Eco-friendly dehydrogenation of dimethylamine-borane catalyzed by core-shell-looking tri-metallic RuNiPd nanoclusters loaded on white-flowering horse-chestnut seed

Generally, white-flowering horse-chestnut seed (WFHC) found in roadsides, parks and gardens, which spills around and causes environmental pollution, is defined as waste-bio material. This study is quite remarkable as it gives WFHC a new field of usage and literally prioritizes the environment. Here, waste-bio WFHC was tested as supporter for tri-metallic RuNiPd nanoclusters in the eco-friendly dehydrogenation of dimethylamine-borane (DMAB). Core-shell-looking tri-metallic RuNiPd@WFHC, with 264.09 ± 45.55 nm particle size, were in-situ synthesized throughout dehydrogenation of DMAB at 35.0 ± 0.1 °C. The WFHC and tri-metallic Ru_2.00Ni_1.86Pd_1.00@WFHC NCs were characterized by advanced analysis and their surface morphologies were studied in detail using adsorption models. The N₂ adsorption-desorption and logarithmic-Freundlich plots indicated that surface morphologies have heterogeneous multi-layer and typical Type-III isotherm with mesoporous surfaces. Also, detailed kinetic studies were actualized on the dehydrogenation of DMAB catalyzed by tri-metallic Ru_2.00Ni_1.86Pd_1.00@WFHC NCs with 158 h^?1 TOF value.     

一种新的密码本原:棘轮密钥交换的定义、模型及构造

在传统密码学应用中,人们总假定终端是安全的,并且敌手只存在于通信信道上。然而,主流的恶意软件和系统漏洞给终端安全带来了严重和直接的威胁和挑战,例如容易遭受存储内容被病毒破坏、随机数发生器被腐化等各种攻击。更糟糕的是,协议会话通常有较长的生存期,因此需要在较长的时间内存储与会话相关的秘密信息。在这种情况下,有必要设计高强度的安全协议,以对抗可以暴露存储内容和中间计算结果(包括随机数)的敌手。棘轮密钥交换是解决这一问题的一个基本工具。文中综述了密码本原——棘轮密钥交换,包括单向、半双向和双向等棘轮密钥交换的定义、模型及构造,并展望了棘轮密钥交换的未来发展趋势。     

普通食用油检验关键点分析

以实际案例和文献资料收集为基础,主要围绕食用油检测从采样到结果判定一系列过程中可能涉及的操作风险点进行分析,并对部分典型检验指标(苯并(a)芘、塑化剂、抗氧化剂、残留溶剂、过氧化值、酸价、辣椒素、黄曲霉毒素B1)进行分析,介绍了分析过程中实验室环境、接触器具、试剂、样本本底、特殊基质干扰、指标稳定性等对实验结果有关键影响的因素,并针对具体问题提出解决措施,旨在为食用油检验风险防控提供技术支撑。     

HACCP在浓香菜籽油生产中的应用

为了保障浓香菜籽油的产品质量安全,采用HACCP体系对浓香菜籽油生产全过程进行生物、物理、化学的危害分析,确定关键控制点,制定预防措施,并对生产环节进行有效监控,制定纠偏措施,做好记录管理,为浓香菜籽油的安全生产提供借鉴。     

超深超高压裂缝性致密砂岩气藏高效开发技术——以塔里木盆地克拉苏气田为例

塔里木盆地库车坳陷克拉苏气田属于国内罕见的超深超高压裂缝性致密砂岩气藏,气田开发在超深圈闭及断层的落实、储层气水分布的预测、气藏精细描述、裂缝活动性变化的评价及预测、动态监测资料录取、渗流机理研究及对水侵的预测和治理等方面面临诸多难题。为此,通过开展超深复杂构造地震处理解释、裂缝性致密储层定量描述与地质建模、断层活动性评价、超高压气井动态监测以及超高压条件下的渗流机理实验,结合考虑水侵影响的优化开发技术政策,攻关形成了适用于该气藏的系列配套开发技术,并应用于气田开发实践。结果表明:(1)对于山前超深复杂构造,宽方位、高覆盖、高密度的地震采集技术和基于高精度速度模型的叠前深度偏移处理技术可以有效改善地震资料的品质,提高圈闭和断层的落实程度;(2)沿轴线高部位集中布井的井网可以较好地规避构造偏移的风险,实现储量的有效动用、延缓边部水侵;(3)防水、控水、排水是裂缝性致密砂岩气藏开发全生命周期都需要考虑的关键问题,温和开采、见水排水是主要的开发技术对策;(4)系列配套开发技术在该气田取得了良好的应用效果,钻井成功率、产能到位率均达到100%,高效井比例达到78%,该气田年产气量从3×10~8 m~3快速上升到74×10~8 m~3。     

Strategies and novel technologies to control Campylobacter in the poultry chain: A review

Campylobacteriosis is one of the most common bacterial infections worldwide causing economic costs. The high prevalence of Campylobacter spp. in poultry meat is a result of several contamination and cross‐contamination sources through the production chain. Moreover, survival mechanisms, such as biofilm formation, viable but nonculturable state, and antimicrobial resistance, enable its persistence during food processing. Therefore, mitigation strategies are necessary in order to avoid and/or inactivate Campylobacter at farm, abattoir, industry, and retail level. In this review, a number of potential strategies and novel technologies that could reduce the prevalence of Campylobacter in poultry meat have been identified and evaluated to provide a useful overview. At farm level for instance, biosecurity, bacteriocins, probiotics, feed and water additives, bacteriophages, and vaccination could potentially reduce colonization in chicken flocks. However, current technologies used in the chicken slaughter and processing industry may be less effective against this foodborne pathogen. Novel technologies and strategies such as cold plasma, ultraviolet light, high‐intensity light pulses, pulsed electric fields, antimicrobials, and modified atmosphere packaging are discussed in this review for reducing Campylobacter contamination. Although these measures have achieved promising results, most have not been integrated within processing operations due to a lack of knowledge or an unwillingness to implement these into existing processing systems. Furthermore, a combination of existing and novel strategies might be required to decrease the prevalence of this pathogen in poultry meat and enhance food safety. Therefore, further research will be essential to assess the effectiveness of all these strategies.     

