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Giant reed is a suitable pioneer plant for metal-contaminated soil phytoremediation,however,it is imperative to dispose the metal-contaminated biomass after harvesting.The liquefaction of metal-contaminated giant reed biomass in ethylene glycol system with sulfuric acid as catalyst for the precursors of polyurethane compounds was studied.The results show that giant reed biomass from metal-contaminated soil is potentially liquefied and significantly affected by solvent/solid ratio,liquefaction temperature and liquefaction time (P〈0.05).The liquefaction rate of biomass in acidified ethylene glycol system can reach 85.2% with optimized conditions of 60 min,170 ℃,3% sulfuric acid and solvent/biomass ratio of 5:1.The hydroxyl value of liquefied products is of 481 mg KOH/g while reactive hydroxyl groups of them are abundant,which is promised as potential precursors for polyurethane compounds.The solvent liquefaction is a potential method to dispose the metal-contaminated biomass,however,the containing-metal liquefied products should be studied deeply in order to get the suitable precursors in future. 相似文献
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This review draws on knowledge for the treatment of heavy‐metal leachate in contaminated mine sites. Mine waste rock dumps and tailings generate a continuous stream of metalliferous and saline leachate over the long term. The mining industry has many legacy sites, which have compromised aquatic ecosystems and groundwater because of heavy‐metal contamination. Chemical and engineering methods are available and have been extensively utilised. However, these methods require intensive energy and often produce substantial volumes of secondary waste. We therefore argue in favour of phytoremediation as a sustainable remediation strategy leading towards efficient and sustainable metal removal and immobilisation through constructed wetlands. 相似文献
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根际微生物促进下鱼腥草对镉的富集作用 总被引:1,自引:0,他引:1
初次探讨了鱼腥草在根际微生物的促进下对土壤镉的富集作用。研究表明当土壤中镉(Cadmium)含量在5mg•kg-1时,鱼腥草(Houttuynia cordata , HCT)对镉的富集率为2.86%,镉含量为10 mg•kg-1时富集率1.63%,鱼腥草对镉的吸收量最高可以达到培养前自身镉浓度的200倍(培养前鱼腥草镉含量0.1146 mg•kg-1,培养后最高达24.44 mg•kg-1),说明鱼腥草对镉有很强的富集作用。研究中还发现,细菌、霉菌对镉的耐性很弱,而培养初期放线菌对镉的耐性很强,较高浓度镉可能刺激了放线菌的大量生长。并且在鱼腥草根系和微生物的联合作用下,土壤微生态系统能够保持较好的稳定性。因此植物-微生物联合修复重金属污染土壤技术,可以实现土壤的生态修复,拥有很大的应用前景。 相似文献
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重金属污染土壤的植物修复技术研究进展 总被引:1,自引:0,他引:1
土壤重金属污染已成为全球性问题。污染土壤的传统治理方法成本高、效率低,并且还给生态环境带来其它危害。植物修复技术因成本较低、易被公众接受且无二次污染等优点越来越受到重视。介绍了植物修复技术的分类及超积累植物的来源、发展、筛选、应用,就植物修复技术的植物资源进行了综述,并对重金属污染土壤的植物修复技术进行了展望。 相似文献
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土壤污染是全球面临的一个亟待解决的环境问题。近年来,植物修复技术迅速发展为主要用于清除土壤重金属污染的生态技术。文章介绍了土壤重金属污染的特性、危害及其治理方法。重点介绍了植物修复技术,并探讨了今后植物修复技术的发展前景。 相似文献
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铬污染土壤的植物修复技术以其经济、高效和生态友好等优点成了众多修复技术中的佼佼者。文章归纳总结了土壤铬污染的来源及危害、铬污染土壤的植物修复以及植物与微生物的联合修复的最新进展,探讨了植物修复铬污染土壤存在的问题,展望了其发展趋势。 相似文献
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Alessia Cao Alessandra Carucci Tiziana Lai Gianluigi Bacchetta Mauro Casti 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(6):884-889
BACKGROUND: The application of phytostabilization and assisted phytoextraction to the remediation of abandoned mining areas can be a valuable method to reclaim these areas without modifying soil and landscape characteristics. An in situ application of a continuous phytoextraction technique was carried out in the area of Campo Pisano (Sardinia, Italy), followed by a laboratory assisted phytoextraction test using the biodegradable chelating agents methylglycine diacetic acid (MGDA) and iminodissuccinic acid (IDSA). The plants used were Scrophularia canina subsp. bicolor, Cistus salviifolius and Teucrium flavum subsp. glaucum. RESULTS: The plant that accumulated more Pb was T. glaucum (353 mg kg?1) while C. salviifolius demonstrated better ability to accumulate Zn (1560 mg kg?1). S. bicolor showed a better tolerance to metals but accumulated 119 mg kg?1 of Pb. Accumulation of metals immediately after chelant application was up to 300 mg kg?1 of Pb and 3000 mg kg?1 of Zn which did not further increase during the assisted phytoextraction experiment. CONCLUSION: The plant that demonstrated to be most suitable for phytoremediation application was S. bicolor due to its higher biomass production and tolerance to metals. The low cation exchange capacity and the high concentration of Ca and Mg in soil determined a low chelant effectiveness. Copyright © 2009 Society of Chemical Industry 相似文献