Thermal properties of hierarchical YSZ and LZO ceramic microspheres with multi-scaled voids investigated by using theoretical,experimental and simulation methods

Heat transfer within ceramic feedstock powders is still unclear, which impedes optimization of the thermal and mechanical properties of the thermal sprayed coatings. The microspheres (yttria-stabilized zirconia YSZ and lanthanum zirconate LZO) were prepared via the electro-spraying assisted phase inversion method (ESP). The thermal properties of the two ESP microspheres and a commercial hollow spherical powder (HOSP) were investigated by using theoretical, experimental, and simulation methods. Thermal conductivity of the single microsphere was estimated via a novel nest model that was derived from the Maxwell-Eucken 1 and the EMT model. Thermal conductivity of a single YSZ/LZO-ESP microsphere prepared at 1100–1200 °C was within 0.36–0.75 W/m K, which was ～ 20 % lower than that of a single YSZ-HOSP microsphere with a similar porosity. Heat flux simulation showed that high tortuosity around the multi-scaled voids of the ESP microsphere led to a more efficient decrease in thermal conductivity compared with total porosity.     

受老空水威胁工作面巷道防治水实践

针对高庄煤矿3_上1104回风巷为沿空掘巷,巷道掘进期间受3_上1102老空水威胁,掘进开采存在严重的水患安全问题,采用超前打设疏水孔的方案来治理老空水威胁,对巷道采用调向增大护巷煤柱厚度等措施实现巷道安全快速掘进,探放水期间无淹巷情况发生,探放水后巷道顶板和上帮无淋水现象发生。     

爆炸载荷下空孔缺陷与爆生裂纹扩展行为研究

空孔在岩石巷道直眼掏槽爆破中具有重要作用,为研究空孔及其缺陷在爆炸荷载作用下的扩展行为和作用机理,以PMMA代替岩石材料,利用预制裂纹代替空孔缺陷,借助动态焦散线系统和理论分析为手段,研究不同间距下空孔、空孔处预制裂纹、爆生裂纹动态扩展规律及机理,分析不同"径距比"与掏槽效果的关系。研究结果表明:在装药量一定的情况下,随着炮孔与空孔距离的变化,爆生裂纹扩展距离呈现递增而预制裂纹扩展距离呈现递减的趋势,但都存在极值;当炮孔与空孔距离较小时,爆生裂纹和预制裂纹扩展及相互作用最复杂,爆生裂纹扩展经历由压缩应力波为主,表现为直线的前期扩展;由空孔处发射应力波和压缩应力波共同作用下,爆生裂纹偏离炮孔与空孔连心线的中期扩展,以及由空孔应力集中区作用使爆生裂纹向空孔方向偏移的后期阶段;预制裂纹扩展经历由空孔处应力集中作用下,表现为直线的前期扩展,以及由爆生裂纹处反射拉伸波作用使其向爆生裂纹发展的后期阶段;当炮孔与空孔距离较大时,反射应力波及应力集中效应对爆生裂纹和预制裂纹扩展在减弱,爆生裂纹与预制裂纹扩展行为仅有前期直线扩展阶段。"径距比"的大小对爆破效果影响较大,直眼掏槽爆破应以最优"径距比"作为掏槽爆破参数设计的依据。     

8809工作面过空巷覆岩失稳规律及围岩控制技术研究

为保障8809工作面推进过空巷区域的安全生产,通过对过空巷区域时覆岩变形规律的分析,得出工作面与未支护的空巷间煤柱宽度为14m时,空巷围岩出现失稳。基于分析结果,确定J09-01和J09-02空巷采取锚网索+工字钢梁的支护技术,J09-03和J09-04空巷采用预充填技术,工作面顺利通过补强支护和充填空巷区域。     

自动多功能可调式便老轮椅的设计

针对老年人群体设计一种自动可调式轮椅，轮椅靠背通过不完全齿轮机构进行自动调整。靠背竖起可作为普通轮椅使用；靠背放平可实现平躺，可通过靠背和座椅安置的滚轴实现从轮椅到床和沙发等位置的移动。该轮椅工作稳定，性能可靠，功能实现效果较好。     

