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1.
《International Journal of Hydrogen Energy》2022,47(67):28782-28793
Highly-efficient and stable non-noble metal electrocatalysts for overcoming the sluggish kinetics of oxygen evolution reaction (OER) is urgent for water electrolysis. Biomass-derived biochar has been considered as promising carbon material because of its advantages such as low-cost, renewable, simple preparation, rich structure, and easy to obtain heteroatom by in-situ doping. Herein, Ni2P–Fe2P bimetallic phosphide spherical nanocages encapsulated in N/P-doped pine needles biochar is prepared via a simple two-step pyrolysis method. Benefiting from the maximum synergistic effects of bimetallic phosphide and biochar, high conductivity of biochar encapsulation, highly exposed active sites of Ni2P–Fe2P spherical nanocages, rapid mass transfer in porous channels with large specific surface area, and the promotion in adsorption of reaction intermediates by high-level heteroatom doping, the (Ni0.75Fe0.25)2P@NP/C demonstrates excellent OER activity with an overpotential of 250 mV and a Tafel slope of 48 mV/dec at 10 mA/cm2 in 1 M KOH. Also it exhibits a long-term durability in 10 h electrolysis and its activity even improves during the electrocatalytic process. The present work provides a favorable strategy for the inexpensive synthesis of biochar-based transition metal electrocatalysts toward OER, and improves the water electrolysis for hydrogen production. 相似文献
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《International Journal of Hydrogen Energy》2022,47(37):16335-16346
Oxygen blocking the porous transport layer (PTL) increases the mass transport loss, and then limits the high current density condition of proton exchange membrane electrolysis cells (PEMEC). In this paper, a two-dimensional transient mathematical model of anode two-phase flow in PEMEC is established by the fluid volume method (VOF) method. The transport mechanism of oxygen in porous layer is analyzed in details. The effects of liquid water flow velocity, porosity, fiber diameter and contact angle on oxygen pressure and saturation are studied. The results show that the oxygen bubble transport in the porous layer is mainly affected by capillary pressure and follows the transport mechanism of ‘pressurization breakthrough depressurization’. The oxygen bubble goes through three stages of growth, migration and separation in the channel, and then be carried out of the electrolysis cell by liquid water. When oxygen breaks through the porous layer and enters the flow channel, there is a phenomenon that the branch flow is merged into the main stream, and the last limiting throat affects the maximum pressure and oxygen saturation during stable condition. In addition, increasing the liquid water velocity is helpful to bubble separation; changing the porosity and fiber diameter directly affects the width of pore throat and the correlative capillary pressure; increasing porosity, reducing fiber diameter and contact angle can promote oxygen breakthrough and reduce the stable saturation of oxygen. 相似文献
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《International Journal of Hydrogen Energy》2022,47(21):11116-11127
An important difficulty associated with alkaline water electrolysis is the rise in anode overpotential attributable to bubble coverage of the electrode surface. For this study, a system with a high-speed video camera was developed, achieving in-situ observation of bubble generation on an electrode surface, monitoring an area of 1.02 mm2 at 6000 frames per second. The relation between polarization curve (current density up to 3.0 A cm?2) and oxygen bubble generation behavior on nickel electrodes having cylindrical wires and rectangular wires of different sizes (100–300 μm) was clarified. The generated bubbles slide upward, contacting the electrode surface and detaching at the top edge. Observations indicate that small electrodes have short bubble residence time and thin bubble covering layer on the electrode. As a result, the small electrode diameter contributes to smaller overpotential at high current density. 相似文献
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Krzysztof M. Tokarz Wojciech Wesoowski Barbara Tokarz Wojciech Makowski Anna Wysocka Roman J. Jdrzejczyk Karolina Chrabaszcz Kamilla Malek Anna Kostecka-Gugaa 《International journal of molecular sciences》2021,22(2)
Grass pea (Lathyrus sativus) is a leguminous plant of outstanding tolerance to abiotic stress. The aim of the presented study was to describe the mechanism of grass pea (Lathyrus sativus L.) photosynthetic apparatus acclimatisation strategies to salinity stress. The seedlings were cultivated in a hydroponic system in media containing various concentrations of NaCl (0, 50, and 100 mM), imitating none, moderate, and severe salinity, respectively, for three weeks. In order to characterise the function and structure of the photosynthetic apparatus, Chl a fluorescence, gas exchange measurements, proteome analysis, and Fourier-transform infrared spectroscopy (FT-IR) analysis were done inter alia. Significant differences in the response of the leaf and stem photosynthetic apparatus to severe salt stress were observed. Leaves became the place of harmful ion (Na+) accumulation, and the efficiency of their carboxylation decreased sharply. In turn, in stems, the reconstruction of the photosynthetic apparatus (antenna and photosystem complexes) activated alternative electron transport pathways, leading to effective ATP synthesis, which is required for the efficient translocation of Na+ to leaves. These changes enabled efficient stem carboxylation and made them the main source of assimilates. The observed changes indicate the high plasticity of grass pea photosynthetic apparatus, providing an effective mechanism of tolerance to salinity stress. 相似文献
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Rakesh K. Upadhyay Marvin Edelman Autar K. Mattoo 《International journal of molecular sciences》2020,21(24)
Lipoxygenases (LOXs) (EC 1.13.11.12) catalyze the oxygenation of fatty acids and produce oxylipins, including the plant hormone jasmonic acid (JA) and its methyl ester, methyl jasmonate (MeJA). Little information is available about the LOX gene family in aquatic plants. We identified a novel LOX gene family comprising nine LOX genes in the aquatic plant Spirodela polyrhiza (greater duckweed). The reduced anatomy of S. polyrhiza did not lead to a reduction in LOX family genes. The 13-LOX subfamily, with seven genes, predominates, while the 9-LOX subfamily is reduced to two genes, an opposite trend from known LOX families of other plant species. As the 13-LOX subfamily is associated with the synthesis of JA/MeJA, its predominance in the Spirodela genome raises the possibility of a higher requirement for the hormone in the aquatic plant. JA-/MeJA-based feedback regulation during culture aging as well as the induction of LOX gene family members within 6 h of salt exposure are demonstrated. 相似文献
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不同给液方式对铜电解过程中有重要的影响,不同的循环方式会影响槽内温度分布、电解液成分及阳极泥沉降等,因此,根据铜电解生产不同情况的需要,分析对比了多种给液方式在贵冶电解车间的应用,总结了这几种给液方式的优缺点和适用条件。 相似文献