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1.
Barium strontium alumino silicate (BSAS); (Ba0.6Sr0.4Al2Si2O8) was synthesized through solid state reaction between BaCO3, SrCO3, Al2O3 and SiO2 subjected to wet milling in isopropanol for about 24 h. The sequence of the solid state reaction was studied by subjecting to DG/DTG from room temperature to 1550 °C. The crystallographic phase evolution was confirmed by X-ray diffraction of the powders calcined in the range 1000 to 1300 °C for 2 h. The monoclinic celsian phase obtained at 1300 °C, pelletized through uniaxial pressing was sinterable to 67 to 78% density in the temperature range of 1300 to 1500 °C. The density improved to 75 to 94% after ball milling for 76 h, while ZrO2 addition further improved the density by 2%. The celcian phase of BSAS was dispersed in isopropyl alcohol, milled for about 24 h and spray coated on to plain SiC and mullite precoated SiC substrates. Sintering of coated samples and characterization for weight gain/loss, microstructure, scratch test prove that mullite + BSAS coating is more effective than single layer coating of BSAS on SiC substrates.  相似文献   
2.
Herein, we report the photosensing property of CdS thin films. CdS thin films were coated onto glass substrates via a spray pyrolysis method using different spray pressures. Prepared films were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and optical and photoluminescence spectroscopy. XRD analysis demonstrated the growth of crystalline CdS films with crystallite sizes varying from 26 to 29 nm depending on the pressure. The SEM and EDAX analyses revealed nearly-stoichiometric CdS films with smooth surfaces and slight variation in grain morphology due to pressure changes. Optical measurements showed a direct bandgap varying from 2.37 eV to 2.42 eV due to pressure changes. A photodetector was also fabricated using the grown CdS films; the fabricated photodetector exhibited good performance depending on the spray pressure. A spray pressure of 1.5 GPa resulted in high photoresponsivity and external quantum efficiency.  相似文献   
3.
The morphology and microstructure of splats impact the comprehensive capability of a new coating methodology called chelate flame spraying (CFS). This study addresses the quantitative characterization of the spread morphologies of flame sprayed Er2O3 splats directly deposited under different spray conditions on aluminum alloy substrates with a mirror finish. The influence of the in-flight particle temperature and velocity, carrier gas type, and carrier gas ratio on the solidification mechanism of molten droplets was investigated. Image analysis methods were employed to identify single splats from the morphology observed with field-emission scanning electron microscopy (FE-SEM). In addition, Er2O3 films were synthesized on an Al–Mg alloy (A5052) substrate using N2 or O2 as the carrier gas. When O2 was used as the carrier gas, 109-μm-thick films were deposited on the A5052 substrate. The cross-sectional porosity of the films was 3.8%. In contrast, films with 101-μm thickness were synthesized on the A5052 substrate when N2 was used as the carrier gas. The cross-sectional porosity of these films was 13.8%. The results showed that the carrier gas type (N2) and carrier gas ratio had a significant effect on the flattening behavior of the molten droplets. A spraying method combined with multidimensional modes is proposed to control the morphology of the splats.  相似文献   
4.
醌类化合物是PM2.5中的一类有害物质。本研究建立了纸喷雾离子化衍生质谱法快速测定PM2.5中的醌类污染物。通过衍生化反应在醌化合物中引入氨基,提高醌在纸喷雾中的离子化效率。随后对衍生化试剂种类、电压、喷雾溶剂种类等反应条件进行优化。在最优实验条件下,采用内标法定量分析1,4-苯醌、甲基对苯醌、1,4-萘醌和1,4-蒽醌,4种化合物均呈现较好的线性关系,其检出限分别为4.49、20.89、0.13、0.17 ng。利用该方法分析PM2.5实际样品中的萘醌和蒽醌,均获得了较好的定性和定量结果。  相似文献   
5.
目的 在保证膜层耐蚀性能的前提下,降低镁锂合金等离子电解氧化过程中的能量消耗.方法 分别使用常规NaOH-Na2SiO3电解体系与自研的NaOH-Na2SiO3-Na2B4O7-Na3C6H5O7·2H2O(柠檬酸钠)低能耗电解体系,对LA91型镁锂合金进行等离子电解氧化,并探究其放电过程.采用扫描电子显微镜(SEM)、能谱仪(EDS)、掠入射X射线衍射仪(GIXRD),表征等离子电解氧化膜层的表面形貌、元素组成、物相组成.通过电化学极化曲线、盐雾试验,测试膜层的耐蚀性.结果 使用低能耗体系对镁锂合金进行等离子电解氧化处理,可将膜层的单位体积能耗降低至12.87 kJ/(dm2·μm),节约能耗约50.34%.在两个体系中制备的膜层表面均产生等离子电解氧化的特征性孔洞.低能耗体系膜层孔洞数量较少,但孔洞直径差异较大,孔隙率为14.21%;常规体系膜层孔洞大小均匀,但数量较多,孔隙率为13.93%.两个膜层表面的主要元素均为O、Mg、Na和Si.在低能耗体系中制备的膜层,主要物相为方镁石型MgO,而在常规体系中制备的膜层,物相组成较为复杂.盐雾试验和电化学极化曲线结果显示,在两种体系中进行等离子电解氧化,均能提升镁锂合金的耐蚀性.低能耗等离子氧化处理后,镁锂合金的腐蚀电流密度降低约3个数量级,腐蚀速率降低约2个数量级,自腐蚀电位正移0.261 V,有效地提升了镁锂合金的耐蚀性,并且耐蚀性的提升程度要优于常规体系.结论 使用低能耗体系电解液进行等离子电解氧化,能够形成孔洞特征不同于常规体系的等离子电解氧化膜层.与常规体系下制备的膜层相比,其厚度、孔隙率并无较大差异,但能够在节约较多能耗的情况下制备出耐蚀性能更好的等离子电解氧化膜层.  相似文献   
6.