养老机构公共空间需求及影响因素研究——基于Kano模型分析

运用细分后的Kano模型甄别养老机构中老年人对公共空间需求的优先度排序及其影响因素的主次排序。首先通过规范、文献研究与访谈研究获取南京市养老机构中老年群体公共空间需求要素，并将得到的需求项进行层次归属划分。接着测算SI与DI系数量化各项需求对空间满意度的影响，得出公共空间需求优先度排序。最后利用多元线性回归对需求项的影响因素进行分析，探讨“自我”和“家庭”维度下影响因素的主次排序。得出养老机构公共空间的设计应首先满足老年人医疗保健空间层面的需求且空间需求受老年人“自我”维度下失能等级的影响程度最深。通过对需求重要度的排序，可以得出设计的优先满足策略，提升空间的利用效率及老年群体的满意度，为养老机构公共空间的投入侧重点提供理论依据。     

广州市老年人使用空气调节设备状况及对健康影响调查

老人的健康与建筑室内环境存在重要联系，为了给适老建筑的暖通系统优化设计提供理论依据，有必要探究室内空气调节设备与老人健康的关系。对广州市104位本地老年人进行了问卷调查，收集了老年人的基本健康信息和家庭使用空气调节设备的情况，包括制冷、除湿、采暖和空气净化4种设备及其使用时长，使用习惯。收集到的信息用SPSS20.0进行了统计分析。结果包括广州市老年人家中四种设备拥有率、设备平均使用龄、设备使用时间以及常见日均使用时长；所调查的老年人健康比例达到55.8%。患病老人中心血管疾病的比例最高，其余为风湿性疾病和关节炎等疾病。相关性分析表明，广州地区夏天家庭采取制冷措施的老人患病可能性更小；制冷设备常见日均使用时长与身处空调区域时长的比值越大，老人患病的可能性越小。     

Association of size‐fractionated indoor particulate matter and black carbon with heart rate variability in healthy elderly women in Beijing

Associations between size‐fractionated indoor particulate matter (PM) and black carbon (BC) and heart rate variability (HRV) and heart rate (HR) in elderly women remain unclear. Twenty‐nine healthy elderly women were measured for 24‐hour HRV/HR indices. Real‐time size‐fractionated indoor PM and BC were monitored on the same day and on the preceding day. Mixed‐effects models were applied to investigate the associations between pollutants and HRV/HR indices. Increases in size‐fractionated indoor PM were significantly associated with declines in power in the high‐frequency band (HF), power in the low‐frequency band (LF), and standard deviation of all NN intervals (SDNN). The largest decline in HF was 19% at 5‐minute moving average for an interquartile range (IQR) increase (24 μg/m³) in PM_0.5. The results showed that smaller particles could lead to greater reductions in HRV indices. The reported associations were modified by body mass index (BMI): Declines in HF at 5‐minute average for an IQR increase in PM_0.5 were 34.5% and 1.0% for overweight (BMI ≥25 kg/m²) and normal‐weight (BMI <25 kg/m²) participants, respectively. Moreover, negative associations between BC and HRV indices were found to be significant in overweight participants. Increases in size‐fractionated indoor PM and BC were associated with compromised cardiac autonomic function in healthy elderly women, especially overweight ones.     

基于静态顶空-气质联用法分析酱香型白酒空杯香气成分

采用静态顶空与气质联用（GC-MC）技术测定酱香型白酒空杯留香中挥发性香气成分。模拟品酒师感官品评过程中空杯留香方法，通过单因素试验分别考察平衡温度、平衡时间对酱香型白酒空杯留香香气成分的影响。结果表明，经过样品预处理的空杯在80 ℃平衡15 min的静态顶空条件下，检测出酱香型白酒中空杯留香香气成分最多。在此优化条件下，共检测出酱香型白酒中空杯留香的香气成分34种，通过香气活力值（OAV）评价香气贡献情况，确定出具有香气贡献的关键化合物（OAV＞1）共11种，以酯类、醛类、酸类香气为主。