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1.
Fernanda Monedeiro Viorica Railean-Plugaru Maciej Monedeiro-Milanowski Pawe Pomastowski Bogusaw Buszewski 《International journal of molecular sciences》2021,22(9)
Considering the advent of antibiotic resistance, the study of bacterial metabolic behavior stimulated by novel antimicrobial agents becomes a relevant tool to elucidate involved adaptive pathways. Profiling of volatile metabolites was performed to monitor alterations of bacterial metabolism induced by biosynthesized silver nanoparticles (bio-AgNPs). Escherichia coli, Enterococcus faecalis, Klebsiella pneumoniae and Proteus mirabilis were isolated from pressure ulcers, and their cultures were prepared in the presence/absence of bio-AgNPs at 12.5, 25 and 50 µg mL−1. Headspace solid phase microextraction associated to gas chromatography–mass spectrometry was the employed analytical platform. At the lower concentration level, the agent promoted positive modulation of products of fermentation routes and bioactive volatiles, indicating an attempt of bacteria to adapt to an ongoing suppression of cellular respiration. Augmented response of aldehydes and other possible products of lipid oxidative cleavage was noticed for increasing levels of bio-AgNPs. The greatest concentration of agent caused a reduction of 44 to 80% in the variety of compounds found in the control samples. Pathway analysis indicated overall inhibition of amino acids and fatty acids routes. The present assessment may provide a deeper understanding of molecular mechanisms of bio-AgNPs and how the metabolic response of bacteria is untangled. 相似文献
2.
Nowadays, oil pollution has become more serious, which causes great threats both to the ecological environment and human life. In this study, a novel type of multifunctional deacetylated cellulose acetate/polyurethane (d-MCA:MTPU) composite nanofiber membranes for oil/water separation are successfully fabricated by electrospinning, which show super-amphiphilicity in air, super-hydrophilicity in oil, and oleophobicity in water. All the d-MCA:MTPU composite nanofiber membranes with different mass ratios can be used as water-removing, oil-removing, and emulsion separation substance only by gravity driving force. The highest separation flux for water and oil reaches up to 37 000 and 74 000 L m−2 h−1, respectively, and all the separation efficiencies are more than 99%. They have outstanding comprehensive mechanics performance, which can be controlled by simply adjusting the mass ratios. They show excellent antifouling and self-cleaning ability, endowing powerful cyclic stability and reusability. Those results show that d-MCA:MTPU composite nanofiber membranes have great application prospects in oil/water separation. 相似文献
3.
Izhar AHMAD Kashif Ali KHAN Tahir AHMAD Muhammad ALAM Muhammad Tariq BASHIR 《Frontiers of Structural and Civil Engineering》2022,16(5):589
In recent building practice, rapid construction is one of the principal requisites. Furthermore, in designing concrete structures, compressive strength is the most significant of all parameters. While 3-d and 7-d compressive strength reflects the strengths at early phases, the ultimate strength is paramount. An effort has been made in this study to develop mathematical models for predicting compressive strength of concrete incorporating ethylene vinyl acetate (EVA) at the later phases. Kolmogorov-Smirnov (KS) goodness-of-fit test was used to examine distribution of the data. The compressive strength of EVA-modified concrete was studied by incorporating various concentrations of EVA as an admixture and by testing at ages of 28, 56, 90, 120, 210, and 365 d. An accelerated compressive strength at 3.5 hours was considered as a reference strength on the basis of which all the specified strengths were predicted by means of linear regression fit. Based on the results of KS goodness-of-fit test, it was concluded that KS test statistics value (D) in each case was lower than the critical value 0.521 for a significance level of 0.05, which demonstrated that the data was normally distributed. Based on the results of compressive strength test, it was concluded that the strength of EVA-modified specimens increased at all ages and the optimum dosage of EVA was achieved at 16% concentration. Furthermore, it was concluded that predicted compressive strength values lies within a 6% difference from the actual strength values for all the mixes, which indicates the practicability of the regression equations. This research work may help in understanding the role of EVA as a viable material in polymer-based cement composites. 相似文献
4.
Stefano Mariani Antonino Amedeo La Mattina Alessandro Paghi Lucanos Strambini Giuseppe Barillaro 《Advanced functional materials》2021,31(26):2100774
Here, a fluoride-assisted route for the controlled in-situ synthesis of metal nanoparticles (NPs) (i.e., AgNPs, AuNPs) on polydimethylsiloxane (PDMS) is reported. The size and coverage of the NPs on the PDMS surface are modulated with time and over space during the synthetic process, leveraging the improved yield (10×) and faster kinetics (100×) of NP formation in the presence of F− ions, compared to fluoride-free approaches. This enables the maskless preparation of both linear and step gradients and patterns of NPs in 1D and 2D on the PDMS surface. As an application in flexible plasmonics/photonics, continuous and step-wise spatial modulations of the plasmonic features of PDMS slabs with 1D and 2D AgNP gradients on the surface are demonstrated. An excellent spatially resolved tuning of key optical parameters, namely, optical density from zero to 5 and extinction ratio up to 100 dB, is achieved with AgNP gradients prepared in AgF solution for 12 minutes; the performance are comparable to those of commercial dielectric/interference filters. When used as a rejection filter in optical fluorescence microscopy, the AgNP-PDMS slabs are able to reject the excitation laser at 405 nm and retain the green fluorescence of microbeads (100 µm) used as test cases. 相似文献
5.
