煤矿锚杆机除尘马达改进

针对煤矿进口锚杆机除尘马达频繁出现故障的情况,通过排查除尘装置的安装方式和监测马达工作时的压力状态,查找故障原因,并制定解决方案。通过马达外接单向阀,可满足马达进油口最低安全压力限制的要求,解决了马达频繁损坏的问题,保障了设备工作的稳定性,提高了工作效率。     

On the Catalytic Activity of Sn Monomers and Dimers at Graphene Edges and the Synchronized Edge Dependence of Diffusing Atoms in Sn Dimers

In this study, in situ transmission electron microscopy is performed to study the interaction between single (monomer) and paired (dimer) Sn atoms at graphene edges. The results reveal that a single Sn atom can catalyze both the growth and etching of graphene by the addition and removal of C atoms respectively. Additionally, the frequencies of the energetically favorable configurations of an Sn atom at a graphene edge, calculated using density functional theory calculations, are compared with experimental observations and are found to be in good agreement. The remarkable dynamic processes of binary atoms (dimers) are also investigated and is the first such study to the best of the knowledge. Dimer diffusion along the graphene edges depends on the graphene edge termination. Atom pairs (dimers) involving an armchair configuration tend to diffuse with a synchronized shuffling (step-wise shift) action, while dimer diffusion at zigzag edge terminations show a strong propensity to collapse the dimer with each atom diffusing in opposite directions (monomer formation). Moreover, the data reveals the role of C feedstock availability on the choice a single Sn atom makes in terms of graphene growth or etching. This study advances the understanding single atom catalytic activity at graphene edges.     

Effects of different metal corrosion inhibitors on hydrogen suppression and film formation with Mg–Zn alloy dust in NaCl solutions

To improve the safety of wet dust removal systems for processing magnesium-based alloys, a new method is proposed for preventing hydrogen generation. In this paper, hydrogen generation by Mg–Zn alloy dust was inhibited with six common metal corrosion inhibitors. The results showed that sodium dodecylbenzene sulfonate was the best hydrogen inhibitor, while CeCl₃ enhanced hydrogen precipitation. The film-forming stability of sodium dodecylbenzene sulfonate was tested with different contents, temperatures, Cl^? concentrations and perturbation rates. The results showed that this inhibitor formed stable protective films on the surfaces of Mg–Zn alloy particles, and adsorption followed the Langmuir adsorption model.     

高温除尘滤料性能检测及对比分析

针对工业除尘(燃煤电厂除尘为主)常用玻璃纤维、PPS纤维(聚苯硫醚)、丙烯腈共聚体纤维(亚克力)、聚酯纤维(涤纶)等4种材质的环保除尘滤料产品进行了测试分析,主要包括单位面积质量、透气率、断裂强力、断裂伸长率、连续工作温度下强力保持率、热收缩率、酸碱处理后断裂强力保持率、静态除尘效率等技术参数。结果表明:大多数滤料的单位面积质量超过800 g/m^2,最高为1253 g/m^2;滤料的透气率基本为2~5 m^3/(m^2·min);不同滤料的静态除尘效率最低为99.79%,最高达99.95%;酸碱处理后的测试结果表明滤料具有较好的耐酸腐蚀性,瞬时工作温度及连续工作温度24 h的断裂强力保持率满足技术要求且具有稳定的热收缩率。测试结果可为工业用户选择滤料提供依据。     

PPS针刺过滤毡常温下拉伸特点研究

结合PPS基布和PTFE基布的经、纬向拉伸性能及其经、纬纱拉伸性能的测试结果,研究分析了PPS基布针刺过滤毡与PTFE基布针刺过滤毡经、纬向所表现的不同拉伸特性。建议针对清灰机理,对除尘滤料的经向、纬向结构进行优化设计。     

湖州南方中转仓储及输送工程建设特点

介绍了湖州南方物流有限公司中转仓储及输送工程项目的建设背景、建设条件,以及线路规划、主要技术方案,该项目是国内采用长距离越野曲线带式输送机系统运输熟料距离最长的绿色环保工程。项目以电力驱动运输替代汽车运输,日输送量达4.5~5万吨。采用密闭廊道输送,粉尘排放量低,噪声<50dB,日均减少汽车运输3000辆次,年节约燃油2000余吨,减少了尾气排放,缓解了沿线的交通拥堵,实现了良好的经济效益和社会效益。     

温度对化学镀锡层形貌和耐蚀性的影响

对不同温度下制备的化学镀锡层进行了电化学腐蚀试验。使用电化学工作站测试了交流阻抗谱,研究了温度对化学镀锡层形貌和耐蚀性的影响。结果表明:Nyquist图显示不同温度下所得化学镀锡层的电化学阻抗谱都呈现出简单的容抗弧特征,随着温度从40℃升高到80℃,容抗弧半径总体上先增大后减小;Bode图显示不同温度下所得化学镀锡层的相位角与频率之间的关系曲线形状相似,在测试频率范围内都只出现一个相角峰。温度为60℃时制备的化学镀锡层表面块状颗粒的尺寸和分布最均匀,容抗弧半径最大,并且在较宽频率范围内的相位角都接近70°,表现出较好的耐蚀性。     

高炉瓦斯灰泥铅锌铁综合利用磁化焙烧条件研究

为了确定新钢高炉瓦斯灰泥中铅锌铁回收的焙烧工艺条件，进行了磁化焙烧温度、焙烧时间、无烟煤用量和料层厚度条件试验，并在条件试验确定的参数基础上进行了组合微调优化。结果表明，在焙烧温度为1 120 ℃、焙烧时间为3.5 h、无烟煤用量为25%、料层厚度为35 mm情况下，铅、锌回收率分别超过86%和93%，磁选铁精矿铁品位超过63%、铅锌总含量不超过0.4%、铁回收率超过81%，达到了国家“863”任务书规定的各项技术指标要求。     

Physical and thermal properties of l‐lactide/ϵ‐caprolactone copolymers: the role of microstructural design

Understanding the underlying role of microstructural design in polymers allows for the manipulation and control of properties for a wide range of specific applications. As such, this work focuses on the study of microstructure–property relationships in l‐ lactide/?‐caprolactone (LL/CL) copolymers. One‐step and two‐step bulk ring‐opening polymerization (ROP) procedures were employed to synthesize LL/CL copolymers of various compositions and chain microstructures. In the one‐step procedure, LL and CL were simultaneously copolymerized to yield P(LL‐stat‐CL) statistical copolymers. In the two‐step procedure, poly(l‐ lactide) (PLL) and poly(?‐caprolactone) (PCL) prepolymers were synthesized in the first step before CL and LL respectively were added in the second step to yield P[LL‐b‐(CL‐stat‐LL)‐b‐LL] and P[CL‐b‐(LL‐stat‐CL)‐b‐CL] block copolymers as the final products. The findings reveal that, in addition to the copolymerization procedure employed, the length and type of the prepolymer play important roles in determining the chain microstructure and thereby the overall properties of the final copolymer. Moreover, control over the degree of crystallinity and the type of crystalline domains, which is controlled during the polymer chemistry process, heavily influences the physical and mechanical properties of the final polymer. In summary, this work describes an interesting approach to the microstructural design of biodegradable copolymers of LL and CL for potential use in biomedical applications. © 2019 Society of Chemical Industry