Oligo(ethylene oxide) side‐chain steric screening effects on conductimetric properties of grafted poly(4‐vinylpyridinium) salts in aqueous solutions

A set of poly[N‐oligo(ethylene oxide)yl 4‐vinylpyridinium tosylate] (P4VOEOOTs) has been prepared by spontaneous polymerization of 4‐vinylpyridine. This method gives a grafted polyelectrolyte having a positive charge on every backbone pyridinic moiety. The P4VP15Ts, P4VP164Ts, P4VP350Ts and P4VP750Ts aqueous solution conductivities were determined in the concentration range from 6 × 10^?4 to 10^?2 M at 25 °C. The variation of the conductivity versus concentration of the investigated system exhibits typical polyelectrolyte behaviour. The polyelectrolyte mobility was found to be dependent on the oligo(ethylene oxide) (OEO) side‐chain length. Manning's rod‐like model fails to describe these results. A simple steric effect is proposed to explain the influence of the OEO length. Copyright © 2003 Society of Chemical Industry     

Synthesis and photosensitivity of acryloylmorpholine copolymers with a pendant (meth)acryloyl group

We have developed new photopolymers that have superior waterproof properties and that can easily interact with polyfunctional acrylate compounds, thus serving as hydrophobic photocrosslinking reagents. Acryloylmorpholine monomers whose homopolymers were less moisture absorbing than the usual water‐soluble polymers but were still water soluble to a good degree, were copolymerized with other acryloyl monomers. We then introduced the photosensitive (meth)acryloyl group to side chains of the resulting polymers. Among six copolymers examined, the copolymers composed of acryloyl morpholine, hydroxyethyl acrylate, ethyl, or methyl methacrylate, and methacryloyl isocyanate were found to have nicely balanced hydrophilicity and waterproof properties, in addition to good compatibility with hydrophobic photocrosslinking reagents. The composite polymers thus obtained were confirmed to be promising photopolymers usable even in a highly humid environment. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 684–692, 2003     

水溶性油墨用富马酸改性松香树脂的研制

介绍了一种水溶性富马酸改性松香树脂的制备方法 ,选取了较佳的工艺条件 ,本产品经国内几家油墨厂使用 ,结果表明适合水溶性油墨的应用要求     

钠水玻璃涂料的固化技术及其应用

论述了五种固化剂改性钠水玻璃的原理及在涂料中的应用，重点介绍了用可溶性金属盐必性钠水玻璃制作涂料的技术关键。     

Solubility of amaranth seed proteins in sodium sulphate and sodium chloride: the main factor in quantitative extraction for analysis

Nitrogen was extracted more efficiently from amaranth seed with 0.04 M Na₂SO₄ (5% w/v) than with either 0.09 M or 0.17 M NaCl (5% or 10% w/v), despite both solutions having the same ionic strength (μ= 1). Solubility of saline soluble proteins (albumin ± globulin) was very poor in either water or 1M NaCl, but increased in 0.4M NaCl at alkaline pH between 7 and 10. Globulins were very soluble in 0.4M NaCl at a pH 9. Albumin was the main storage protein. Saline soluble proteins formed very weak gels.     

Effect of harvesting time and fruit size on titratable acidity, soluble solid and distribution of limonin in Thai tangerine juice

The effect of fruit size and harvesting of Thai tangerine fruit ( Citrus reticulata , Blanco) at different growth stages, 8–12 months after fruit set, on the distribution of limonin in whole fruit as well as in the individual fruit parts and extracted juice was investigated. The highest limonin concentration was observed in seed, followed by albedo, flavedo, segment membrane and juice sacs in decreasing order. The limonin concentration in juice as well as in whole fruit was decreased when fruit was harvested 8–12 months of fruit set. Increasing harvesting time from 8 to 12 months showed corresponding decreases in the amount of limonin in flavedo, albedo and seed. There was a decrease in titrable acidity and increase in total soluble solid and total soluble solid/titrable acidity ratio of juice with a later than normal harvesting time. However, fruit size showed no effect on limonin content and other properties of juice extracted from tangerine.     

Controlled release of insecticide carbaryl from sodium alginate,sodium alginate/gelatin,and sodium alginate/sodium carboxymethyl cellulose blend beads crosslinked with glutaraldehyde

Interpenetrating network polymeric beads of sodium alginate (NaAlg) and its blend with gelatin (gels) or sodium carboxymethyl cellulose (NaCMC) have been prepared by crosslinking with a common crosslinking agent, glutaraldehyde (GA), for the release of insecticide carbaryl (Carb). The prepared beads were characterized by Fourier transform infrared spectroscopy and scanning electron microscopy. Scanning electron microscopy confirmed the spherical nature and surface morphology of the particles. Bead characteristics, such as carbaryl entrapment efficiency, particle size, equilibrium swelling degree, and carbaryl release kinetics, were determined. The effects of the preparation conditions, such as Carb/NaAlg ratio, time of exposure to GA, blend ratio, and temperature of release medium on the carbaryl release, were investigated for 25 days at 25°C. It was observed that the carbaryl release decreased with increase in crosslinking of network, while it increased with increase in Carb/NaAlg ratio and temperature. The release of carbaryl also increased with increase in Gel or NaCMC content in the blend beads. The highest carbaryl release was found to be 100%, for the beads that were prepared with 1 : 1 NaAlg/Gel at 16 days. The diffusion coefficients have been calculated for the transport of insecticide through the polymeric beads, using initial time approximation method. These values were also consistent with the carbaryl release data. The carbaryl release from most of the bead formulations followed the Fickian trend. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1310–1319, 2006     

EDTA滴定法精确测定可溶性氯化物中氯含量

介绍了利用EDTA滴定法精确测定可溶性氯化物中氯含量的原理、条件和方法。试样溶解后,先在强酸性介质中用AgNO3沉淀Cl-离子,沉淀过滤后,加入过量Ni(CN)42-发生置换反应,然后在pH9.5的氨性缓冲溶液中,以紫脲酸铵为指示剂,用EDTA标准溶液滴定置换出的Ni2 离子。结果表明,改进后的本法,准确、干扰小、终点现象明显,是一种准确的测氯方法。测定结果的变异系数仅为0.18%,回收率为98.3%～100.9%。     

水基液压液用聚醚的研制

详细总结了国内外水基液压液的研制、使用情况 ,合成水溶性聚醚所用的各种催化剂。利用开发出的工艺可在现有的聚醚生产线上生产水溶性聚醚 ,该工艺条件、生产配方合理 ,生产重现性好 ,生产出的JH系列产品比国内的PE系列产品性能优良 ,且可取代进口同类产品 ,满足国内市场需要     

水溶性聚合物在油田钻井液中的应用

介绍国内水溶性聚合物钻井液处理剂的研究与应用情况，水溶性聚合物可用泥浆降滤失剂，增粘剂，絮凝剂，降粘剂和防塌型，它包括天然高分子材料和合成聚合物。