Shanshan Luo Jing Sun Anrong Huang Tingting Zhang Liangqiang Wei Shuhao Qin 《应用聚合物科学杂志》2019,136(21):47557
In situ microfibrillar reinforced composites with ethylene-vinyl acetate (EVA) as matrix and isotactic polypropylene (iPP) as dispersed fibrils were successfully fabricated by multistage stretching extrusion with an assembly of laminating-multiplying elements (LMEs). Four types of EVA with different apparent viscosity were utilized to study the influence of viscosity ratio on the morphology and mechanical properties of EVA/iPP in situ microfibrillar blends. The scanning electron micrographs revealed that the dividing–multiplying processes in LMEs could effectively transform the morphology of iPP phase into microfibrils and the morphology of iPP microfibrils strongly depended on the viscosity ratio. Higher viscosity ratio was favorable for formation of finer microfibrils with narrower diameter distribution. The morphology development of iPP with different viscosity ratio greatly affected the rheological and mechanical properties of EVA/iPP blends. The dynamic rheological results shown that the iPP microfibrils were helpful to increase the storage modulus and loss modulus. The tensile test indicated that the mechanical properties of EVA/iPP blends were controlled by the morphology of iPP phase and the polarity of EVA matrix. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47557. 相似文献
6.
光降解乙醛(CH3CHO)是一种新型高效的乙醛去除方法,通常采用TiO2作为光催化剂。然而TiO2对乙醛吸附能力较弱,对产物的选择性较低,电子-空穴对重组率较高,严重限制了对乙醛的降解性能。本研究通过在TiO2上负载CuAg纳米粒子(CuAg/TiO2),成功构建了高效稳定的光催化降解乙醛催化剂,有效解决了TiO2的固有缺陷。在自然光照射下,CuAg/TiO2对乙醛的降解率高达42.49%。连续4轮全光谱光催化降解乙醛,CuAg/TiO2活性均保持在98.89%以上。进一步的机理研究表明,CuAg/TiO2中的CuAg纳米粒子在光照下产生热电子,随后热电子转移到TiO2和吸附在Ag位点上的氧中。CuAg/TiO2上生成的超氧自由基能有效地降解乙醛,从而在乙醛降解过程中表现出优异的性能。 相似文献
7.
8.
《Advanced Powder Technology》2019,30(12):3088-3098
The purpose of this paper is to give process for preparing monodispersed silver particles with round shape having aspect ratio of 1, because the shape is suitable for preparing silver grids with fine pattern size. We found that the combination of gelatin and hydrazine gave the monodispersed silver particles with the aspect ratio of 1. Presence of the high molecular compounds is crucial probably because they are adsorbed on the surface of growing silver particles and control the uniform crystal growth. In addition, the relationship between these reaction conditions and the particle shape are discussed in detail. 相似文献
9.
铀铌铅多金属矿组成成分复杂,准确有效的测定其中的痕量银,有利于银的回收利用。采用HCl-HNO3-HF-HClO4处理铀铌铅多金属矿样品,以HCl(1+4)-2g/L酒石酸为测定介质,以λAg=328.068nm为分析谱线,建立了高分辨连续光源原子吸收光谱法(HR-CS-AAS)测定铀铌铅多金属矿样品中痕量银的新方法。对仪器参数进行了优化,确定采用迭代基线校正(IBC)背景校正方式,CCD检测器有效像素点选择5个;由银的平均吸收光谱图和吸光度-波长-时间三维吸收光谱图可知,银的CCD检测器分辨率为0.0020nm/pixel,λAg=328.068nm在327.86~328.27nm范围内没有受到溶液中其他共存元素的谱线干扰。在优化的实验条件下,银的吸光度与其质量浓度在0.40~1.60μg/mL范围内运用二次方程最小二乘法拟合校准曲线,相关系数为0.9999,特征浓度为0.0148μg/mL,方法检出限为0.0013μg/mL。将HR-CS-AAS测定样品中银的参数与空心阴极灯原子吸收光谱法(HCL-AAS)相比,其检出限更低,特征浓度更低,标准溶液系列的吸光度更高。按照实验方法对铀铌铅多金属矿样品中的银进行测定,结果与电感耦合等离子体质谱法基本一致,相对标准偏差(RSD,n=9)为0.63%~3.3%。按实验方法在铀铌铅多金属矿样品中加入银标准溶液进行加标回收试验,回收率为97%~104%,满足国家地质矿产行业标准DZ/T 0130—2006的要求。 相似文献
10.
采用尿素调节三水醋酸钠的相变温度到合适范围再添加膨胀石墨来降低过冷度,研制了高性能的三水醋酸钠-尿素-膨胀石墨混合相变材料,并对其在电地暖中的应用性能进行了研究。结果表明,当尿素质量分数为36.5%、膨胀石墨添加量为4%(质量)时,所得混合相变材料的熔化焓高达209.1 J/g,熔点在31.98℃,过冷度仅为2.04℃,热导率为2.349 W/(m·K),热可靠性良好;将用该混合相变材料制成的相变板安装在实验房的电地暖中时,实验房的热舒适度随着相变材料层厚度的增加而增加,但也带来加热时间和用电量的增加;当相变材料层厚度为10 mm时,电加热温度适宜设置在45℃;在热舒适度相当的条件下,有相变板的实验房与无相变板的参比房相比具有用电量小及电费低的优势。 相似文献