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排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
Yuelong Ma Le Zhang Tianyuan Zhou Bingheng Sun Chen Hou Shunshun Yang Jin Huang Rui Wang Farida A. Selim Zhongying Wang Ming Li Hao Chen Yun Wang 《Journal of the European Ceramic Society》2021,41(4):2834-2846
Ce:Y3Al5O12 transparent ceramics (TCs) with appropriate emission light proportion and high thermal stability are significant to construct white light emitting diode devices with excellent chromaticity parameters. In this work, strategies of controlling crystal-field splitting around Ce3+ ion and doping orange-red emitting ion, were adopted to fabricate Ce:(Y,Tb)3(Al,Mn)5O12 TCs via vacuum sintering technique. Notably, 85.4 % of the room-temperature luminescence intensity of the TC was retained at 150 °C, and the color rendering index was as high as 79.8. Furthermore, a 12 nm red shift and a 16.2 % increase of full width at half maximum were achieved owing to the synergistic effects of Tb3+ and Mn2+ ions. By combining TCs with a 460 nm blue chip, a warm white light with a low correlated color temperature of 4155 K was acquired. Meanwhile, the action mechanism of Tb3+ ion and the energy transfer between Ce3+ and Mn2+ ions were verified in prepared TCs. 相似文献
2.
A new aqueous slurry-based laminated object manufacturing process for porous ceramics is proposed: firstly, an organic mesh sheet is pre-paved as a pore-forming template before slurry layer scraping; secondly, the 2D pattern is built with laser outline cutting of the dried mesh–ceramic composite layer; finally, the pore structure is formed after degreasing and sintering. Alumina parts with porosities of 51.5 %, round hole diameters of 80 ± 5 μm were fabricated using 70 wt. % solid content slurry and 100 mesh nylon net. Using an organic mesh as the framework and template not only reduces the risk of damage of the green body but also ensures the regularity, uniformity and connectivity of the micron scaled pore network. The layer-by-layer drying method avoids the delamination phenomenon and improves the paving density. The new method can realize the flexible design of the pore structure by using various organic mesh templates. 相似文献
3.
In this study, chemically bonded phosphate ceramic coatings (CBPCCs) with different contents of aluminum phosphate (AP) are prepared on stainless steel (AISI 304L). Differential scanning calorimetry, X-ray diffraction, contact angle test, and a tribocorrosion experiment are carried out to clarify the role of AP in the tribocorrosion performance of CBPCCs. The results show that, with the increase in the AP content, the enthalpy of curing increases because of the greater formation of the bonding phase AlPO4. Both in static corrosion and in tribocorrosion, the corrosion current density of CBPCCs achieves the lowest value when the weight ratio of AP to polytetrafluoroethylene is about 0.78. Additionally, the influence mechanism of AP on tribocorrosion is clarified. AlPO4 from the reaction between AP and Al2O3 has excellent mechanical properties and can enhance the wear resistance of CBPCCs by reducing the mechanical wear and the increased wear due to corrosion. The alumina particles wrapped by AlPO4 can form a dense and smooth surface and change the direction of electrolyte propagation, which leads to the increase in the tribocorrosion resistance of CBPCCs. 相似文献
4.
Optimization of room-temperature TCR of polycrystalline La0.9-xSrxK0.1MnO3 ceramics by Sr adjustment
Hongjiang Li Kaili Chu Xingrui Pu Xiaohan Yu Xiaoli Guan Shuaizhao Jin Xiang Liu 《Ceramics International》2021,47(1):94-101
High-density La0.9-xSrxK0.1MnO3 ceramics (LSKMO, A-site = La, Sr and K, 0 ≤ x ≤ 0.25) are successfully fabricated by using facile sol-gel method. Electrical properties are performed by using combination of phenomenological percolation (PP) model, double exchange (DE) mechanism, and Jahn-Teller (JT) effect. Moreover, X-ray diffraction and scanning electron microscopy are employed to analyze the structure and morphology of LSKMO ceramics. Valence states and ionic stoichiometry are assessed by using X-ray photoemission spectrometry. Results reveal that Sr2+ ions, substituting La3+ ions, significantly influenced DE mechanism and JT effect. In addition, Sr-doping plays essential role in improving electrical properties of LSKMO ceramics. At optimal doping content of x = 0.09, peak temperature coefficient of resistance (TCR) of the resistivity is found to be 11.56% K?1 at 297.15 K, which is optimal TCR for A-site K-occupied perovskite manganese oxides. These results confirm that polycrystalline LSKMO ceramics render high room-temperature TCR values due to Sr-doping. 相似文献
5.
