Electrical Characterization of Individual Cesium Lead Halide Perovskite Nanowires Using Conductive AFM

Perovskite nanostructures have attracted much attention in recent years due to their suitability for a variety of applications such as photovoltaics, light-emitting diodes (LEDs), nanometer-size lasing, and more. These uses rely on the conductive properties of these nanostructures. However, electrical characterization of individual, thin perovskite nanowires has not yet been reported. Here, conductive atomic force microscopy characterization of individual cesium lead halide nanowires is presented. Clear differences are observed in the conductivity of nanowires containing only bromide and nanowires containing a mixture of bromide and iodide. The differences are attributed to a higher density of crystalline defects, deeper trap states, and higher inherent conductivity for nanowires with mixed bromide–iodide content.     

Chemical reaction kinetics dataset of Cs-I-B-Mo-O-H system for evaluation of fission product chemistry under LWR severe accident conditions

In order to improve LWR source term under severe accident conditions, the first version of a fission product chemistry database named ‘ECUME’ was developed. The ECUME is intended to include several datasets of major chemical reactions and their effective kinetic constants for representative severe accident sequences. It is expected that the ECUME can serve as a fundamental basis from which fission product chemical models can be elaborated for use in the severe accident analysis codes. The implemented chemical reactions in the first version were those for representative gas species in Cs-I-B-Mo-O-H system from 300 to 3000 K. The chemical reaction kinetic constants were evaluated from either literature data or calculated values using ab-initio calculations. The sample chemical reaction calculation using the presently constructed dataset showed meaningful kinetics effects at 1000 K. Comparison of the chemical equilibrium compositions by using the dataset with those by chemical equilibrium calculations has shown rather good consistency for the representative Cs-I-B-Mo-O-H species. From these results, it was concluded that the present dataset should be useful to evaluate fission product chemistry in Cs-I-B-Mo-O-H system under LWR severe accident conditions, where kinetics effects should be considered.     

基于Vondark-Cepek滤波的氢铯时间尺度融合方法研究

氢原子钟和铯原子钟是当前国际原子时和各国标准时间产生的主要精密频率源,二者分别拥有优良的短期和长期稳定度特性。充分利用氢钟短稳和铯钟长稳进行时间保持成为时间产生过程中的一项关键技术。以提高时间尺度的长短期稳定性为目标,提出了Vondark-Cepek组合滤波的氢铯融合时间产生方法。首先利用AT1算法分别对氢钟组和铯钟组各产生一个钟组时间尺度,然后根据最小二乘原则对Vondark-Cepek组合滤波关键参数进行选取,进而通过氢钟组时间尺度时间序列的差分信息对铯钟组时间尺度进行性能增强,从而获得氢铯融合时间尺度。计算结果表明:该时间尺度1 h稳定度为3. 36×10-15,15 d稳定度为3×10-15,均优于氢铯单个时间尺度相同平均时间上的性能指标。     

Investigation of high-temperature chemical interaction of calcium silicate insulation and cesium hydroxide

ABSTRACT

The interaction of cesium hydroxide and a calcium silicate insulation material was experimentally investigated at high-temperature conditions to evaluate the possibility of unprecedented cesium retention under severe accident of boiling water reactor. The temperature where the interactions occurred and chemical species of cesium after the interaction were examined in this study. A thermogravimetry equipped with differential thermal analysis was used to analyze thermal events in the samples of mixed calcium silicate and cesium hydroxide under oxidizing and reducing atmospheric conditions with a maximum temperature of 1100°C. Before being mixed with cesium hydroxide, a part of calcium silicate was pretreated at high temperature to evaluate the effect of possible structural changes of this material due to a preceding thermal history and also for the sake of thermodynamic evaluation. It was found that for the original material, as xonotlite (Ca₆Si₆O₁₇(OH)₂) crystal, the endothermic reaction with cesium hydroxide occurred over the temperature range 575–730°C; meanwhile, for heat-treated material, which varied the crystal phase of original material to wollastonite (CaSiO₃), the interaction occurred over the temperature range 700–1100°C. The X-ray diffraction analyses have indicated that both types of calcium silicates regardless of the atmospheric conditions, cesium aluminum silicate, CsAlSiO₄, was formed with aluminum in the samples as an impurity or adduct. The insolubility of this formed cesium suggested the potency of cesium localization in the primary containment vessels on other structural materials that possess similar elements to that of calcium silicate insulation; hence, an effective decommissioning process could be developed.     

Cesium-adsorption capacity and hydraulic conductivity of sealing geomaterial made with marine clay,bentonite, and zeolite

Great amounts of soil and waste contaminated with radioactive cesium have been generated due to the decontamination work after the Fukushima Daiichi Nuclear Power Plant accident. The aim of this study is to develop a sealing geomaterial for use at the disposal facilities of the soil and waste constructed in the maritime environment. The geomaterial consists of marine clay, bentonite, and zeolite. The hydraulic conductivity and cesium-adsorption performance of the geomaterial were examined through laboratory tests with different proportions of bentonite and zeolite added to marine clay. It was concluded that the hydraulic conductivity could be reduced to the required level by increasing the amount of bentonite and that the cesium-adsorption capacity could be enhanced by increasing the amount of zeolite.     

Analysis of Cs-adsorption behavior using a column filled with microcapsule beads of potassium copper hexacyanoferrate

Ash-washing technology is a crucially important technology for removing radioactive Cs from contaminated ash. For that technology, Cs⁺ removal from the ash-washing solution by the adsorbent is necessary. This study was conducted to establish rapid preparation of appropriate adsorption columns for Cs⁺ uptake. A one-site model was not used for analysis because the model cannot accommodate sites with different adsorption speed. Results demonstrated that the adsorption behavior of the column filled with the granules of potassium copper hexacyanoferrate was well reproduced by a two-site adsorption model with parameters chosen through analysis of batch adsorption test results.     

Computer Simulation Study of Transient Diffusion of Cesium through Granite with Unsteady-State Diffusion Model

A steady-state diffusion model has been used widely to determine the diffusivities of radionuclides in rocks. Buffer container at the source solution side is used to keep the concentration constant. It is suitable for non-sorptive species, but not for sorptive species. Some researchers proposed a unsteady-state diffusion model recently. It is possible to use simple experimental apparatus without buffer container to measure the diffusivity with this model. To obtain the diffusional information more easily according to the sorption properties of radionuclides, through- diffusion experiments were performed in granites. Methods of determining of diffusivities are discussed according to sorption properties of species. For the non-sorptive species, the steady- state diffusion model was effective to determine the diffusivity. For the sorptive species, the analytical solution of the unsteady-state diffusion model found to be more appropriate to determine the diffusivity. Surface diffusion of sorbed species on rock did important role in diffusive transport.     

Measurement of Thermal Neutron Cross Section of 137Cs(n, γ)138Cs Reaction

A calculational model for a modified diffusion coefficient has been developed to incorporate the neutron streaming effect in heterogeneous low-density channels accurately into diffusion theory calculations. The model uses a supercell, and the axial and radial diffusion coefficients of the heterogeneous inner cell are so defined that they can reproduce Benoist's axial and radial diffusion coefficients of the supercell when the diffusion coefficient of the outer cell is given as 1/3 Σ_tr . In the case of the axial diffusion coefficient, the axial buckling effect is taken into account by modifying the neutron path length within the streaming channel in calculating the collision probabilities. This model has been applied to an RZ fast reactor Core model with a gas expansion module (GEM). By using the axial diffusion coefficient obtained with the presented model, calculational error of GEM worth was reduced to less than 1/7 compared to the formula of Rowlands and Eaton.