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1.
现代农业如植物工厂的快速发展对植物照明的需求不断扩大,发光强度高、热稳定性良好的深红色荧光粉是LED人工植物照明光源的关键材料。为研究Eu3+在CaLu2-xAl4SiO12基质中的发光性能,采用高温固相法合成了新型CaLu2-xAl4SiO12:xEu3+(x=0.1、0.3、0.5、0.7、0.9、1.1)荧光粉,通过多种表征测试技术,系统地研究了荧光粉的晶体结构、微观形貌、荧光性质及热稳定性能,并初步探究了CaLu2-xAl4SiO12:xEu3+在植物照明领域应用的可能性。通过XRD、Rietveld结构精修、EDS能谱和元素分布分析发现, Eu3+成功进入了CaLu2Al4SiO12基质中。荧光光谱测试结果表明:在711 nm光的监测下,样品在280—500 nm范围出现了Eu3+的特征f-f跃迁吸收峰;在394 nm光的激发下,样品在550—750 nm范围出现了Eu3+的5D0-7FJ (J=0、1、2、3、4)跃迁发射,其最强发射峰位于711 nm(5D0-7F4)处,Eu3+的最佳掺杂量x=0.5;Eu3+的荧光寿命衰减曲线和荧光发射光谱,证明了Eu3+在CaLu2Al4SiO12基质中只占据一个晶体学格位;CaLu1.5Al4SiO12:0.5Eu3+荧光粉在423 K下的发射峰积分强度为室温下的91.75%,表明了该荧光粉具有良好的热稳定性;CaLu2-xAl4SiO12:xEu3+的深红色强发射峰位于711 nm处,与植物的光敏色素(PFR)吸收波段相吻合,表明CaLu2-xAl4SiO12:xEu3+是一种潜在的可用于LED植物照明的荧光粉。 相似文献
2.
以河南、云南、黑龙江、内蒙古和福建5个不同产地的黑豆为研究对象,通过测定γ-氨基丁酸(GABA)含量、溶栓酶活性、大豆异黄酮含量等指标,并对电子鼻分析结果进行主成分分析(PCA)和聚类分析(CA),比较不同产地的发芽黑豆利用中国根霉12#发酵前后的营养、活性及挥发性风味成分变化。结果表明,云南产地的发芽黑豆发酵处理后γ-氨基丁酸、大豆异黄酮、氨基酸态氮含量均高于其他产地,分别高达(6.68±0.07) mg/g、(4.57±0.04) mg/g、(0.91±0.05) g/100 g;黑龙江产地发芽黑豆发酵处理后,其溶栓酶活性为(1 032.94±88.08) IU/g,显著高于其他产地的溶栓酶活性(P<0.05),其挥发性成分种类增加最多,2,3,5-三甲基吡嗪、1-辛烯-3-醇、壬醛、3-羟基-2-丁酮等含量以及挥发性风味成分电子鼻分析响应值均为最高。根据营养成分分析,云南产地的黑豆质量较优,根据溶栓酶活性和风味分析,黑龙江产地的黑豆质量较好。 相似文献
3.
Keshun Liu 《Journal of the American Oil Chemists' Society》2021,98(12):1115-1129
For measuring trypsin inhibitor activity (TIA), there are two major official methods: American Oil Chemists Society (AOCS) method Ba 12a-2020 and International Organization for Standardization (ISO) 14902:2001. The former was recently approved. The two methods differ in sample preparation, extraction, colorimetric assay systems and TIA calculations. In this study, the two methods were symmetrically compared using three unique sets of samples: assorted protein products of soybeans, pulses, and grains; soybeans boiled for varied durations; and soy white flakes toasted for varied durations. For given samples, significant differences existed in TIA measured by the two methods, resulting from effects related to the assay systems and TIA calculations, not from the difference in sample preparation and extraction. When the same trypsin was used, TIA (in mg trypsin inhibited/g sample) measured by the two methods were highly correlated (r = 0.9973, n = 27), giving an equation of y = 0.5464x − 0.4887, where y represents ISO values and x for AOCS values. The line connecting ratios of ISO/AOCS in TIA and AOCS values remained relatively flat around 0.53 but started to curve down when TIA approached the lowest. Furthermore, for the same samples, TIA values measured by the ISO method decreased with increasing specific activity of trypsin used, while AOCS values remained consistent, leading to decreasing ratios of ISO/AOCS. Therefore, accurate and direct comparison of the two methods was impossible. It could not be resolved by simply changing ISO method's calculations as hypothesized earlier. Regardless, for most samples, ISO values were roughly about 55% of AOCS values. 相似文献
4.