Shammya Afroze Nico Torino Md Sumon Reza Nikdalila Radenahmad Quentin Cheok Paul F. Henry Abul K. Azad 《Ceramics International》2021,47(1):541-546
The structural and electrochemical properties of the double perovskite-type oxide, PrBaMnMoO6-δ, was investigated using neutron diffraction with in-situ conductivity measurement under a dry Argon atmosphere from 25 °C to 700 °C. A Rietveld refinement of the neutron diffraction data confirmed monoclinic symmetry in the P21/n space group. Rietveld refinement also confirms the unit cell parameters of a = 5.6567 (1) Å, b = 5.6065 (2) Å, c = 7.9344 (1) Å and β = 84.43° with reliable atomic positions and refinement factors (R-factors). Neutron diffraction data refinement shows two minor phases (<5%), an orthorhombic AB2O5 type phase of PrMn2O5 in the Pbam (No. 32) space group with unit cell parameters, a = 7.9672 (1) Å, b = 8.9043 (2) Å and c = 5.8540 (1) Å and a scheelite phase of BaMoO4 in the tetragonal I41/a (88) space group with the unit cell parameters, a = b = 5.9522 (1) Å, and c = 12.3211 (2) Å. Morphological images revealed a porous and intertwined microstructure. In-situ conductivity measurement shows that the total conductivity of this material was 130.84 Scm?1 at 700 °C. 相似文献
6.
Wire arc additive manufacturing(WAAM)has been investigated to deposit large-scale metal parts due to its high deposition efficiency and low material cost.However,in the process of automatically manufacturing the high-quality metal parts by WAAM,several problems about the heat build-up,the deposit-path optimization,and the stability of the process parameters need to be well addressed.To overcome these issues,a new WAAM method based on the double electrode micro plasma arc welding(DE-MPAW)was designed.The circuit principles of different metal-transfer models in the DE-MPAW deposition process were analyzed theoretically.The effects between the parameters,wire feed rate and torch stand-off distance,in the process of WAAM were investigated experimentally.In addition,a real-time DE-MPAW control system was developed to optimize and stabilize the deposition process by self-adaptively changing the wire feed rate and torch stand-off distance.Finally,a series of tests were performed to evaluate the con-trol system's performance.The results show that the capability against interferences in the process of WAAM has been enhanced by this self-adaptive adjustment system.Further,the deposition paths about the metal part's layer heights in WAAM are simplified.Finally,the appearance of the WAAM-deposited metal layers is also improved with the use of the control system. 相似文献
7.
In this communication, the structural, micro-structural, dielectric, electrical, magnetic, and leakage-current characteristics of a double perovskite (Y2CoMnO6) ceramic material have been reported. The material was synthesized via a high-temperature mixed-oxide route. The compound crystallizes in a monoclinic structure which is confirmed from preliminary X-ray structural study. The morphological study by using scanning electron micrograph reveals the almost homogeneous distribution of grains throughout the surface of the sample. The nature of frequency-dependence of dielectric constant has been described by the Maxwell-Wagner model. The occurrence of a dielectric anomaly in the temperature dependence of dielectric permittivity study demonstrates the ferroelectric-paraelectric phase transition in the material. From the Nyquist plots, we found the existence of both grain and grain boundary effects. The frequency dependence of conductivity was studied by the Jonscher’s Power law, and the conduction phenomenon obeys the large overlapping polaron tunneling model. By using the Arrhenius equation, the activation energy has been calculated which is nearly equal to the energy required for the hoping of the electron. Both impedance and conductivity analysis demonstrate that the sample exhibits negative temperature coefficient of resistance (NTCR) properties indicating the semiconducting type of material at high temperatures. The anti-ferromagnetic character of the material is observed from the nature of magnetic hysteresis loop. The leakage current analysis suggests that the conduction process in the material follows the space charge limited conduction phenomenon. Such material will be helpful for modern electronic devices and spintronic applications. 相似文献
8.
