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1.
为指导实际双金属管精确成形工艺,基于LS-Dyna对铝/钢双金属管电磁缩径连接进行了结构场-电磁场耦合的有限元数值模拟,研究了内外管壁厚比值、内外管间隙、放电电压以及芯模对成形质量的影响规律.结果表明:内外管壁厚比值过小易引起内外管连接不紧密,比值过大易导致内管凹陷和外管开裂;随着放电电压增大或内外管间距的减小,外管缩径冲击力增大,导致内管周向应力的急剧增大和失稳起皱,同时造成外管开裂;而随着放电电压减小或内外管间距的增大,外管相对的缩径冲击力减小,内管会因无法经历一个有效的形变回弹过程导致内外管有效连接区域逐渐减小;采用弹性芯模可一定程度抑制开裂等宏观缺陷的产生,同时也能适当增加内管的回弹.最后,基于理论计算与有限元仿真获得复合管电磁成形规律和缺陷控制理论,以增大有效连接区域长度、减少宏观缺陷为目标进行优化,在施加弹性芯模的状态下,内管壁厚维持1 mm不变,外管壁厚取1.5 mm,内外管间隙取0.7 mm,放电电压取50 kV时得到的成形质量最佳. 相似文献
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Lennard F. Torres Zach McCaffrey Wisdom Washington Tina G. Williams Delilah F. Wood William J. Orts Colleen M. McMahan 《应用聚合物科学杂志》2021,138(28):50684
This study explored the feasibility of using torrefied biomass as a reinforcing filler in natural rubber compounds. Carbon black was then replaced with the torrefied biomass in elastomer formulations for concentrations varying from 0% to 100% (60 parts per hundred rubber or phr total). Their influence on the curing process, dynamic properties, and mechanical properties was investigated. Results were compared with the properties of vulcanizates containing solely carbon black fillers. Time to cure (t90) for compounds with torrefied biomass fillers increased, while filler-filler interactions (ΔG') decreased, compared to carbon black controls. At low strains, the tan δ values of the torrefied fillers vulcanizates were similar to the controls. Incorporation of torrefied biomass into natural rubber decreased compound tensile strength and modulus but increased elongation. Replacement with torrefied fillers resulted in a weaker filler network in the matrix. Still, results showed that moderate substitution concentrations (~20 phr) could be feasible for some natural rubber applications. 相似文献
4.
In this work, Bis-(3-triethoxysilylpropyl) tetrasulphane was employed for surface modification of silica, ferrite and kenaf fiber filled natural rubber composites using aqueous solvent deposition, dry blending and integral blend methods. The efficiency of each method and the preferred modification method for improving the mechanical performance of natural rubber composites was assessed. The appearance of the Fourier transform infrared spectroscopy peak around 1088 cm−1 for all types of fillers provided evidence that silane interaction had occurred between the fillers and rubber and the formation of siloxane linkages were quantitatively determined by the crosslink density measurement. The surface treatment by dry method for silica and ferrite fillers showed significant improvement of tensile performance at approximately 67% and 34% compared to those with untreated fillers. For kenaf fiber-filled rubber composites, the surface treatment by aqueous solvent deposition showed the highest tensile improvement of 59% compared to the dry blending and integral blend method. 相似文献
5.
This study reports a green and powerful strategy for preparing cellulose nanocrystal (CNC)/graphene oxide (GO)/natural rubber (NR) nanocomposites hosting a 3D hierarchical conductive network. Due to good dispersibility and amphiphilic nature of CNC, well dispersed CNC/GO nanohybrids were prepared. Hydrogen bonding interactions between CNC and GO greatly enhanced the stability of the CNC/GO nanohybrids. CNC/GO nanohybrids were introduced into NR latex under sonication and the mixture was cast. Self-assembled CNC/GO nanohybrids preferentially dispersed in the interstice between latex microspheres allowing the construction of a 3D hierarchical conductive network. By combining strong hydrogen bonds and 3D conductive network, both electrical conductivity and mechanical properties (tensile strength and modulus) have been significantly improved. The electrical conductivity of the nanocomposite with 4 wt% GO and 5 wt% CNC exhibited an increase of nine orders of magnitude compared to the nanocomposite with only 4 wt% GO; meanwhile, the electrical percolation threshold was 3-fold lower than for NR/GO composites. 相似文献
6.
