at 1173 K for 2 h. According to the neutron Rietveld refinement, Li02N and Li02O are tetragonal and orthorhombic, respectively, where the lattice volume of Li02O is significantly smaller than that of Li02N. The ionic conductivity (σion) of Li02N and Li02O was evaluated by the ac impedance spectroscopy and the equivalent circuit analysis. Both Li02N (σion = 10?5.5 S/cm at 671 K) and Li02O (σion = 10?6.2 S/cm at 667 K) exhibited an Arrhenius behavior of ionic conductivity with activation energies of 0.87 eV and 0.75 eV, respectively. It is interpreted that the nitride component enhances the ionic conduction of Li02N, while the vacancy of the anion lattice makes an opposite effect. 相似文献
9.
《Ceramics International》2021,47(22):31920-31926
The Sr and Ba bearing Tl-1212 phase, Tl(Ba,Sr)CaCu2O7 is an interesting superconductor. The Sr only bearing TlSr2CaCu2O7 is not easily prepared in the superconducting form. The Ba only bearing TlBa2CaCu2O7 on the other hand does not show improvement in the transition temperature with elemental substitution. In this work the influence of multivalent Se (non-metal) and Te (metalloid) substitutions at the Tl-site of Tl1-xMx(Ba,Sr)CaCu2O7 (M = Se or Te) superconductors for x = 0–0.6 was studied. The samples were prepared via the conventional solid-state reaction method. XRD patterns showed a single Tl-1212 phase for x = 0 and 0.1 Se substituted samples. The critical current density at the peak temperature, Tp of the imaginary (χ”) part of the AC susceptibility (χ = χ’ +χ”), Jc-inter(Tp) for all samples was between 15 and 21 A cm−2. The highest superconducting transition temperature was shown by the x = 0.3 Se-substituted sample (Tc-onset = 104 K, Tc-zero = 89 K, Tcχ’ = 104 K and Tp = 80 K). Te suppressed the superconductivity of Tl-1212 phase. The order of highest transition temperatures are as follows: Tl1-xTex(Ba,Sr)CaCu2O7<Tl(Ba,Sr)CaCu2O7<Tl1-xSex(Ba,Sr)CaCu2O7. This work showed that Se was better than Te in improving the transition temperature and flux pinning of the Tl-1212 phase. The roles of ionic radius of Se and Te on the superconductivity of Tl(Ba,Sr)CaCu2O7 are discussed in this paper. 相似文献
10.