Abidur Rahman Makoto Kobayashi Kotaro Sugimoto Yuta Endo Manabu Kojima Shigenori Furukawa Takafumi Watanabe Shu Soeda Yuko Hashimoto Keiya Fujimori Hideki Chiba 《International journal of molecular sciences》2021,22(7)
Background: Within the claudin (CLDN) family, CLDN12 mRNA expression is altered in various types of cancer, but its clinicopathological relevance has yet to be established due to the absence of specific antibodies (Abs) with broad applications. Methods: We generated a monoclonal Ab (mAb) against human/mouse CLDN12 and verified its specificity. By performing immunohistochemical staining and semiquantification, we evaluated the relationship between CLDN12 expression and clinicopathological parameters in tissues from 138 cases of cervical cancer. Results: Western blot and immunohistochemical analyses revealed that the established mAb selectively recognized the CLDN12 protein. Twenty six of the 138 cases (18.8%) showed low CLDN12 expression, and the disease-specific survival (DSS) and recurrence-free survival rates were significantly decreased compared with those in the high CLDN12 expression group. We also demonstrated, via univariable and multivariable analyses, that the low CLDN12 expression represents a significant prognostic factor for the DSS of cervical cancer patients (HR 3.412, p = 0.002 and HR 2.615, p = 0.029, respectively). Conclusions: It can be concluded that a reduced CLDN12 expression predicts a poor outcome for cervical cancer. The novel anti-CLDN12 mAb could be a valuable tool to evaluate the biological relevance of the CLDN12 expression in diverse cancer types and other diseases. 相似文献
5.
Pengfei Chen Honggang Chang Tao Peng Yongfan Tang Youquan Liu Chao Xiang 《应用聚合物科学杂志》2021,138(30):50314
Hydraulic fracturing with slickwater is a field-proven stimulation technology used in tight reservoirs. Because of the high pumping rate associated with slickwater fracturing, drag reduction (DR) is critical in minimizing pressure drop and the success of oilfield operations. In this paper, a new type of drag reducer (SPR) was synthesized with acrylamide and 12-allyloxydodecyl acid sodium, and its drag reduction performance was evaluated. The results showed that the new drag reducer features low molecular weight, fast-dissolving rate and low interfacial tension. The algorithm of estimating the drag reduction rate of non-Newtonian fluid SPR was proposed and validated. Empirical or semianalytical models for estimating the friction ratio (σ) or friction factor (λ or f) were used to simulate the turbulence behavior of the SPR drag reducer under different Reynolds numbers (Re). The modified Virk's correlation could accurately model the turbulent behavior of the SPR drag reducer. A unified calculation formula was established in this study for different pipe diameters. 相似文献
6.
