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1.
Three N-heteroleptic Pt(II) complexes, [Pt(C^C)(O^O)] [O^O = acetylacetonate, C^C = 1-phenyl-1,2,4-triazol-5-ylidene (1), C^C = 4-phenyl-1,2,4-triazol-5-ylidene (2), C^C = 2-phenylpyrazine (3)] have been investigated with density functional theory (DFT) and time-dependent density functional theory (TDDFT). The radiative decay rate constants of complexes 1–3 have been discussed with the oscillator strength (fn), the strength of spin–orbit coupling (SOC) interaction between the lowest energy triplet excited state (T1) and singlet excited states (Sn), and the energy gaps between E(T1) and E(Sn). To illustrate the nonradiative decay processes, the transition states between triplet metal-centered (3MC) and T1 states have been optimized and were verified with the calculations of vibrational frequencies and intrinsic reaction coordinate (IRC). In addition, the minimum energy crossing points (MECPs) between 3MC and ground states (S0) were optimized. At last, the potential energy curves relevant to the nonradiative decay pathways are simulated. The results show that complex 3 has the biggest photoluminescence quantum yield because the complex 3 has the biggest radiative decay rate constant and the smallest nonradiative decay rate constant in complexes 1–3. 相似文献
2.
扩声系统在体育馆中的典型应用 总被引:1,自引:1,他引:0
针对体育馆举办不同类型的大型活动,分别对扩声系统的音质及扩声特点提出要求,以人声和乐器声的频率特性为依据,阐述了调音师在不同场合中对于不同的扩声对象按所要达到的扩声效果应采取的调控方法。 相似文献
3.
Significant increases in the activity of vanadium(III) amidinate catalysts for ethylene polymerization have been obtained by immobilization on a MgCl2‐based support prepared by reaction of AlEt3 with a MgCl2/ethanol adduct. Catalyst immobilization and activation on this type of support prevents the rapid decay in activity observed under homogeneous polymerization conditions with unsupported catalysts. Stable polymerization activity is also observed with analogous titanium(III) complexes. Polyethylene with narrow molecular weight distribution and spherical particle morphology is obtained without reactor fouling. Copyright © 2005 Society of Chemical Industry 相似文献
4.
本文应用NOPD技术设计了一种复合多层板,按照四边固定薄板结构的模态振型,对不同的NOPD填充形式,进行声学实验,来评价不同填充形式在降低板类结构声辐射方面的效果,分析了该类板结构声振耦合的关系并验证了NOPD技术对声辐射控制的作用。 相似文献
5.
应用音平化渣图象分析和指导转炉造渣操作 总被引:3,自引:1,他引:2
利用音平化渣图象可以清晰地看出在转炉造渣过程中何时发生喷溅,何时发生炉渣返干和何时化渣正常。应用音平化渣图象和炉渣三元相图,可以正确地分析发生喷溅和返干的原因,从而找到避免突发性喷溅和严重返干的方法。正确的枪位和炉渣碱度控制是实现平稳吹炼的保证,而音平化渣图象能帮助操作工实现这一目标。 相似文献
6.
7.
8.
Ideal-gas thermodynamic properties for natural-gas applications 总被引:2,自引:0,他引:2
Calculating caloric properties from a thermal equation of state requires information such as isobaric heat capacities in the ideal-gas state as a function of temperature. In this work, values for the parameters of thec
p
0
correlation proposed by Aly and Lee were newly determined for 21 pure gases which are compounds of natural gas mixtures. The values of the parameters were adjusted to selectedc
p
0
data calculated from spectroscopic data for temperatures ranging from 10 to 1000 K. The data sources used are discussed and compared with literature data deduced from theoretic models and caloric measurements. The parameters presented will be applied in a current GERG project for evaluating equations of state (e.g., the AGA 8 equation) for their suitability for calculating caloric properties. 相似文献
9.
The photoconductive properties of a carotenoid polyene,β-Apo-8′ carotenal in polycrystalline form has been studied. The growth of the photocurrent shows an overshoot in the growth-time
curve before steady state value is attained. This behaviour of photocurrent is proposed to be due to higher value of recombination
coefficient than trapping coefficient. From the temperature dependence study it is observed that the steady state photocurrent,
at first increases with increase of temperature, attains a maximum at a particular temperatureT
max and then decreases with temperature. TheT
max value agrees with the temperature above and below which steady state photocurrent is attained differently. Monomolecular
and bimolecular recombination processes at two temperature regimes are proposed to account for the observed behaviour. The
dependence of photocurrent with excitation light intensity and wavelength study provide information on the carrier generation
processes. The fast decay of photocurrent have been observed at different temperatures and from this study the decay constant
is calculated and it is found to be temperature independent. 相似文献
10.
Air cleaning as a means of mitigating the risks arising from exposure to indoor radon progeny has been evaluated in a single-family house in the north eastem US. using an automated, semi-continuous activity-weighted size distribution measurement system. The measurements included radon concentration, condensation nuclei count, and activity-weighted size distribution of radon decay products. Measurements were made in the house with and without an operating air filtration system and with various particle sources common to normal indoor activities operating. Aerosols were generated by running water in a shower, candle burning, cigarette smoking, vacuuming, opening doors, and cooking. Using a room model, the changes in attachment rates, average attachment diameters, and deposition rates of the unattached fraction with and without the air cleaning system were calculated. In the presence of active aerosol sources, the air filtration unit typically reduced the concentration of particles within the hour following the end of particle generation. After candle burning, cigarette smoking, and vacuuming in the bedroom, the reductions of PAEC by air filtration are about 60% with the air filtration system operating in the bedroom. During cooking in the kitchen, the reductions of PAEC in the bedroom with the air filtration system were about 40%. However, for all cases the dose reductions were smaller than the particle and PAEC reductions. For those particles that were generated within the bedroom, there was a 20% to 50% reduction in dose. In the case of cooking where the door was open and particles infiltrated from the rest of the house, the dose reduction was only 5% on average and appears to be insignificant. Thus, the dose reductions were h e r than the reductions in activity concentration, but there were no cases where the estimated dose actually increased. 相似文献