首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3023篇
  免费   205篇
  国内免费   72篇
电工技术   21篇
技术理论   3篇
综合类   307篇
化学工业   327篇
金属工艺   16篇
机械仪表   36篇
建筑科学   1657篇
矿业工程   60篇
能源动力   27篇
轻工业   105篇
水利工程   59篇
石油天然气   21篇
无线电   55篇
一般工业技术   318篇
冶金工业   65篇
原子能技术   4篇
自动化技术   219篇
  2024年   33篇
  2023年   81篇
  2022年   102篇
  2021年   89篇
  2020年   123篇
  2019年   99篇
  2018年   72篇
  2017年   71篇
  2016年   80篇
  2015年   115篇
  2014年   244篇
  2013年   199篇
  2012年   227篇
  2011年   244篇
  2010年   190篇
  2009年   193篇
  2008年   216篇
  2007年   168篇
  2006年   172篇
  2005年   100篇
  2004年   89篇
  2003年   86篇
  2002年   68篇
  2001年   47篇
  2000年   42篇
  1999年   30篇
  1998年   33篇
  1997年   17篇
  1996年   11篇
  1995年   9篇
  1994年   8篇
  1993年   5篇
  1992年   4篇
  1990年   4篇
  1988年   3篇
  1987年   2篇
  1986年   3篇
  1985年   5篇
  1984年   6篇
  1983年   3篇
  1982年   2篇
  1980年   1篇
  1965年   2篇
  1964年   1篇
  1959年   1篇
排序方式: 共有3300条查询结果,搜索用时 15 毫秒
1.
During the day, there are considerable variations in the climatic factors prevailing in these regions. This is especially so during the 24-hour daily cycle of the long, hot and dry summer (mid-May to midOctober). Such climatic conditions have had a considerable impact on the daily living pattern of family life in the same season, particularly in the urban areas. During the same 24-hour cycle, they have compelled the inhabitants to shift their living activities both vertically in section and horizontally in plan; they do this in pursuit of more acceptable, if not, desirable internal thermal environmental ambience.  相似文献   
2.
通过对西安绿色康居小区规划设计的实例分析,阐明了小康型住宅区的标准和要求,在旧城住宅区改造中的落实和运用,试图探索下一世纪旧城住宅区的改造之路.  相似文献   
3.
辽宁省城镇居民生活用水定额   总被引:1,自引:0,他引:1  
本文分析了城镇居民生活用水的特点,介绍了辽宁省城镇居民生活用水定额制定的原则、方法。通过对全省县级以上城镇居民生活用水情况的调查,制定适合辽宁省实际情况的城镇居民生活用水定额。  相似文献   
4.
BACKGROUND: Two peat biofilters were used for the removal of toluene from air for one year. One biofilter was fed with pure toluene and the other received 1:1 (by weight) ethyl acetate:toluene mixture. RESULTS: The biofilters were operated under continuous loading: the toluene inlet load (IL) at which 80% removal occurred was 116 g m?3 h?1 at 57 s gas residence time. Maximum elimination capacity of 360 g m?3 h?1 was obtained at an IL of 745 g m?3 h?1. The elimination of toluene was inhibited by the presence of ethyl acetate. Intermittent loading, with pollutants supplied for 16 h/day, 5 days/week, did not significantly affect the removal efficiency (RE). Biomass was fully activated in 2 h after night closures, but 6 h were required to recover RE after weekend closures. Live cell density remained relatively constant over the operational period, while the dead cell fraction increased. Finally, a 15 day starvation period was applied and operation then re‐started. Performance was restored with similar re‐acclimatization period to that after weekend closures, and a reduction in dead cell fraction was observed. CONCLUSION: This study demonstrates the capacity of the system to handle intermittent loading conditions that are common in industrial practices, including long‐term starvation. Copyright © 2008 Society of Chemical Industry  相似文献   
5.
In a recent discovery, coaxial electrospinning was explored to encapsulate living organisms within a continuous bio‐polymeric microthread from which active biological scaffolds were fabricated (Townsend‐Nicholson and Jayasinghe, Biomacromolecules 2006, 7, 3364). The cells were demonstrated to have gone through all expected cellular activity without their viability being compromised. These biologically active threads and scaffolds have direct and tremendous applicability from regenerative to therapeutic medicine. Currently these post‐processed cells as composite threads and scaffolds are being investigated in‐depth at a cellular level to establish if the processing methodology has any affect on the cellular make‐up. We now demonstrate a competing non‐electric field driven approach for fabricating composite threads and scaffolds influenced only by a differential pressure. We refer to this novel composite thread to scaffold fabrication methodology as coaxial aerodynamically assisted bio‐threading (CAABT). Our investigations firstly, demonstrate that this technique can process handle living organisms without biologically perturbing them in anyway. Secondly the process is elucidated as possessing the ability to form composite active threads from which biologically viable scaffolds are formed. Finally our study employs florescent activated cell sorting (FACScan), a method by which the cellular dynamics and viability are quantified on control and threaded cellular samples at two prescribed time points. In parallel with FACScan, optical comparison of cellular morphology at three time points within a period of three weeks is carried out to photographically observe any changes in the post‐processed cellular phenotype. Our developmental investigations into this novel aerodynamically assisted threading methodology has unearthed a unique biomicrofabrication approach, which joins cell electrospinning in the cell threading to scaffold fabrication endeavor. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
6.