Yu Yang Zhiwei Zhou Bingchu Mei Yongqiang Zhang Xinwen Liu 《Ceramics International》2021,47(12):17139-17146
SrF2 transparent ceramic is a promising upconversion material due to the low phonon energy. The effect of different sintering temperatures on Er:SrF2 transparent ceramics was investigated. The suitable sintering temperature for Er:SrF2 transparent ceramics was 900 °C by hot-pressed sintering in this study. High quality of Er:SrF2 transparent ceramics with different doping concentrations were obtained. The upconversion luminescence spectra and decay behavior were compared between Er:SrF2 and Er:CaF2 transparent ceramics with different Er3+ doping concentration. The green emission of 5 at.% Er:SrF2 ceramic was much stronger than that of 5 at.% Er:CaF2 ceramic, while the red emission of Er:SrF2 ceramic was almost the same as that of Er:CaF2 ceramic. The upconversion luminescence lifetime of Er:SrF2 transparent ceramics was longer than that of Er:CaF2.All the results indicated Er:SrF2 transparent ceramics was a candidate for green fluorescent upconversion materials. 相似文献
9.
Nengbing Long Yanqing Fu Tianxiang Xu Dashuang Ding Shaoqian Zhang Shengzhi Sun Shiliang Kang Tiefeng Xu Shixun Dai Qiuhua Nie Changgui Lin 《Journal of the European Ceramic Society》2021,41(8):4584-4589
The confinement of CsPbX3 (X = Cl, Br, and I) perovskite nanocrystals (NCs) in a stabilized inorganic glass matrix is a new strategy for improving their long-term stability and promoting their applications in the optoelectronic field. Here, in situ nanocrystallization strategy is developed to precipitate CsPbBr3?xIx NCs with arbitrary I/Br ratio among an elaborately designed GeS2–Sb2S3-based chalcogenide glass matrix. Spherical CsPbBr3?xIx NCs are homogeneously distributed in the glass matrix after thermal treatment. The photoluminescence (PL) spectra show that the emission peaks of CsPbBr3?xIx NCs can be tuned from 570 nm to 722 nm with the replacement of Br by I. The fs transient absorption (TA) spectra reveal that there exists some structural defects in the NCs, leading to short PL decay life. This work would shed light on confining CsPbX3 NCs into glassy matrices, facilitating their future applications in photoelectronic fields. 相似文献
10.
《Ceramics International》2022,48(6):7593-7604
The ceramic core, produced by hot injection molding, is one of the critical components for manufacturing high-performance aircraft engine turbine blades. However, the injection molding process will cause defects such as burrs and flashes in the fine structure of the formed ceramic core. Manual trimming is necessary, but the trimming quality is poor, and the yield is low. In this paper, the online trimming method of ceramic cores is studied. Based on the orthogonal experiment method, the optimal laser parameters for processing the ceramic core's porous multi-scale particle structure material were obtained. Further, the problems of the match head and tail phenomenon and dimensional accuracy improvement in trimming ceramic cores have been studied. A path optimisation method is proposed to improve the quality and accuracy of the trimming profile effectively. Finally, the overall process flow of ceramic core trimming is elaborated, and experimental verification is given. The results show that the ceramic core online trimming method proposed in this paper has advantages of high precision and high yield compared with the manual method, which will have substantial potential application value in the aviation field. 相似文献