快干型芭蕉芋淀粉粘合剂的制备

介绍一种快干型芭蕉芋淀粉粘合剂，它特别适合于粘结瓦楞纸板，其制法是芭蕉芋等直链淀粉含量较代低的天然植物淀粉为原料，经氧化、糊化、交联等步骤而制得；产品结力强，产品性能稳定，贮存期长。     

氧化淀粉变性基团的分析方法

介绍了淀粉工业中氧化淀粉变性基团羧基和羰基的测定方法     

Synthesis and characterization of copolythiophene

Copolythiophenes (Co‐PTs), poly(3‐hexylthiophene‐co‐3‐thiophene carboxylic acid) (P3HT‐TCa), poly(3‐hexyloxylthiophene‐co‐3‐thiophene carboxylic acid) (P3HOT‐TCa), and poly(3‐phenylthiophene‐co‐3‐thiophene carboxylic acid) (P3PhT‐TCa), were synthesized by chemical oxidized polymerization to investigate the effect of copolymerization on the properties of polythiophenes (PTs). Gel permeation chromatography showed that the molecular weight (MW) of Co‐PT was lower than that of homopolythiophene. Fourier transform infrared (FTIR) spectra indicated that the copolymerization was successful between the monomers. The λ_max of Co‐PTs gave a “blue shift” in ultraviolet‐visible (UV‐VIS) spectra. Photoluminescence (PL) spectra showed that the PL intensity of Co‐PT became weaker than that of homopolythiophene and the disappearance of PL had been observed in P3HOT‐TCa. The thermal stability of Co‐PT was influenced by the carboxyl for its low decomposition temperature. Furthermore, the copolymerization between multi‐wall carbon nanotube containing thiophene ring (MWNT‐Th) and 3‐hexyloxylthiphene could also take place successfully. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Study of the influence of reaction conditions on the degree of substitution,intrinsic viscosity,and yield of oxidized cellulose acetate by factorial experimental design

A half‐fraction, two‐level, four‐factor factorial experimental design was used to study the effects of the acetic anhydride concentration, reaction temperature, reaction time, and sulfuric acid concentration on the degree of substitution, intrinsic viscosity, and yield of oxidized cellulose acetate (OCA). Oxidized cellulose containing 20% (w/w) carboxylic acid was used as the starting material. The data were fitted by multiple regression analysis with SAS software. The correlation coefficients obtained from plots of the predicted and observed values for the degree of substitution, intrinsic viscosity, and yield were 0.985, 0.993, and 0.991, respectively. Residual normal plots of the regression models showed a linear relationship. Lenth and main‐factor‐effect plots revealed an increase in the degree of substitution of OCA with an increasing concentration of acetic anhydride. The latter had no effect on the intrinsic viscosity and yield of OCA. An increase in the reaction temperature led to an increase in the degree of substitution and a decrease in the intrinsic viscosity and yield of OCA. The influence of the reaction time on the degree of substitution and intrinsic viscosity followed a trend similar to that observed with the reaction temperature, but the yield of OCA was unaffected. Increasing the concentration of sulfuric acid reduced the degree of substitution, intrinsic viscosity, and yield of OCA. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 696–705, 2005     

研究Nd-Fe-B粉末材料中不同状态氧的新方法

基于不同氧化物与碳的结合能不同,与碳的还原反应在不同的分析条件下具有先后次序,用脉冲红外氧化物夹杂分析仪,对4μm的烧结Nd Fe B永磁材料粉末的氧化行为进行了方法研究。实验结果表明,通过合理设置参数,选用跟踪升温模式,可以快速分离Nd Fe B永磁材料粉末中的不同氧化物,并可以通过加权方法进行定性验证。     

昆钢120万t氧化球团试生产实践

本文详细介绍了昆钢第一条120万t／a链篦机-回转窑氧化球团生产线试生产期间的原料情况，生产情况以及如何解决生产中遇到的困难等，并分析了使用自产球团矿期间6号高炉的生产情况。     

葡醛内酯生产工艺改进研究

在实验研究的基础上，对现有葡醛内酯生产工艺中存在的的问题提出了相应的对策．为了提高产率，减轻污染以降低生产成本，进行了分阶段和全流程工艺实验，确认淀粉氧化工序中硝酸的浓度以70％适宜，氧化温度应控制在50℃或稍低，氧化淀粉水解前用硼氢化钠或氢气对氧化淀粉进行还原是提高葡醛内酯产率的有效手段．通过控制用酸量、改进加料方式和改善吸收可以有效地减轻环境污染．     

强化链篦机-回转窑氧化球团生产的途径

本文通过对原料选择到成品球团矿产出各个工艺环节的分析，提出了强化链篦机-回转窑氧化球团生产的途径。特别强调了优化造球原料、造好球、布好料以及保证链篦机的运行和提高链篦机尾部温度提高入窑强度是强化生产的关键。     

十红滩铀矿床有机地球化学特征及与铀成矿作用

十红滩铀矿床属层间氧化带砂岩型铀矿床,赋存于中侏罗统西山窑组含煤碎屑岩中。容矿层岩石中富含有机质,有机碳、可溶有机物、酸解吸附烃在不同地球化学分带的岩石中含量大小不同,尤以氧化还原过渡带含量最高。矿石有机质母质类型为腐殖型,处于未成熟演化阶段,酸解吸附烃为煤成气型。统计计算表明:容矿层中铀和可溶有机物、酸解吸附烃含量之间具明显的相关关系。分析了有机质在砂岩型铀矿床形成过程中的作用,认为容矿层中有机质在含氧环境下分解的产物利于铀在水中的溶解和迁移,而在缺氧条件下分解的产物,构成铀沉淀的还原和吸附地球化学障,在铀的成矿过程中发挥重要的作用。     

某难选地表氧化铁矿的选矿试验研究

对某难选地表氧化铁矿进行了选铁试验研究。采用阶磨-弱磁-强磁-反浮选流程选别该矿石, 可以取得精矿产率39.11%, 铁品位65.10%, 回收率70.5%的指标。