采用纸毛细管喷雾(PCS)原位电离便携式质谱,在正离子模式下采集国内列管的40种卡西酮类毒品的质谱信息,分析一级质谱图[M+H]+峰,MS2、MS2_DDA模式下的特征碎片峰及其相对丰度比,建立用于40种卡西酮类毒品快速筛查的质谱数据库。研究发现,所有卡西酮类毒品均存在α位的C—N键裂解;根据最高离子峰是否为[M-H2O+H]+碎片峰可推测其是否存在仲、叔胺结构;N上取代基为吡咯烷基的卡西酮类毒品存在m/z 98+CnH2n系列特征峰;苯环上取代基为亚甲二氧基的卡西酮类毒品存在[M+H]+峰失去48 u或非[M+H]+峰失去30 u的特征离子峰。设计推断未知卡西酮类化合物的分析策略,并成功应用于10种待测物的结构推断。本方法可为卡西酮类毒品的结构鉴定和现场办案提供数据支持,有望成为打击卡西酮类毒品犯罪新的研判思路。  相似文献   
7.
解晓雷 《涂料工业》2021,51(3):35-39
防腐型熔结环氧粉末涂料与富锌环氧粉末涂料应用多年,但在很多高耐盐雾锈蚀环境仍无法完全替代溶剂型涂层。为提升粉末涂料耐盐雾性能,本研究通过对环氧富锌粉末涂料进行改性,在降低涂层体积电阻率的基础上提升牺牲阳极效率,使涂层达到液体涂料耐盐雾等级性能。结果表明:添加 0. 2%导电材料单壁碳纳米管与 30%片状锌粉以及其他功能助剂,最终制备涂层的 1 500 h中性盐雾单边锈蚀可控制在 1 mm以内,涂层综合性能也可达到液体富锌涂层指标,在一些环境可替换液体富锌涂层。  相似文献   
8.
Suspension plasma spraying (SPS) as a potential technique to prepare thermal barrier coatings (TBCs) has been attracting more and more attention. However, most reports on SPS were carried out in the atmosphere. Given the unique features of in-flight particles and plasma jets under low pressure, the resulting coatings are expected to be different from those under atmospheric pressure. In this article, yttria-stabilized zirconia (YSZ) thermal barrier coatings were prepared using suspension plasma spraying under different environmental pressures. The results show that as the environmental pressure decreased, the column-like structural coating turned into a vertical crack segmented structure, as well as a dramatic decrease in surface roughness. More nanoparticle agglomerates were formed in the coating under lower environmental pressures. The real porosity of the coating increased with a decrease in environmental pressure.  相似文献   
9.
This study deals with the manufacturing of catalyst-coated membranes (CCMs) for newcomers in the field of coating. Although there are many studies on electrode ink composition for improving the performance of proton-exchange membrane fuel cells (PEMFCs), there are few papers dealing with electrode coating itself. Usually, it is a know-how that often remains secret and constitutes the added value of scientific teams or the business of industrialists. In this paper, we identify and clarify the role of key parameters to improve coating quality and also to correlate coating quality with fuel cell performance via polarization curves and electrochemical active surface area measurements. We found that the coating configurations can affect the performance of lab-made CCMs in PEMFCs. After the repeatability of the performance obtained by our coating method has been proved, we show that: (i) edge effects, due to mask shadowing - cannot be neglected when the active surface area is low, (ii) a heterogeneous thickness electrode produces performance lower than a homogeneous thickness electrode, and (iii) the origin and storage of platinum on carbon powders are a very important source of variability in the obtained results.  相似文献   
10.
采用理论分析和试验研究相结合的方法,研究了阻垢剂投加在纺织厂后喷淋水硬度、电导率、pH值及临界pH指数(pHc)的变化情况。3#空调室为投加PESA阻垢剂的试验水池,5#空调室为未投加阻垢剂的对比水池。加入阻垢剂有明显的增溶螯合作用,使3#空调室喷淋水硬度高于5#,同时3#空调室喷淋水pH值和电导率先上升后下降,而5#空调室喷淋水pH值与电导率则是一直处于上升状态;5#空调室的喷淋水从第9 d开始,pH值一直大于pHc,结垢的趋势越来越严重,3#空调室喷淋水随着阻垢剂与成垢离子的不断反应,在运行21 d之后,pH值持续降低且小于pHc,水质处于不结垢稳定状态,阻垢剂具有良好的阻垢效果。  相似文献   
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