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1.
Alison Willette Benjamin Fallen Hem Bhandari Carl Sams Feng Chen Virginia Sykes Chris Smallwood Kristin Bilyeu Zenglu Li Vincent Pantalone 《Journal of the American Oil Chemists' Society》2021,98(8):861-869
Soybean oil hydrogenation alters the linolenic acid molecule to prevent the oil from becoming rancid, however, health reports have indicated trans-fat caused by hydrogenation, is not generally regarded as safe. Typical soybeans contain approximately 80 g kg−1 to 120 g kg−1 linolenic acid and 240 g kg−1 of oleic acid. In an effort to accommodate the need for high-quality oil, the United Soybean Board introduced an industry standard for a high oleic acid greater than 750 g kg−1 and linolenic acid less than 30 g kg−1 oil. By combing mutations in the soybean plant at four loci, FAD2-1A and FAD2-1B, oleate desaturase genes and FAD3A and FAD3C, linoleate desaturase genes, and seed oil will not require hydrogenation to prevent oxidation and produce high-quality oil. In 2017 and 2018, a study comparing four near-isogenic lines across multiple Tennessee locations was performed to identify agronomic traits associated with mutations in FAD3A and FAD3C loci, while holding FAD2-1A and FAD2-1B constant in the mutant (high oleic) state. Soybean lines were assessed for yield and oil quality based on mutations at FAD2-1 and FAD3 loci. Variations of wild-type and mutant genotypes were compared at FAD3A and FAD3C loci. Analysis using a generalized linear mixed model in SAS 9.4, indicated no yield drag or other negative agronomic traits associated with the high oleic and low linolenic acid genotype. All four mutations of fad2-1A, fad2-1B, fad3A, and fad3C were determined as necessary to produce a soybean with the new industry standard (>750 g kg−1 oleic and <30 g kg−1 linolenic acid) in a maturity group-IV-Late cultivar for Tennessee growers. 相似文献
2.
光动力疗法(PDT)以其超高时空分辨率、非侵入性及低毒副作用的优点,被认为是治疗癌症和各种非恶性疾病的有效疗法之一。本文主要综述了几类光敏剂发展历史、主要结构、特点及研究进展,分析了高性能光敏剂的开发动态,包括化学修饰;与具有特定细胞受体的其他配体缀合成复合光敏剂;采取纳米技术,如纳米颗粒输送,基于富勒烯的光敏剂等。基于此,指出具有临床应用前景的高性能光敏剂的基本特征、设计原则及发展趋势。 相似文献
3.
This paper focuses on the design of a 2.3–21 GHz Distributed Low Noise Amplifier (LNA) with low noise figure (NF), high gain (S21), and high linearity (IIP3) for broadband applications. This distributed amplifier (DA) includes S/C/X/Ku/K-band, which makes it very suitable for heterodyne receivers. The proposed DA uses a 0.18 μm GaAs pHEMT process (OMMIC ED02AH) in cascade architecture with lines adaptation and equalization of phase velocity techniques, to absorb their parasitic capacitances into the gate and drain transmission lines in order to achieve wide bandwidth and to enhance gain and linearity. The proposed broadband DA achieved an excellent gain in the flatness of 13.5 ± 0.2 dB, a low noise figure of 3.44 ± 1.12 dB, and a small group delay variation of ±19.721 ps over the range of 2.3–21 GHz. The input and output reflection coefficients S11 and S22 are less than −10 dB. The input compression point (P1dB) and input third-order intercept point (IIP3) are −1.5 dBm and 11.5 dBm, respectively at 13 GHz. The dissipated power is 282 mW and the core layout size is 2.2 × 0.8 mm2. 相似文献
4.
Yuanyuan Zhou Miao Li Hao Lu Hui Jin Xiaodong Wang Yan Zhang Shuaishuai Shen Zaifei Ma Jinsheng Song Zhishan Bo 《Advanced functional materials》2021,31(27):2101742
A series of tetrathiophene-based fully non-fused ring acceptors (4T-1, 4T-2, 4T-3, and 4T-4), which can be paired with the star donor polymer PBDB-T to fabricate highly efficient organic solar cells are developed. Tailoring the size of lateral chains can tune the solubility and packing mode of acceptor molecules in neat and blend films. It is found that the incorporation of 2-ethylhexyl chains can effectively change the compatibility with the donor polymer PBDB-T, and an encouraging power conversion efficiency of 10.15% is accomplished by 4T-3-based organic solar cells. It also presents good compatibility with the other polymer donor and an even higher power conversion efficiency (PCE) of 12.04% is achieved based on D18:4T-3 blend, which is the champion PCE for the fully non-fused acceptors. Importantly, these inexpensive tetrathiophene fully non-fused ring acceptors provide cost-effective photovoltaic performance. The results demonstrate a high photovoltaic performance from synthetically inexpensive materials could be achieved by the rational design of non-fused ring acceptor molecules. 相似文献
5.
位于巴音戈壁盆地南部的塔木素铀矿床在矿化特征上明显有别于我国北方其他砂岩型铀矿床,对于该矿床的成因也存在较大的争议。通过岩石学、同位素地质学、扫描电子显微镜、阴极发光、径迹蚀刻等综合研究,结果显示塔木素铀矿床巴音戈壁组上段第三岩性段(K 1 b 2-3)含铀泥灰岩至少经历了4个阶段的成岩作用,铀矿物呈微粒(粒径<1μm)浸染状分布于最早期的角砾中,具有沉积成岩成因特征,成矿物质主要来自于沉积成岩期水体中溶解的铀并因蒸发浓缩作用而富集在特定的层位。巴音戈壁组上段第二岩性段(K 1 b 2-2)含铀砂岩在沉积成岩阶段盆地内封存的高矿化度地下水与碎屑物之间以及成岩后酸性地表水与碳酸盐胶结物之间共发生了两个阶段的水岩作用,每个阶段形成了表现特征不同的铀矿化。沥青铀矿U-Pb同位素测试结果显示,区内最早的铀矿化形成时间为111.6±8.1 Ma,与砂岩形成时间接近,而最新的铀矿化形成时间为2.5 Ma,具有明显后生成因特征,综合研究显示砂岩中的铀矿化具有沉积成岩及后期层间氧化叠加改造双重成因特征,沉积成岩期成矿物质主要来自封存的地下水,而层间氧化期成矿物质主要来自地表水带入的铀及富铀岩层。同时研究认为塔木素铀矿床存在后期热液活动,但暂未发现热液活动与铀成矿具有直接的成因联系。 相似文献
6.
