Evidence of fluid evolution of Baoshan Cu−Pb−Zn polymetallic deposit: Constraints from in-situ sulfur isotope and trace element compositions of pyrite

In-situ LA-ICP-MS and S isotopes of pyrite from the Baoshan Cu polymetallic deposit were conducted to investigate the ore-forming process and the enrichment mechanism of elements. Three generations of pyrite (Py I, Py II, and Py III) in the skarn-type ores and pyrite in the carbonate-hosted sulfide ores from central, western, and northern (C_Py, W_Py, and N_Py) mining districts are selected for comparison. Compared with Py I and Py III, the contents of most elements in Py II are apparently higher. The As and Se contents are high within a wide range and are decoupled in the growth band of the C_Py. The highest As, Se, and Pb contents were found in W_Py and N_Py. These results indicate the drastic changes in the temperature and fluid mixing during the mineralization. The occurrence of fluctuation and change in temperature and f(O₂) was triggered by intermittent pulses of magmatic-hydrothermal fluids, mixing with meteoric water, and water−rock interactions. The sulfur isotopes of all species of pyrite indicated the magmatic source. The change in the f(O₂) conditions caused slight differences in the sulfur isotope compositions. Consequently, a metallogenic model was proposed to explain the ore-forming processes.     

Poly(lactide)/cellulose nanocrystal nanocomposites by high-shear mixing

There is currently considerable interest in developing stiff, strong, tough, and heat resistant poly(lactide) (PLA) based materials with improved melt elasticity in response to the increasing demand for sustainable plastics. However, simultaneous optimization of stiffness, strength, and toughness is a challenge for any material, and commercial PLA is well-known to be inherently brittle and temperature-sensitive and to show poor melt elasticity. In this study, we report that high-shear mixing with cellulose nanocrystals (CNC) leads to significant improvements in the toughness, heat resistance, and melt elasticity of PLA while further enhancing its already outstanding room temperature stiffness and strength. This is evidenced by (i) one-fold increase in the elastic modulus (6.48 GPa), (ii) 43% increase in the tensile strength (87.1 MPa), (iii) one-fold increase in the strain at break (∼6%), (iv) two-fold increase in the impact strength (44.2 kJ/m²), (v) 113-fold increase in the storage modulus at 90°C (787.8 MPa), and (vi) 10³-fold increase in the melt elasticity at 190°C and 1 rad/s (∼10⁵ Pa) via the addition of 30 wt% CNC. It is hence possible to produce industrially viable, stiff, strong, tough, and heat resistant green materials with improved melt elasticity through high-shear mixing.     

两种混合单元混合机理的数值模拟

为了研究SV型和SX型混合单元在全静态乳化器的混合机理,使用群体平衡模型对乳化器内部流场进行模拟分析。结果表明,SV型与SX型混合单元的混合机理是油相与水相材料通过混合单元时其空间流动方向改变,在流场内形成大量的漩涡,从而达到乳化的目的;通过比较流体在经过SV型和SX型混合单元后的水相索特平均直径(d_(32)),得出SV型混合单元的乳化效果更强,但同时消耗更多的能量,压降更大。     

Synthesis of ZSM‐5 by hydrothermal method with pre‐mixing in a stirred‐tank reactor

This work proposed a synthesis route of ZSM‐5 via the hydrothermal method with premixing in a stirred tank reactor (STR). Effects of various operating conditions, including pre‐mixing time, molar ratio of SiO₂/Al₂O₃, TPAOH (organic template agents) concentration, NaCl (alkali metal cations) concentration, crystallization temperature, and crystallization reaction time, on the average particle size (PS) and particle size distribution (PSD) were investigated. It was found that the pre‐mixing time in the STR significantly affect the formation of proto‐nuclei in premixing process and crystal growth in hydrothermal reaction process, and consequently influence the PS and PSD of the prepared ZSM‐5. ZSM‐5 with good thermal stability, a PS of 380 nm, PSD of 0.17–0.9 µm, pore diameter of 2.31 nm, pore volume of 0.19 cm³ · g^?1 and specific surface area of 337.25 m² · g^?1 were obtained under the optimal conditions of a crystallization reaction time of 24 h, a crystallization temperature of 130 °C, a molar ratio of SiO₂/Al₂O₃ of 200, a TPAOH concentration of 3.5 mol · L^?1, NaCl concentration of 0.3 mol · L^?1, and a pre‐mixing time of 5 h. This work indicated that the operating conditions including premixing time have a significant effect on its PS and PSD.     

