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1.
3,13-Diglycidyloxypropyloctaphenyl double-decker silsesquioxane (EP-DDSQ) was synthesized by process of alkaline hydrolysis condensation of phenyltrimethoxysilane and corner capping reaction of methyldichlorosilane, followed by hydrosilylation with allyl glycidyl ether, and the resultant structure was confirmed by fourier transform infrared spectrometer (FTIR) and nuclear magnetic resonance (NMR), respectively. The thermosetting phenol-formaldehyde (PF) resin was then modified by EP-DDSQ, and the reactivity of PF resin with EP-DDSQ and thermal pyrolysis of modified cured resin were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The surface morphologies of modified resins at high temperature were characterized with field emission scanning electron microscope (FESEM), and chemical structure of modified resins was analyzed through X-ray photoelectron spectrometer (XPS). The results showed that the appropriate addition of EP-DDSQ did not affect the curing temperature of the PF resin itself, but could improve the heat resistance of the system. When the amount of EP-DDSQ added was 10%, the initial degradation temperature of PF resin was increased by 49.31°C, and when the amount of EP-DDSQ added was 16%, the char yield of which was reached up to 61.39%, compared with that of pure PF resin (TGA1,000°C of 57.62%) at Ar atmosphere. More importantly, the modified resin formed a regular and dense layer of SiC and SiOx ceramic on the surface after ablation in the muffle furnace at 800°C air atmosphere, which is very important for ablative resistant materials. 相似文献
2.
A Fluorimetric Readout Reporting the Kinetics of Nucleotide‐Induced Human Ribonucleotide Reductase Oligomerization 下载免费PDF全文
Dr. Yuan Fu Dr. Hong‐Yu Lin Somsinee Wisitpitthaya William A. Blessing Prof. Yimon Aye 《Chembiochem : a European journal of chemical biology》2014,15(17):2598-2604
Human ribonucleotide reductase (hRNR) is a target of nucleotide chemotherapeutics in clinical use. The nucleotide‐induced oligomeric regulation of hRNR subunit α is increasingly being recognized as an innate and drug‐relevant mechanism for enzyme activity modulation. In the presence of negative feedback inhibitor dATP and leukemia drug clofarabine nucleotides, hRNR‐α assembles into catalytically inert hexameric complexes, whereas nucleotide effectors that govern substrate specificity typically trigger α‐dimerization. Currently, both knowledge of and tools to interrogate the oligomeric assembly pathway of RNR in any species in real time are lacking. We therefore developed a fluorimetric assay that reliably reports on oligomeric state changes of α with high sensitivity. The oligomerization‐directed fluorescence quenching of hRNR‐α, covalently labeled with two fluorophores, allows for direct readout of hRNR dimeric and hexameric states. We applied the newly developed platform to reveal the timescales of α self‐assembly, driven by the feedback regulator dATP. This information is currently unavailable, despite the pharmaceutical relevance of hRNR oligomeric regulation. 相似文献
3.
有机/无机杂化材料的改性及应用是目前材料科学中最富有活力的研究领域之一。其中笼型倍半硅氧烷(Polyhedral oligomeric silsesquioxane,POSS)在分子水平上实现了有机组分与无机组分的结合,结构呈硅氧骨架连接的立体笼型,具有优异的反应活性、耐热阻燃性、多孔性和纳米尺寸效应等特性,通过化学改性可将其应用在多个领域。本文主要从官能团改性、聚合改性和配位改性三个方面阐述了POSS的改性方法,综述了POSS在耐热材料、阻燃材料、增强材料和多孔材料等领域的应用研究进展,并对POSS今后的研究方向提出了展望。可从POSS的构效关系、改性方法以及安全性等方面进行更加深入和系统的研究,以促进POSS材料更广泛的应用。 相似文献
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A series of cyanate ester resin (CE) based organic–inorganic hybrids containing different contents (0, 5, 10, 15 and 20 wt%) of epoxy‐functionalized polyhedral oligomeric silsesquioxane (POSS‐Ep) were prepared by casting and curing. The hybrid resin systems were studied by the gel time test to evaluate the effect of POSS‐Ep on the curing reactivity of CE. The impact and flexural strengths of the hybrids were investigated. The micromorphological, dynamic mechanical and thermal properties of the hybrids were studied by SEM, dynamic mechanical analysis (DMA) and TGA, respectively. Results showed that POSS‐Ep prolonged the gel time of CE. CE10 containing 10 wt% POSS‐Ep displayed not only the optimum impact strength but the optimum flexural strength. SEM results revealed that the improvement of mechanical properties was attributed to the large amount of tough whirls and fiber‐like pull‐outs observed on the fracture surfaces of CE10. DMA results indicated that POSS‐CE tended to decrease E′ of the hybrids in the glassy state but to increase E′ of the hybrids in the rubbery state. TGA results showed that CE10 also possesses the best thermal stability. The initial temperature of decomposition (Ti) of CE10 is 426 °C, 44 °C higher than that of pristine CE. © 2013 Society of Chemical Industry 相似文献
6.
合成及表征了八苯基倍半硅氧烷(PH-POSS)、γ-甲基丙烯酰氧丙基倍半硅氧烷(MA-POSS),并利用差示扫描量热(DSC)和热重分析(TGA)分别研究其在聚碳酸酯(PC)体系中对体系热性能的影响。研究结果表明,复合材料Tg随着PH-POSS含量的增加而降低;而随着MA-POSS含量的增加基本不受影响。在氮气中,复合... 相似文献
7.
接枝法制备聚苯乙烯/笼型倍半硅氧烷复合材料 总被引:1,自引:0,他引:1
以工业级的3-氯丙基三氯硅烷和七聚(苯基)倍半硅氧烷三硅醇钠为原料,通过顶端封角法合成了含有一个3-氯丙基、七个苯基的单官能团POSS(3-氯丙基POSS),并以其作为聚苯乙烯的添加剂,采用化学接枝的方法制备POSS/PS复合材料.利用傅立叶转变红外光谱(FT-IR)、核磁共振(1H-NMR、29Si-NMR)和X-射... 相似文献
8.
从合成八苯基硅倍半氧烷(OPS)出发,通过控制硝化条件制备了不同多官能度硝基苯基硅倍半氧烷(NPS),然后对NPS催化还原得到相应的多官能度氨基苯基硅倍半氧烷(APS).利用红外、核磁、元素分析、热失重对多面体低聚硅倍半氧烷(POSS)化学结构和热性能进行了表征.元素分析发现OPS硝化时间越长,硝基越多,但是不是正比关... 相似文献
9.
Vitor R. ManfrinatoLin Lee Cheong Huigao DuanDonald Winston Henry I. SmithKarl K. Berggren 《Microelectronic Engineering》2011,88(10):3070-3074
We fabricated 9-30 nm half-pitch nested Ls and 13-15 nm half-pitch dot arrays, using 2 keV electron-beam lithography with hydrogen silsesquioxane (HSQ) as the resist. All structures with 15 nm half-pitch and above were fully resolved. We observed that the 9 and 10-nm half-pitch nested Ls and the 13-nm-half-pitch dot array contained some resist residues. We obtained good agreement between experimental and Monte-Carlo-simulated point-spread functions at energies of 1.5, 2, and 3 keV. The long-range proximity effect was minimal, as indicated by simulated and patterned 30 nm holes in negative-tone resist. 相似文献
10.