目的 针对某飞机吊挂结构用2A12铝合金开展预腐蚀后的动态腐蚀-疲劳耦合试验,很快发生断裂行为,寻找失效原因并提出解决措施.方法 利用自制的卧式动态腐蚀-疲劳试验装置,开展2A12铝合金预腐蚀后的腐蚀-疲劳协同试验直至样品断裂.同时,对比开展2A12铝合金腐蚀与疲劳交替试验,分析断口腐蚀形貌、元素含量、价态变化,获得2A12铝合金在两种试验方法下的腐蚀疲劳机理.结果 2A12铝合金主要由铝基体以及弥散分布其中的多种合金强化相组成.当有预裂纹时,2A12铝合金在腐蚀与疲劳交替作用下,很快发生疲劳断裂,且裂纹几乎贯穿整个断面,在整个裂纹附近存在较多的腐蚀产物Al2O3.2A12铝合金在预腐蚀后,基体与其表面的氧化膜之间形成腐蚀电池,初期的点蚀孔快速发展成明显腐蚀坑并产生大量腐蚀产物Al2O3,腐蚀坑底部由于应力集中现象而成为裂纹源,在动态腐蚀-疲劳耦合作用下快速萌生裂纹并呈放射状扩展,很快发生疲劳断裂行为,同时裂纹扩展区无腐蚀产物.结论 2A12铝合金用作飞机吊挂结构件时,必须进行表面防腐处理,避免形成腐蚀坑,减缓吊挂结构发生腐蚀-疲劳断裂进程. 相似文献
7.
Dawid Polak Marcin Talar Nina Wolska Dagmara W. Wojkowska Kamil Karolczak Karol Kramkowski Tomasz A. Bonda Cezary Watala Tomasz Przygodzki 《International journal of molecular sciences》2021,22(6)
Blood platelets’ adenosine receptors (AR) are considered to be a new target for the anti-platelet therapy. This idea is based on in vitro studies which show that signaling mediated by these receptors leads to a decreased platelet response to activating stimuli. In vivo evidence for the antithrombotic activity of AR agonists published to date were limited, however, to the usage of relatively high doses given in bolus. The present study was aimed at verifying if these substances used in lower doses in combination with inhibitors of P2Y12 could serve as components of dual anti-platelet therapy. We have found that a selective A2A agonist 2-hexynyl-5’-N-ethylcarboxamidoadenosine (HE-NECA) improved the anti-thrombotic properties of either cangrelor or prasugrel in the model of ferric chloride-induced experimental thrombosis in mice. Importantly, HE-NECA was effective not only when applied in bolus as other AR agonists in the up-to-date published studies, but also when given chronically. In vitro thrombus formation under flow conditions revealed that HE-NECA enhanced the ability of P2Y12 inhibitors to decrease fibrinogen content in thrombi, possibly resulting in their lower stability. Adenosine receptor agonists possess a certain hypotensive effect and an ability to increase the blood–brain barrier permeability. Therefore, the effects of anti-thrombotic doses of HE-NECA on blood pressure and the blood–brain barrier permeability in mice were tested. HE-NECA applied in bolus caused a significant hypotension in mice, but the effect was much lower when the substance was given in doses corresponding to that obtained by chronic administration. At the same time, no significant effect of HE-NECA was observed on the blood–brain barrier. We conclude that chronic administration of the A2A agonist can be considered a potential component of a dual antithrombotic therapy. However, due to the hypotensive effect of the substances, dosage and administration must be elaborated to minimize the side-effects. The total number of animals used in the experiments was 146. 相似文献
8.
利用Gleeble3180热模拟试验机,在变形温度为950~1100 ℃,应变速率为0.001~1 s-1,真应变为0.7的条件下,对X12CrMoWVNbN钢进行了高温单向热压缩试验。通过不同条件下的高温流变曲线分析了变形温度和应变速率对试验钢热变形力学行为的影响。以Arrhenius方程为本构模型,建立了能够预测该钢流动应力的本构方程。基于动态材料模型和试验参数、结果,绘制了该钢不同应变量下的热加工图并结合图进行了组织分析。结果表明,流变峰值应力和稳态应力随温度降低或应变速率升高而升高;功率耗散系数随应变速率降低和变形温度的升高而增大;最优热加工区域功率耗散系数η的值都在0.4以上,且这些区域的变形组织晶粒均匀细小;0.3、0.4、0.5和0.6应变下的最优热加工区域都处于变形温度1050~1100 ℃、应变速率0.001~0.003 s-1的范围。 相似文献
9.
10.