Enhancement of optical emission generated from femtosecond double-pulse laser-induced glass plasma at different sample temperatures in air

In double-pulse laser-induced breakdown spectroscopy(DP-LIBS), the collinear femtosecond double-pulse laser configuration is experimentally investigated with different initial sample temperatures using a Ti:sapphire laser. The glass sample is ablated to produce the plasma spectroscopy. During the experiment, the detected spectral lines include two Na(I) lines(589.0 nm and 589.6 nm) and one Ca(I) line at the wavelength of 585.7 nm. The emission lines are measured at room temperature(22 ℃) and three higher initial sample temperatures(T_s?=?100 ℃, 200 ℃, and 250 ℃). The inter-pulse delay time ranges from-250 ps to 250 ps.The inter-pulse delay time and the sample temperature strongly influence the spectral intensity,and the spectral intensity can be significantly enhanced by increasing the sample temperature and selecting the optimized inter-pulse time. For the same inter-pulse time of 0 ps(single-pulse LIBS), the enhancement ratio is approximately 2.5 at T_s?=?200 ℃ compared with that obtained at T_s?=?22 ℃. For the same inter-pulse time of 150 ps, the enhancement ratio can be up to 4 at T_s?=?200 ℃ compared with that obtained at T_s?=?22 ℃. The combined enhancement effects of the different initial sample temperatures and the double-pulse configuration in femtosecond LIBS are much stronger than that of the different initial sample temperatures or the double-pulse configuration only.     

Effect of distances between lens and sample surface on laser-induced breakdown spectroscopy with spatial confinement

Spatial confinement can significantly enhance the spectral intensity of laser-induced plasma in air.It is attributed to the compression of plasma plume by the reflected shockwave.In addition,optical emission spectroscopy of laser-induced plasma can also be affected by the distance between lens and sample surface.In order to obtain the optimized spectral intensity,the distance must be considered.In this work,spatially confined laser-induced silicon plasma by using a Nd:YAG nanosecond laser at different distances between lens and sample surface was investigated.The laser energies were 12 mJ,16 mJ,20 mJ,and 24 mJ.All experiments were carried out in an atmospheric environment.The results indicated that the intensity of Si (I) 390.55 nm line firstly rose and then dropped with the increase of lens-to-sample distance.Moreover,the spectral peak intensity with spatial confinement was higher than that without spatial confinement.The enhancement ratio was approximately 2 when laser energy was 24 mJ.     

不同空间约束壁数对激光诱导铜击穿光谱的影响

提高激光诱导击穿光谱(LIBS)的信号强度是提高LIBS探测灵敏度的重要途径。本文以铜靶为烧蚀样品,研究了大气环境中不同空间约束壁数(0、2、3、4)和圆柱形约束壁对激光诱导Cu等离子体光谱的影响,并通过Boltzmann图方法测量了等离子体的电子温度。实验结果表明：当使用约束壁约束Cu等离子体时,Cu原子谱线强度、信背比和电子温度均比不存在约束时明显提高;随着腔体约束壁数增加,Cu原子谱线强度、信背比和电子温度逐渐提高;当腔体约束壁为圆柱形时,Cu原子谱线强度、信背比和电子温度最高。空间约束壁为圆柱形壁时空间约束对等离子体的约束效果最好,光谱信号最优。     

台风云图伪彩色增强的Berkeley小波变换法

将Berkeley小波变换(BWT)和线性分配伪彩色增强方法相结合,给出一种有效的台风云图伪彩色增强方法。首先在Berkeley小波域增强云图的细节,然后将增强后的云图分别利用经典的线性分配和改进的线性分配法进行彩色增强。最后将所给出的方法与直接利用经典的线性分配方法、经典离散正交小波预处理后利用改进的线性分配方法进行对比分析。实验结果证明,该方法简便易行,运算量小,在应用中有较大的灵活性,为低对比度台风云图增强处理提供了一种新途径,同时能够有效突出台风眼区和外围螺旋云带等台风结构信息,为后续台风中心定位和台风强度预报提供参考。     

试论国有企业的全面创新

面对我国入世后，经济全球化和社会信息化带来的发展机遇和严峻挑战，作为市场竞争主体的国有企业革除本身积弊，推进全面创新，既是企业本身生存和壮大的迫切需要，也是我国经济继续保持高速增长的有力保证。     

双温方程用于飞秒激光烧蚀金属的模拟分析

讨论了双温模型在不同近似下的电子热传导率对于模拟飞秒激光烧蚀金属过程中靶材的电子温度和晶格温度分布的影响,用有限差分法对飞秒激光脉冲烧蚀金属靶的过程的温度场进行了一维数值计算,以铜靶为例给出了靶材电子与晶格温度分布随时间和深度的演化规律并进行了分析,结果表明不同近似下电子热传导率对于模拟温度分布计算结果有着重要的影响。     

一种带样品槽的小型倒锥腔实用黑体

本文介绍了JD-1型黑体的设计思想、结构特点及测试的结果,并计算了腔体的有效辐射率分布和积分辐射率。认为JD-1型黑体是一种有效辐射率高、工作温区宽、升温速率快、控温精度高的具有实际应用价值的工作黑体。     

酮类分子热学性质研究

本文对环丙酮分子通常的解离通道进行描述,对2甲基环戊酮分子描述了两方面:一时通过激发态的解离通道,二是通过过渡态的解离通道进行描述,同时也对其它分子的热学性质进行描述。     

城市空中慢行廊道建设分析

城市化进程的加快导致"大城市病"日益加剧,而交通拥堵是大城市的通病.为缓解城市人车矛盾,保障城市交通安全,营造城市公共绿色慢行空间,提出构建城市空中慢行廊道的构想,以期为城市交通分流和交通安全提供引导.     

通过圆偏振光提高飞秒激光诱导击穿光谱的发射强度

激光诱导击穿光谱(LIBS)是一种快速、实时的元素成分分析技术。为了提高LIBS的灵敏度,人们已经提出多种方法来提高LIBS的光谱强度。本文采用飞秒脉冲激光烧蚀黄铜产生LIBS,对比了圆偏振和线偏振下LIBS光谱的强度,结果发现圆偏振下的光谱强度比线偏振下的强,光谱强度大约提高了15%。采用飞秒激光照射金属时,金属内部的自由电子吸收光子的能量。在线偏振飞秒激光场中,电子在脉冲的每个光学周期中经历交替的加速和减速;而圆偏振飞秒激光可以连续加速电子,因此电子可以获得更高的能量,这使得圆偏振飞秒激光产生的光谱强度不同于线偏振飞秒激光产生的光谱强度,圆偏振激光有助于改善飞秒LIBS信号的强度。