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排序方式: 共有1298条查询结果,搜索用时 15 毫秒
1.
Studies on Catalytic Side-Chain Oxidation of Nitroaromatics to Aldehydes with Oxygen 总被引:2,自引:0,他引:2
The side-chain oxidation of 2-nitrotoluene in liquid phase in the presence of catalytic amount of manganese sulfate and stoichiometric amount of potassium hydroxide with oxygen was studied. In the most favorable conditions, over 80% of conversion of 2-nitrotoluene and 50% of selectivity to 2-nitrobenzaldehyde was achieved. Effects of the reaction parameters on the conversion of the reactant and the selectivity of the product were examined. These results, together with EPR spectroscopic study, show that a benzyl anion was formed in the early stage of the reaction, which was then converted to the final product via a free radical mechanism. 相似文献
2.
从理论上分析了液碱对阴树脂再生度的影响。通过两种不同纯度的液碱再生阴树脂的实际运行经济指标统计分析,说明用高纯度液碱再生阴树脂,可提高树脂的工作交换容量和周期制水量,有很好的经济效益。 相似文献
3.
Anion exchange membranes (AEMs) are one of the core components of AEM fuel cells. A series of poly(vinyl alcohol)/polyquaternium-10 (PVA/PQ-10) AEMs with semi-interpenetrating networks (s-IPNs) are prepared by a simple solution-casting method using glutaraldehyde (GA) as a cross-linking agent. Subsequently, the prepared PVA/PQ-10 cross-linked membranes are characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, mechanical analysis, water uptake and swelling ratio tests, ion exchange capacity (IEC) tests, ionic conductivity measurements, and oxidative/alkaline stability tests. The effects of the mass ratio of PVA and PQ-10 and the amount of cross-linking agent GA on the performance of the PVA/PQ-10 cross-linked membranes are systematically explored. The results show that the cross-linked PVA/PQ-10 AEMs have high IEC and low water uptake and swelling ratio, and its maximum ionic conductivity can reach 79.37 mS cm–1 at 80 °C. In addition, the PVA/PQ-10 cross-linked membrane has good oxidative and alkaline stability under optimal preparation conditions. These results may provide valuable insights toward more effective scheme designs and new, simple preparation methods for AEMs with s-IPN structures. 相似文献
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6.
D301树脂分离衣康酸的工艺研究 总被引:1,自引:0,他引:1
采用弱碱性阴离子交换树脂D301对发酵法生产的衣康酸进行了分离研究。通过静态交换实验,研究了D301树脂对衣康酸的静态交换动力学,确定了传质机制和影响因素;通过动态交换实验,研究了以硫酸为洗脱剂,以氨水为再生剂的工艺过程,确定了主要工艺参数。 相似文献
7.
扩散渗析法从钛白废酸中回收硫酸 总被引:20,自引:0,他引:20
针对钛白废酸的回收,在静态扩散条件下测定了硫酸、硫酸亚铁在阴离子交换膜中的渗析系数以考察膜的分离性能。进一步考察动态扩散操作参数如流量、流量比、停留时间等对回收率及回收酸浓度的影响。研究表明,使用的阴离子交换膜具有良好的分离性能,酸盐分离系数达23.6,在水酸流量比维持在1~1.1,废酸流量维持在0.6L·h-1左右的条件下,硫酸回收率大于85%,硫酸亚铁透过率小于7%。 相似文献
8.
Organic–inorganic hybrid materials and mem branes were prepared through coating on Teflon plate or dip‐coating on microporous alumina substrates with the solution of glycidylmethacrylate (GMA) and γ‐methacryloxypropyl trimethoxy silane (γ‐MPS) copolymer, followed by ring‐opening of the GMA moiety with trimethylamine hydrochloric and sol–gel reaction of the γ‐MPS moiety. Composition of the GMA and γ‐MPS copolymer was varied by changing the feed ratio of GMA to γ‐MPS during the copolymerization. So the thermal stability, hydrophilicity, electrical properties, etc. of the hybrid materials and membranes were varied. Results showed that as the γ‐MPS amount increased in the copolymer, Td (the temperature on thermogram at 5% weight loss) value of the hybrid materials and water contact angle of the hybrid membrane generally increased, while the anion exchange capacity, water uptake (WR) and pure water flux decreased. The charge transition point of the hybrid membranes deduced from their streaming potential behavior decreased from pH > 12 to pH = 7–8 as the γ‐MPS amount increased. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3580–3589, 2006 相似文献
9.
由于聚合物受热易燃烧,常存在火灾风险,通常需要引入阻燃剂来提升其阻燃性能。水滑石(LDHs)因其无卤、无毒且抑烟性能优异,在阻燃领域受到了越来越多的关注。基于此,对LDHs的结构、制备方法及其阻燃机理进行了介绍,特别是对提高LDHs阻燃性能的途径即从层板阳离子掺杂、层间阴离子插层和表面改性进行了重点综述,并对不同结构LDHs的阻燃机理及阻燃性能进行了总结,最后展望了LDHs作为阻燃剂今后的发展趋势。 相似文献
10.
The synthesis of polyacrylonitrile‐block‐poly(ethylene oxide) (PAN‐b‐PEO) diblock copolymers is conducted by sequential initiation and Ce(IV) redox polymerization using amino‐alcohol as the parent compound. In the first step, amino‐alcohol potassium with a protected amine group initiates the polymerization of ethylene oxide (EO) to yield poly(ethylene oxide) (PEO) with an amine end group (PEO‐NH2), which is used to synthesize a PAN‐b‐PEO diblock copolymer with Ce(IV) that takes place in the redox initiation system. A PAN‐poly(ethylene glycol)‐PAN (PAN‐PEG‐PAN) triblock copolymer is prepared by the same redox system consisting of ceric ions and PEG in an aqueous medium. The structure of the copolymer is characterized in detail by GPC, IR, 1H‐NMR, DSC, and X‐ray diffraction. The propagation of the PAN chain is dependent on the molecular weight and concentration of the PEO prepolymer. The crystallization of the PAN and PEO block is discussed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1753–1759, 2003 相似文献