浅析铅电解生产中杂质金属的行为及影响

本文阐述了目前铅电解生产过程中杂质金属的影响,并通过阳极泥的电化学行为来分析这些影响,并结合生产实践提出了相应的解决办法。     

求解VLSI 电路划分问题的混合粒子群优化算法

电路划分是VLSI物理设计过程中的一个关键阶段.该问题本质上是一个NP困难的组合优化问题.针对该问题,提出了一种带FM策略的混合粒子群优化算法.引入遗传算法的两点交叉算子和随机两点交换变异算子,保证了粒子在位置更新后依然可行;为了提高算法的局部搜索能力,将具有较强局部搜索能力的FM策略融入算法的位置更新;设计了种群多样性变异策略,提高了种群多样性,避免了易陷入局部最优的缺陷.对ISCAS89标准测试电路的仿真实验结果表明,所构造的算法是有效的.     

离子交换树脂催化乳酸与异丁醇及正丁醇酯化反应的动力学研究

The esterification reactions of lactic acid with isobutanol and n-butanol have been studied in the presence of acid ion-exchange resin Weblyst D009. The influences of catalyst loading, stirrer speed, catalyst particle size, initial reactant molar ratio and temperature on the reaction rate have been examined. Experimental kinetic data were correlated by using the Pseudo-homogeneous, Langmuir-Hinshelwood and Eley-Rideal models. Nonideality of the liquid phase was taken into account by using activities instead of molar fractions. The activity coefficients were calculated according to the group contribution method UNIFAC. Provided that the nonideality of the liquid is taken into account, the esterification kinetics of lactic acid with isobutanol and n-butanol catalyzed by the acid ion-exchange resin can be described using all three models with reasonable errors.