Stable Light-Emitting Electrochemical Cells Using Hyperbranched Polymer Electrolyte

The choice of an adequate electrolyte is a fundamental aspect in polymer light-emitting electrochemical cells (PLECs) as it provides the in situ electrochemical doping and influences the performance of these devices. In this study, a hyperbranched polymer (Hybrane DEO750 8500) blended with a Li salt is used as a novel electrolyte in state-of-the-art Super Yellow (a polyphenylenevinylene) based LECs. Due to the desirable properties of the hyperbranched polymer and the homogeneous and smooth films that it forms with the emitting polymer, PLEC with excellent electroluminescent properties are obtained using a pulsed current bias scheme. The devices are very stable, with lifetimes in excess of 2000 h with initial luminance values above 450 cd m⁻², a peak efficiency of 12.6 lm W⁻¹, and sub-minute turn-on times. The stability of the devices is also studied by measuring the photoluminescence (PL) of the semiconductor during electroluminescent operation. The findings suggest that it is possible to observe the quenching of the PL in vertically stacked devices due to the advancement of the doped fronts in the film and an immediate PL recovery when the bias is removed.     

New insight into subcritical rupture of SiC-based filaments at intermediate temperatures (400–900 °C) under air

The delayed failure of SiC fibrous reinforcement has continuously been investigated to warrant the long term performances of Ceramic Matrix Composite (CMC). Chiefly assessed on multifilament tow samples to alleviate some handling difficulties, subcritical crack growth (SCG) parameters are however ruled by structural artifacts which hinder the identification of intrinsic filament behavior. In this paper, we propose to estimate the true filament parameters for 5 fiber types from bundle behavior using a recently communicated Monte Carlo algorithm integrating flaw and stress distributions through a deterministic fracture mechanics law under Paris’ formulation. So computed tow lifetime are broadly dispersed, encompassing raw data, and show a structure-dependent scale effect, revealed by n_filament>n_tow where n is the stress exponent. The relationship between SCG coefficient and chemical composition of the substrate is discussed and highlights the major effect of doping elements (Ti or Zr), oxygen or hydrogen content.     

基于联合节点行为策略的WSN覆盖控制算法

针对无线传感器网络在对移动目标节点覆盖过程中出现网络能量快速消耗问题，提出了一种基于联合节点行为策略的覆盖算法。根据网络模型建立传感器节点与目标节点从属关系，确定覆盖关联模型；利用概率理论求解邻居节点冗余覆盖度，确定最少传感器节点数量；给出了邻居节点覆盖期望值的求解方法；仿真实验表明，该算法与其他算法在网络覆盖率和网络生存周期两个性能指标上均提升了12.39%和15.01%，从而验证了算法的有效性。     

Theoretical kinetic study of the reaction between dimethyl disulfide and OH radicals

The potential energy profile of the reaction between dimethyl disulfide and OH^? radicals is explored by utilizing ab initio and hybrid meta density functional theory methods. Having the energies and structural data of the stationary points, statistical rate theories, such as transition state theory and variable reaction coordinate-transition state theory, are employed to compute the overall rate constants, and discuss the mechanism and product channels. On the basis of the calculations, the overall rate coefficient is predicted to be 2.49?×?10^?10?cm³?molecule^?1?s^?1 at 298?K. It is found that in the most favorable pathway, the reaction proceeds via formation of the relatively unstable intermediate CH₃S^?(OH)SCH₃ decomposing rapidly to yield CH₃S^?+CH₃SOH.     

Coverage control algorithm for wireless sensor networks based on non-cooperative game

For the redundancy coverage of nodes leads to the phenomenon of low energy efficiency,Non-cooperative game theory was used to solve it.A revenue function was proposed,which considering the coverage of nodes and the residual energy.The lifetime of the node and network path gain were applied to revenue function.The network topology was built by nodes with the appropriate work strategy.Control algorithm coverage in wireless sensor network was proposed based on Non-cooperative game theory.A Nash equilibrium between the coverage rate and the residual energy was proved,and the return function converged to the Pareto optimal.Experiments show that the algorithm can provide reasonable coverage of network nodes and ensure energy efficiency.     