为探究某加氢装置高压换热器管束腐蚀泄漏原因,利用Aspen Plus工艺模拟软件计算了冷低压分离器油相(简称冷低分油)中水质量分数分别为1%,2%,3%时,冷低分油系统的露点温度、氯化铵结晶温度、氯化铵潮解点温度和相对湿度。结果表明:相较于经验的露点温度预测方法,通过引入潮解点、划分系统“湿环境”温度范围判断氯化铵垢下腐蚀风险区域的方法与实际腐蚀案例更为切合;在3种油相含水条件下,换热器管束存在氯化铵垢下腐蚀的“湿环境”温度范围分别为:50~103 ℃,50~161 ℃,50~176 ℃;随着油相中含水量的提高,“湿环境”腐蚀区域逐渐向高温部位迁移,预计铵盐导致的垢下腐蚀将会愈加严重。 相似文献
7.
Shuang Xia Yukun Chen Jinfeng Tian Jinfeng Shi Chengzhen Geng Huawei Zou Mei Liang Zhibo Li 《Advanced functional materials》2021,31(26):2101143
Gecko-inspired microfibrillar adhesives have achieved great progress in microstructure design and adhesion improvement over the past two decades. Space applications nowadays show great interest in this material for the characteristics of reversible adhesion and universal van der Waals interactions. However, the impact of harsh environment of space on the performance of microfibrillar adhesives, especially the extreme low temperature, is rarely addressed. Herein, microfibrillar adhesives fabricated by phenyl containing polydimethylsiloxane (p-PDMS) elastomers with superior low-temperature reversible adhesion is proposed. p-PDMS elastomers are synthesized through one-pot anionic ring-opening copolymerization, and the resulting elastomers become non-crystallizable with excellent low-temperature elasticity. Low-temperature adhesion tests demonstrate that the adhesion strength of microfibrillar adhesives fabricated by p-PDMS elastomers can be well maintained to as low as −120 °C. In contrast, the adhesion strength of pure PDMS microfibrillar adhesive reduces more than 50% below its crystallization temperature. The low-temperature cyclic adhesion tests further demonstrate that p-PDMS microfibrillar adhesives exhibit superior reversible adhesion compared to that of PDMS microfibrillar adhesives, owing to the sustainable conformal contact and even distribution of loads over repeated cycles. This study provides a new fabrication strategy for microfibrillar adhesives, and is beneficial for the practical application of microfibrillar adhesives. 相似文献
8.
以模拟铀污染地下水为对象,采用腐败希瓦氏菌对其进行了固定铀实验,利用单粒子 电感耦合等离子体质谱(SP ICP MS)、3种胞外聚合物(EPS)提取方法和碳酸氢钠 硝酸分级提取法表征了腐败希瓦氏菌和EPS中铀的含量和赋存形态,并采用傅立叶红外光谱(FT IR)技术分析了EPS与铀反应前后的变化。结果表明,阳离子交换树脂(CER)法适用于表征EPS中的铀含量及形态,EPS中的铀可占腐败希瓦氏菌固定铀总量的(140±10)%。SP ICP MS分析表明,CER法获得的EPS中颗粒铀是其主要形态,EPS在固定铀的过程中,既涉及到生物吸附,也涉及到生物矿化。FT IR分析进一步说明生物吸附时,铀可与EPS中的羧基官能团结合。以上结果表明,EPS在腐败希瓦氏菌固定铀的过程中发挥了重要作用。 相似文献
9.
采用CAPture电极CdZnTe探测器获取X射线注量谱,为建立ISO 4037-1:1996标准以外的参考辐射和计算辐射场特殊剂量物理量的约定真值提供基础。CdZnTe探测器的主要缺点是由于空穴迁移率寿命积过小,导致电荷收集不完全,全能峰左侧出现低能尾。CAPture电极CdZnTe探测器采用扩展阴极降低阴极附近区域的电场强度,弱化空穴输运对电荷收集效率的影响,实现对低能尾的抑制。但由于探测器内的电场不再均匀,电荷收集效率无法用Hecht方程计算。本文根据Shockley-Ramo原理建立了CAPture电极CdZnTe探测器电荷收集效率计算公式,用有限元分析软件模拟了探测器内的电场分布。进而用Geant4软件开展了蒙特卡罗仿真计算,确定了载流子迁移率寿命积,并取得了与实测结果基本一致的脉冲幅度谱,为建立探测器的响应矩阵奠定了基础。 相似文献
10.
某微细粒嵌布磁铁矿选矿工艺研究 总被引:1,自引:0,他引:1
针对某微细粒磁铁矿进行了全磁选流程和磁选-反浮选流程对比试验研究。结果表明,在最终磨矿细度相当的情况下,2种工艺流程都获得了产率48%左右、TFe品位66%左右、回收率80%左右的铁精矿指标,而采用磁选-反浮选流程的第三段磨矿量比全磁选流程减少了2/3。磁选-反浮选流程具有显著的节能降耗优势。 相似文献