Rheokinematics for product development—Formulation screening in rotational rheometers

Product formulations for industrial processes are typically developed at laboratory scale. However, the mixing conditions are not easily mimicked in the laboratory. A rotational device is proposed in this study as a fast laboratory-scale formulation development, which enables mimicking the mixing conditions in the industrial process. The geometrical configurations of the rotational device are from rheometry devices (plate-plate and cone-plate). The main advantages of this method are the small amounts of raw materials and shorter testing times. This methodology is applied to an industrial case study, the reaction injection molding (RIM) process. The mixing length scales evolution in the rotational rheometer were matched to those in RIM machines. The main novelty of this study is the introduction of a protocol that bridges the processing conditions at laboratory using small amounts of raw materials to high throughput continuous flow reactors.     

混炼方式对螺旋纳米碳纤维增强天然橡胶复合材料力学性能的影响

采用干法和湿法两种混炼工艺制备了螺旋纳米碳纤维(HCNFs)/炭黑(CB)/天然橡胶(NR)复合材料,通过扫描电镜、拉伸试验机和应变扫描仪分别对所制备复合材料的界面形貌、力学性能和Payne效应进行了测试分析,考察了混炼方式对复合材料宏观力学性能及Payne效应的影响。结果表明,与纯CB填料相比,在干湿两种混炼方式下,添加适量的HCNFs(1～6份)能提高HCNFs/CB/NR复合材料的300%定伸应力、扯断伸长率、拉伸强度和硬度。与干法混炼相比,湿法混炼能明显增强HCNFs/CB/NR复合材料的Payne效应,并提升在HCNFs高添加量(2～6份)条件下的拉伸强度和扯断伸长率,这主要源于湿法混炼能够有效改善HCNFs在橡胶基质中的分散性。     

多晶硅生产中残液搅拌罐密封结构的改造

在处理多晶硅生产中产生的残液时,残液搅拌罐填料密封出现泄漏,针对此问题提出了优化措施,达到了预期效果。     

D-最优混料设计优化树莓平菇解酒片主料配比

红树莓中富含的鞣花酸和其聚合物以及其他化合物具有解酒功能,该文利用所培育出的树莓平菇,添加传统药膳葛花、拐枣、苦荞以及具有养胃功效的小米进行平菇解酒片的开发。采用软件Design Expert(V.8.0.6)中的混料(mixture)设计D-Optional的方法,以体外乙醇脱氢酶(alcohol dehydrogenase,ADH)的激活率为评价指标,设计解酒片的最佳主料配方。通过建立各组分不同比例与ADH激活率之间的回归模型,考察该配方中各组分的交互作用对响应值的影响,利用软件的优化功能和验证试验得出最佳主料配方为:小米粉31.2%、苦荞粉21.7%、平菇粉20.5%、葛花粉16.8%、拐枣粉9.8%,在该条件下对ADH的激活率最大达到15.87%,验证试验结果与预测值相吻合,表明采用本方法优化得到的处方工艺稳定可靠。     

撞击流反应器撞击面稳定性研究进展

撞击流技术因其良好的混合特性近些年用于强化制备超细粉体反应中的混合过程。撞击面的稳定影响反应器内的混合效果，所以本文对撞击面稳定性的研究进行了综述。撞击流反应器不同结构形式包括平面撞击流、轴对称撞击流和微型撞击流等。文中简述了撞击流稳定性的实验研究手段，分析轴对称撞击流反应器的径向偏转振荡的起止条件和不同喷嘴间距下的轴向偏移振荡规律，并且分析平面撞击流反应器的撞击面偏转周期以及偏转振荡的起止条件。得出轴对称撞击流与平面撞击流撞击面驻点的振荡对混合都有促进作用，并且偏移振荡周期不定，轴对称撞击面偏移振幅与喷嘴间距和雷诺数相关。平面撞击流的偏转振荡周期与进口流速成反比，反应器结构参数是撞击流稳定性的影响因素之一。根据轴对称撞击流偏移振荡对混合的促进作用，本文提出一种新型的预设流量波形双组撞击流反应器。新型撞击流反应器的独特结构克服了物料反应通道单一缺点，通过预设波形控制其进口流量，增大其撞击面偏移振幅，消除撞击面无序振荡，使流动轨迹扩展，扩大混合区域，并设计实验装置与方法讨论动态流量撞击流反应器撞击面稳定性对混合效果的影响。最后，本文对轴对称撞击流反应器的混合性能研究前景进行展望。     

循环流化床脱硫灰用于水泥生产的研究

褐煤作燃料热电厂产生的循环流化床脱硫灰应用于我公司2 500 t/d新型干法窑生产线水泥生产，由于褐煤中全硫含量偏高且波动大，由此致使脱硫过程中脱硫剂比例变化波动也大，将熟料、矿渣、脱硫灰分别用小磨粉磨后进行试验，在试验基础上，除了对该脱硫灰超细粉磨外，同时必须要解决脱硫灰的均化和f-CaO消解问题，通过技术改造使系统设备、工艺更加适合采用脱硫灰复掺技术。