Edoardo Zonta Francesco Valentini Andrea Dorigato Luca Fambri Alessandro Pegoretti 《Polymer Engineering and Science》2021,61(1):136-153
The thermomechanical behavior of ethylene propylene diene monomer (EPDM) foams produced with the salt leaching method has been investigated and compared with the behavior of EPDM foams obtained from conventional blowing agents. Moreover, the salt-leaching process has been optimized to minimize salt residues and the influence of different parameters (such as average particle size and particle size distribution) has been investigated. Scanning electron microscopy and density measurements highlighted that salt-leaching leads to the formation of open-cell porosity with cell dimensions of around 60 to 80 μm, while foams obtained with the two traditional foaming agents lead to closed-cell porosity. Compression set values indicate that the behavior of the foams produced with salt leaching are more similar to the unfoamed rubber, characterized by higher elasticity and low residual deformation. Two theoretical models were successfully applied to the compression curves (Mooney-Rivlin and Exponential-Logarithmic) and they highlighted the effect of foaming on the properties of EPDM rubber and in particular the higher chain extensibility obtained through the salt leaching foaming method. 相似文献
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我公司使用的硫化机采用氮气定型,二次水硫化的工艺。由于特种工程胎胎体偏厚且大,成型机都比较大,生产过程中的帘布筒、钢丝、胎侧等部件都比较重且大。成型胎面使用胎面缠绕机缠绕,所以整个生产过程难度较大。特种工程胎硫化外胎的主要质量问题有:胎面皮泡、胎侧缺胶、胎侧泡、胎肩侧皮泡、子口内侧露线、子口缺胶、胎肚内缺(窝气)、胎肚露线、胎肚皮泡、胎肚串泡、子口支边、胎冠支边、子口鼓包、外胎花缺等。通过对特种工程胎硫化外胎质量缺陷原因分析,找到相应的解决措施,从而减少硫化外胎质量缺陷。 相似文献
9.
In this paper, aramid fiber (AF)/ethylene-propylene-diene monomer (EPDM) microcellular foams added with different content of AF are prepared by the supercritical foaming method. The effect of the AF content on the rheological behavior, mechanical properties, thermal properties and cellular structure of the AF/EPDM microcellular foams has been systematically studied. The research illustrates that compared with pure EPDM, the AF/EPDM matrix has greater viscosity and modulus, which is conducive to reduce the cell size and increase its density. And the thermal stability of EPDM foams is improved with the addition of aramid fiber. Meanwhile, when the content of AF is added to 1 wt%, the AF/EPDM microcellular foam exhibits a relatively low thermal diffusion coefficient and apparent density with the thermal conductivity to 0.06 W/mK. When the AF is added to 5 wt%, the tensile strength of the AF/EPDM microcellular foam increases to 1.95 MPa, which is improved by 47% compared with that of the pure EPDM foam. Furthermore, when the compressive strain reaches to 50%, the compressive strength of the AF/EPDM microcellular foam is 0.48 MPa, improved by 296% compared with that of the pure EPDM foam. 相似文献
10.
以SZ36-1环烷基减四线馏分油为原料,考察加氢精制-糠醛单段萃取以及加氢精制-糠醛两段萃取两种组合工艺制备高芳烃含量环保橡胶增塑剂的技术可行性。结果表明:采用两种组合工艺均可以制得满足国家标准指标要求的橡胶增塑剂产品,加氢精制-糠醛单段萃取可以制得环保橡胶增塑剂A1220产品,在产品收率上更具优势;加氢精制-糠醛两段萃取可以制得环保橡胶增塑剂A1820产品,在产品的芳碳率上更具优势。 相似文献