双功能催化剂上四氢萘加氢裂化生成单环芳烃的反应网络研究

Conversion of LCO (light cycle oil) to BTX (benzene, toluene, and xylene) is an economically valuable method for refineries. However, this approach still faces difficulties as the main reactions are not clearly understood. Here we study the detailed hydrocracking pathway of typical reactants, 1-methylnaphthalene and tetralin, through molecular simulations and experiments to improve our understanding of the conversion process of LCO to BTX. Molecular simulations demonstrate that the rate-determining step is the isomerization pathway of six-membered ring to five-membered ring in tetralin as its activation energy (ΔEa) is the highest among all the reactions and the order of ΔEa of reactions is isomerization > ring-opening ≈ side-chain cleavage. The results of experiments show that with the increase in reaction depth, i.e., through a high temperature (350 – 370 °C) and low LHSV (4.5 – 6.0 h−1), isomerization, ring-opening, and side-chain  cleavage reactions occurred, thus improving the selectivity and yield of alkyl aromatics.     

Comparative analysis of the determinants of fees charged by fee-based homes for the elderly in urban and suburban areas

This study contributes to establishing the payment function of fee-based homes for the elderly. Disclosure statements from such homes for the elderly in selected urban and suburban cities in Fukuoka Prefecture, Japan—considered a typical prefecture with adjoining urban and suburban areas—were examined. The study compared the determinants of the amounts charged by the homes based on the distinct geographic features of urban and suburban areas. The hedonic price model was combined with a two-stage least squares regression to determine the determinants of lump-sum and monthly payments. We found that the factors that influence monthly payments in urban areas include distance to a park, distance to the coast, meals offered, number of care staff, and initial lump-sum payment. In contrast, factors such as room size, distance to a bus stop, distance to a park, and the number of night staff influence monthly payments in suburban areas. We conclude that the surrounding landscape has a greater influence on monthly payments in urban areas than in suburban areas. Moreover, in suburban areas, the number of night staff has a substantial impact on monthly payments. The results can help provide investment suggestions in certain cases depending on the amount of investment capital.

     

“一带一路”背景下粉彩团花纹饰设计传承与创新

目的 以现代设计的角度解析粉彩团花纹饰，探索其传承创新的可能性。在相关研究的基础上，丰富并启发传统纹饰研究，促进传统纹饰在当代设计中的多元融合，给当下设计提供传承与创新理论支持。方法 研究“一带一路”的传统文化艺术源头，以景德镇粉彩纹饰为切入点，用现代设计的法则解析粉彩团花纹饰的形成。对馆藏的典型粉彩团花纹饰举例说明，分析其纹饰在艺术性、功能性及思想性上的独特之处，为传统纹饰在当代设计的创新做出一些有意义的探索。结论 “一带一路”背景下研究中国传统纹饰艺术不仅有历史考古与文化收集的价值，也有审美的价值。通过设计角度的解构和分析粉彩团花纹饰的基本特征、文化意义、艺术审美和传承载体等，有利于进一步解读“一带一路”源头的中国传统文化艺术内涵，促进传统元素在当代艺术中的创意传承与创新发展。     

Fe3+-TiO2@CGS复合材料光催化处理苯酚废水研究

以煤气化渣(CGS)为载体,采用溶胶凝胶法制备了Fe3+掺杂改性的Fe3+-TiO2@CGS光催化剂复合材料,利用电子扫描显微镜、N2物理吸附仪、热重分析仪等设备对复合材料进行了表征,并以苯酚废水为目标污染物,考察了该复合材料的光催化性能.实验结果表明,250mL浓度为300mg·L-1苯酚溶液在光催化反应器进行处理,当Fe3+-TiO2@CGS复合材料投入量为1.5g、溶液pH值为7、光源功率为600W时,苯酚溶液COD的去除效果最明显,去除率达64.8％.     

化脓隐秘杆菌对奶牛脾脏组织细胞凋亡的影响

目的观察化脓隐秘杆菌自然感染奶牛脾脏组织的病理学变化,并检测组织细胞中Caspase-3、Caspase-8、Caspase-9、Bax和Bcl-2的表达,以确定化脓隐秘杆菌感染对奶牛脾脏组织细胞凋亡的影响。方法筛检2头化脓隐秘杆菌阴性健康奶牛(对照)和5头自然感染化脓隐秘杆菌的奶牛,收集脾脏组织样本,采用本课题组国家发明专利方法,进行石蜡制片和HE染色,观察脾脏组织病理学变化;采用免疫组织化学方法与本课题组国家发明专利方法相结合,检测奶牛脾脏组织中与细胞正负凋亡相关的调节基因Bax和Bcl-2及凋亡通路蛋白Caspase-3、Caspase-8和Caspase-9的表达情况。结果肉眼观察可见化脓隐秘杆菌自然感染奶牛脾脏肿大、柔软,有出血;病理组织学观察可见脾脏组织出血,水肿,淋巴细胞数量减少,有坏死;脾脏淋巴细胞Caspase-3、Caspase-9和Bax表达阳性,与对照组相比,差异有统计学意义(P <0.05),少量淋巴细胞Caspase-8和Bcl-2表达阳性,与对照组相比,差异无统计学意义(P> 0.05)。结论化脓隐秘杆菌能够引起奶牛脾脏淋巴细胞发生坏死和凋亡;可通过调节脾脏中淋巴细胞Bcl-2家族的活性,引起其Bax和Bcl-2比率改变,增加淋巴细胞线粒体内外膜通透性,导致与凋亡相关因子的释放,激活Caspase-9,进一步激活Caspase-3,从而引起脾脏中淋巴细胞发生凋亡。