Fatigue strength evaluation of self-piercing riveted Al-5052 joints under different specimen configurations

In this study, static and fatigue tests were conducted using coach-peel, cross-tension and tensile–shear specimens with Al-5052 plates for evaluation of the fatigue strength of the SPR joints. For the coach-peel, cross-tension and tensile–shear geometries, the ratios of the fatigue endurance limit to static strength were 11%, 14% and 34%, respectively, assuming fatigue cycles of 10⁶ for an infinite lifetime. The equivalent stress intensity factor range can properly predict the current experimental fatigue lifetime. Fatigue crack initiation occurred due to fretting damage between the upper and lower sheets and between the rivet and these sheets.     

Multilevel approach to lifetime assessment of steam turbines

This paper presents a multilevel methodology for a steam turbine lifetime assessment based on the damage calculation, probabilistic analysis and fracture mechanics considerations. Creep-fatigue damage calculations serve as a basis for evaluating the current lifetime expenditure and for defining additional steps of analysis. The need for the use of probabilistic analysis results from the inherent uncertainty in estimating the lifetime expenditure primarily caused by scatter in material properties. Fracture mechanics considerations are helpful in determining additional safety margins for components containing cracks. This methodology has been illustrated using an example of the lifetime calculations of a high-temperature steam turbine rotor. The calculations were based on the results of 2D numerical simulations performed for steady state and transient operating conditions.     

Maximizing lifetime in wireless sensor networks with multiple sensor families

Wireless sensor networks are generally composed of a large number of hardware devices of the same type, deployed over a region of interest in order to perform a monitoring activity on a set of target points. Nowadays, several different types of sensor devices exist, which are able to monitor different aspects of the region of interest (including sound, vibrations, proximity, chemical contaminants, among others) and may be deployed together in a heterogeneous network. In this work, we face the problem of maximizing the amount of time during which such a network can remain operational, while maintaining at all times a minimum coverage guarantee for all the different sensor types. Some global regularity conditions in order to guarantee a fair level of coverage for each sensor type to each target are also taken into account in a second variant of the proposed problem. For both problem variants we developed an exact approach, which is based on a column generation algorithm whose subproblem is either solved heuristically by means of a genetic algorithm or optimally by an appropriate ILP formulation. In our computational tests the proposed genetic algorithm is shown to be able to dramatically speed up the procedure, enabling the resolution of large-scale instances within reasonable computational times.     

Intravital FRET: Probing Cellular and Tissue Function in Vivo

The development of intravital Förster Resonance Energy Transfer (FRET) is required to probe cellular and tissue function in the natural context: the living organism. Only in this way can biomedicine truly comprehend pathogenesis and develop effective therapeutic strategies. Here we demonstrate and discuss the advantages and pitfalls of two strategies to quantify FRET in vivo—ratiometrically and time-resolved by fluorescence lifetime imaging—and show their concrete application in the context of neuroinflammation in adult mice.     

Effect of sodium doping on graded Cu(In1−xGax)Se2 thin films prepared by chemical spray pyrolysis

In the present work we have studied the effect of Na on the properties of graded Cu(In_1−xGa_x)Se₂ (CIGS) layer. Graded CIGS structures were prepared by chemical spray pyrolysis at a substrate temperature of 350 °C on soda lime glass. Sodium chloride is used as a dopant along with metal (Cu/In/Ga) chlorides and n, n-dimethyl selenourea precursors. The addition of Na exhibited better crystallinity with chalcopyrite phase and an improvement in preferential orientation along the (112) plane. Energy dispersive analysis of X-rays (line/point mapping) revealed a graded nature of the film and percentage incorporation of Na (0.86 at%). Raman studies showed that the film without sodium doping consists of mixed phase of chalcopyrite and CuAu ordering. Influence of sodium showed a remarkable decrease in electrical resistivity (0.49–0.087 Ω cm) as well as an increase in carrier concentration (3.0×10¹⁸–2.5×10¹⁹ cm⁻³) compared to the un-doped films. As carrier concentration increased after sodium doping, the band gap shifted from 1.32 eV to 1.20 eV. Activation energies for un-doped and Na doped films from modified Arrhenius plot were calculated to be 0.49 eV and 0.20 eV, respectively. Extremely short carrier lifetimes in the CIGS thin films were measured by a novel, non-destructive, noncontact method (transmission modulated photoconductive decay). Minority carrier lifetimes of graded CIGS layers without and with external Na doping are found to be 3.0 and 5.6 ns, respectively.