在本文中,以利用适地性服务机制之设计,来建立一个行动导览系统带领用户体验空间和主题维度的古迹导览服务。为了满足此需求,设计了一套后设数据(Metadata)来描述导览内容,并且在适地性服务机制设计上,提供包含适地性内容方法有效取得使用者附近的内容,并藉由适地性内容的暂存与安排方法,减少网络间的讯息传递,提供用户结构化的介绍内容,并在适当的时机触发内容的呈现。最后,以所提供之内容的相关性来比较所提方法与一般适地性服务之差异。邀请用户进行实地系统测试,以了解系统的实用性,取得测试者的建议。结果证实所设计之导览系统可以是导览解说员的多媒体辅助工具,或在没有导览解说员时,为使用者提供景点导览解说的服务。  相似文献   
7.
Summary: A semi‐batch process using nitroxide mediated polymerization, was explored for the design of low molecular weight solvent‐borne coatings, typical of those used in the automotive industry. While living radical polymerization (LRP) offers many advantages in the control of polymer chain microstructure that may confer important physical and chemical property benefits to coatings, adapting LRP to a semi‐batch process poses significant challenges in the design and operation of the process. Using styrene monomer, various two‐component initiating systems (free radical initiator, 4‐hydroxy‐TEMPO) were studied to understand the effects of different initiators on the course of polymerization. In addition, an alkoxyamine was synthesized and used as the initiating source. The initiators Luperox 7M75 and Luperox 231 give higher polymerization rates and reasonable control over polymerization, while benzoyl peroxide (BPO), Vazo 67, and the alkoxyamine are less effective. The number of polymer chains in the final product is always less than the theoretical value, reflecting poor initiation efficiency, probably resulting from undesirable termination reactions that become important due to the nature of the semi‐batch process. Adding camphorsulfonic acid (CSA) or charging initiator concurrently with monomer during semi‐batch feed, can increase the polymerization rate while maintaining the living character of the polymerization. The copolymerization of styrene and butyl acrylate is also shown to exhibit living character.

Schematic representation of the exchange reaction to produce N‐TEMPO capped polymer chains.  相似文献   

8.
Dimethylsiloxane-tetramethyl-p-silphenylenesiloxane-dimethylsiloxane (DMS-TMPS-DMS) triblock copolymer was synthesized by employing living anionic polymerization of hexamethylcyclotrisiloxane (D3). Two synthetic methods were carried out for the polymerization. One of those methods was the anionic polymerization of D3 initiated at the silanolate anion which was prepared from the terminal hydroxyl group of silanol-terminated TMPS prepolymer by reaction with n-butyllithium (method 1). The other was the coupling reaction of vinyl-terminated TMPS prepolymer with hydrosilyl-terminated DMS prepolymer obtained from the anionic polymerization of D3 by using diphenylmethylsilanolate anion as initiator (method 2). In method 1, DMS contents of the copolymers ranged from 25.8 to 72.5 wt% and the values agreed with the ratio of D3 to TMPS prepolymer. The weight-average molecular weights ranged from 1.36×104 to 19.4×104 and were close to the predicted values calculated from the M?v of the TMPS prepolymer and the amount of D3 added. In the case of method 2, weight-average molecular weights ranged from 19.5×104 to 24.2×104. The high molecular weight copolymer could thus be obtained by method 2. Intrinsic viscosity values of the triblock copolymers agreed with calculated values obtained by considering the copolymer as a binary mixture of these homopolymers. Differential scanning calorimetry and thermogravimetry were carried out on the triblock copolymers. The equilibrium melting temperatures of each of the copolymers were very close to that of poly-TMPS (160°C). The glass transition temperature and heat of fusion were decreased as the DMS content was increased. The thermogravimetric curves for the copolymers indicated that the thermal stability of the triblock copolymer was intermediate between the DMS and TMPS homopolymers.  相似文献   
9.
The controllability of the atom transfer radical polymerization of methyl methacrylate in the polar solvent N,N‐dimethylformamide and the nonpolar solvent xylene with 4‐(chloromethyl)phenyltrimethoxysilane as an initiator and with CuCl/2,2′‐bipyridine and CuCl/4,4′‐di(5‐nonyl)‐2,2′‐bipyridine as catalyst systems was studied. Gel permeation chromatography analysis established that in the nonpolar solvent xylene, much better control of the molecular weight and polydispersity of poly(methyl methacrylate) was achieved with the CuCl/4,4′‐di(5‐nonyl)‐2,2′‐bipyridine catalyst system than with the CuCl/2,2′‐bipyridine as catalyst system. In the polar solvent N,N‐dimethylformamide, unlike in xylene, the polymerization was more controllable with the CuCl/2,2′‐bipyridine catalyst system than with the CuCl/4,4′‐di(5‐nonyl)‐2,2′‐bipyridine catalyst system. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2751–2754, 2007  相似文献   
10.
Technological infrastructure at home is changing continuously and is becoming increasingly interconnected. Media devices, including the TV set, provide access to the Internet and offer manifold opportunities to consume media on demand. Additionally, personal devices, such as smartphones, also enable flexible consumption and sharing of media. Questions about how these technologies change the user's media usage and how these changes affect the social structure of a household, however, remain largely unanswered. In order to gain insight into the adoption of new technologies into daily routines, we explored these changes in respect of people's media usage in a qualitative long-term Living Lab study. We will present findings regarding personal routines, flexible integration of new devices into existing practices, influences on households as social systems and related issues in device access and collective use. We will highlight potentials and conflicts regarding device shifts and roles; restrictions in device access; social influences in the living room; and individual changes in media consumption.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号