强化吸收过程的吸收稳定节能流程关键参数辨识与分析

针对一种吸收塔带有侧线抽出的节能流程，通过比较各参数在一定范围内的变化对系统总费用的影响程度，辨识了影响吸收稳定系统效益的关键参数，还考察了烯烃以及能源市场价格变化对参数辨识的影响。结果表明，凝缩油罐温度和补充吸收剂流量是两个关键操作参数，解吸塔压力、吸收塔侧线抽出量和抽出位置、稳定塔进料温度对系统总费用有着较大的影响，稳定塔进料位置、解吸塔热进料比例则对系统总费用的影响较弱。     

采动覆岩卸荷膨胀累积效应

地下煤层开采引起的岩层运动是一系列安全和环境问题的根源,研究采动岩层运动规律是安全、高效、绿色开采的重要基础。通过对岩层运动过程的研究,揭示了采动覆岩卸荷膨胀累积效应及其对岩层运动规律的影响机制。研究表明:采动覆岩经历了卸荷膨胀与再压实的动态过程。受关键层结构控制,上覆岩层由下向上成组破断运动,关键层破断前,阻断了上覆载荷向下方岩层的传递,导致其因卸荷而产生膨胀,包括碎胀与弹性膨胀。随着关键层破断高度增加,覆岩卸荷高度同步增大,因卸荷而膨胀的岩层总厚度不断增大;同时卸荷煤岩也受到已破断关键层载荷的压实作用,从而造成覆岩卸荷膨胀总量的不断变化。将这种覆岩卸荷膨胀总量随覆岩卸荷高度动态变化的现象定义为采动覆岩卸荷膨胀累积效应,进而建立了理论模型,并通过淮北海孜煤矿巨厚火成岩下采煤覆岩裂隙实测进行了验证。结果表明,采动覆岩卸荷膨胀累积效应对采动岩层运动规律产生了重要影响,如影响覆岩关键层下离层量,影响覆岩关键层贯通破断的高度,影响不同开采条件的地表下沉系数等。采动覆岩卸荷膨胀累积效应改变了对离层存在形式的传统认识,该效应的存在导致关键层下最大离层量一般小于采高的10%,覆岩可注浆充填空间并非传统认识上的“离层区”,而主要是注浆充填压力“压实”作用下将覆岩卸荷累积膨胀所转化出的那部分空间,该发现指导了覆岩隔离注浆充填绿色开采技术的创新研发及其在建筑物压煤开采中的成功实践。     

原油及馏分油脱酸技术进展

石油酸是原油和馏分油中普遍存在的腐蚀性物质，其主要成分为环烷酸并且含量可以高达90%以上。环烷酸具有羧酸的所有化学性质，所以常常造成严重的腐蚀，从而影响原油加工设备及油品使用设备的正常运行和使用寿命。随着近年来世界范围内高酸原油产量的逐渐增加，高原油及各种高酸值馏分油所带来的腐蚀与产品质量问题显得愈发严重，因此迫切需要开发出经济高效的脱酸技术与工艺路线。本文较为全面而详细地总结并评述了国内外原油及油品的各种脱酸技术方法。分析表明：目前所报道的各类脱酸工艺较多，其中工业应用的加氢脱酸效果虽好但是成本较高，而其他大多数脱酸方法都存在较多的缺点或不足，因此探寻一种绿色环保、经济高效并且具有较好普适性的油品脱酸工艺显得非常迫切而必要。酯化法脱酸具有加工工艺简单、不需要复杂的后继处理，几乎可以降低所有的高酸值原油和油品（轻质、重质馏分油以及渣油）的酸值，为原料油的进一步加工提供了方便。酯化脱酸工艺的关键在于高效催化剂的选择，而目前的催化酯化体系虽然脱酸率较高，但仍存在着反应时间较长的不足，相信通过反应过程强化等手段解决该问题以后，催化酯化脱酸工艺会被很快投入到原油及油品的脱酸实际工业生产中去。     

The role of smart packaging system in food supply chain

Food supply chain is a rapidly growing integrated sector and covers all the aspects from farm to fork, including manufacturing, packaging, distribution, storing, as well as further processing or cooking for consumption. Along this chain, smart packaging could impact the quality, safety, and sustainability of food. Packaging systems have evolved to be smarter with integration of emerging electronics and wireless communication and cloud data solutions. Although there are many factors causing the loss and waste issues for foods throughout the whole supply chain of food and there have been several articles showing the recent advances and breakthroughs in developing smart packaging systems, this review integrates these conceptual frameworks and technological applications and focuses on how innovative smart packaging solutions are beneficial to the overall quality and safety of food supply by enhancing product traceability and reducing the amount of food loss and waste. We start by introducing the concept of the management for the integrated food supply chain, which is critical in tactical and operational components that can enhance product traceability within the entire chain. Then we highlight the impact of smart packaging in reducing food loss and waste. We summarize the basic information of the common printing techniques for smart packaging system (sensor and indicator). Then, we discuss the potential challenges in the manufacturing and deployment of smart packaging systems, as well as their cost-related drawbacks and further steps in food supply chain.