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1.
Electroinitiated cationic copolymerisation of indene and styrene was investigated by constant potential electrolysis. Effects of copolymerisation potential and temperature on the copolymer composition and the reactivity ratios are discussed. The reactivity ratios of the monomers were calculated according to the integrated Lewis-Mayo equation. 相似文献
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Research on Poly(Styrene-Crylicacid)-Suported Neodymium Complex Catalytic Copolymerization of Styrene and 4-Vinylpyridine 相似文献
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《Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment》2013,30(4):723-733
Due to the 2011 labelling of styrene monomer as “reasonably anticipated to be a human carcinogen” by the National Institutes of Health’s National Toxicology Program (NTP) and the controversy over whether styrene oligomers mimic the physiological effects of estrogen, an updated review of styrene monomer and oligomers in food and food contact materials (FCMs) was performed. The concentrations of styrene monomer and oligomers were determined in 24 polystyrene (PS) products and ranged from 9.3 to 3100 mg kg–1 for the styrene monomer, 130–2900 mg kg–1 for the sum of three styrene dimers, and 220–16,000 mg kg–1 for the sum of six styrene trimers. Foods in contact with PS packaging had styrene monomer concentrations ranging from 2.6 to 163 ng g–1; dimer concentrations from the limit of quantitation (LOQ) to 4.8 ng g–1 and trimer concentrations were all below the LOQ (2 ng g–1). Diffusion coefficients (Dp) and partition coefficients (K) were also calculated for styrene dimers and trimers. The results presented here indicate that styrene monomer concentrations in foods have not significantly changed since the 1980s and monomer concentrations in food packaging quantified in this study were all below USFDA limits. Although styrene dimers and trimers are present in higher concentrations in PS FCMs than the monomer, their migration to food is limited because of their high K values (4 × 102 to 2 × 106) and their low diffusion coefficients in PS products. Additionally, diffusion coefficients calculated using USFDA-recommended food simulants and Arrhenius plots describing the temperature dependence of styrene dimers and trimers can be used in future calculations of dietary intake of the styrene oligomers. 相似文献
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用自制的苯乙烯.马来酸酐共聚物盐(SMA)对经过AKD施胶的漂白麦草抄造的纸进行了表面施胶实验,实验发现:SMA分子质量高,纸的施胶度增大,透气度值下降,相对分子质量超30000时,纸的施胶度不再有明显的提高,而透气度值则继续降低;钠盐的抗水性较差,但对纸页的成膜能力较强.且明显好于SMA铵盐;苯乙烯对马来酸酐比例越大,赋予纸页表面的抗水性和平滑度越好。与SMA共同进行表面施胶的阴离子淀粉对纸页平滑度和IGT拉毛强度的改善明显好于氧化淀粉;木薯淀粉表面施胶性能优于玉米淀粉。 相似文献
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Jozef P H Linssen Anneloes L G M Janssens Hanneke C E Reitsma Wender L P Bredie Jacques P Roozen 《Journal of the science of food and agriculture》1993,61(4):457-462
Taste recognition threshold concentrations (TRTC) of styrene were determined in samples of oil-in-water emulsions (30–300 g kg?1 oil) and yoghurts (1–30 g kg?1 fat), spiked with styrene. The observed TRTC increased linearly with increasing fat content and ranged from 0–3 to 2–1 mg kg?1 for the emulsions and from 36 to 171 g kg?1 for the yoghurts. Styrene equilibrium partition coefficients between emulsions and their respective vapour phases were determined. The concentrations of styrene in the continuous aqueous phase of the emulsions and yoghurts were calculated at the TRTC. The styrene concentrations in the continuous phase had constant values of about 15 g kg?1 indicating that perception of styrene for oil-in–water emulsions is determined by the aqueous phase of the emulsion. The concentrations of styrene in the vapor phases above the emulsions and yoghurts were also calculated and were found to be constant at the TRTC. This relationship probably resulted from the equilibrium of distribution of styrene between the respective phases. Commercial yoghurt packed in polystyrene beakers contained styrene levels in the range 2–11 g kg?1, much lower then the TRTC reported. 相似文献
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