首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1962篇
  免费   110篇
  国内免费   79篇
电工技术   38篇
综合类   49篇
化学工业   110篇
金属工艺   38篇
机械仪表   38篇
建筑科学   79篇
矿业工程   30篇
能源动力   9篇
轻工业   1055篇
水利工程   22篇
石油天然气   16篇
武器工业   2篇
无线电   81篇
一般工业技术   319篇
冶金工业   22篇
原子能技术   24篇
自动化技术   219篇
  2024年   3篇
  2023年   58篇
  2022年   58篇
  2021年   65篇
  2020年   55篇
  2019年   27篇
  2018年   38篇
  2017年   30篇
  2016年   23篇
  2015年   18篇
  2014年   179篇
  2013年   168篇
  2012年   207篇
  2011年   234篇
  2010年   207篇
  2009年   200篇
  2008年   133篇
  2007年   159篇
  2006年   193篇
  2005年   30篇
  2004年   6篇
  2003年   4篇
  2002年   13篇
  2001年   14篇
  2000年   4篇
  1999年   13篇
  1998年   2篇
  1997年   1篇
  1996年   8篇
  1995年   1篇
排序方式: 共有2151条查询结果,搜索用时 15 毫秒
1.
为探究含石量对不同围压下砂卵石土的颗粒破碎及抗剪强度与变形特性的影响,利用室内大型三轴试验仪开展了固结排水剪切试验。试验设计了0~100%之间5级含石量,在0.5 MPa、1.5 MPa、2.5 MPa三种不同围压条件下进行固结排水三轴剪切试验。基于试验结果,分析了含石量及围压对砂卵石土抗剪强度和剪胀、剪缩特性的影响,并分析了相应的颗粒破碎情况。试验结果表明,在相同含石量下,砂卵石土抗剪强度随着围压的升高不断增加,体变初期表现为明显剪缩,之后剪胀性随围压升高而降低,颗粒破碎率随围压升高而增加;在相同围压下,含石量在50%~75%时,颗粒破碎率最大,并出现最大抗剪强度,而围压越高,试样剪胀越不明显。  相似文献   
2.
矿山地质环境治理前须做好矿区地质环境调查工作。针对露天矿地质环境调查中地形、地质灾害调查存在的精度不足等问题,讨论无人机技术在地质环境调查时的应用。以山东东平县某露天采石场为研究区,通过使用无人机结合SfM算法快速获取研究区DEM及DOM,实现矿山1∶500大比例尺地形和地质灾害点调绘。研究表明,无人机航测技术具有成本低、精度高、快速高效等特点,可以为地质环境治理的勘察设计工作提供更加精准的基础资料。  相似文献   
3.
对岩巷工程灾害的预警预报和应急响应是减少人员伤亡和经济损失的重要途径,通过红外辐射和声发射联合监测含孔岩石在受力过程中的物理变化可以有效地模拟岩巷工程灾害演化与爆发。为此,开展了 含孔洞岩石加载过程的红外辐射和声发射联合监测试验,对含孔洞岩石加载的红外辐射和声发射特征以及二者之间的关系进行了研究。结果表明:①极差曲线随应变的变化具有明显的阶段性特征,特别在最后阶段, 极差曲线加速上升并出现突跳点,反映了温度场的分异现象和前兆特征,前兆时间平均为95.71%峰值应力;②声发射能率和声发射率曲线具有阶段性变化特征,在后期阶段普遍存在岩石破坏的前兆特征,前兆时间平 均为82.68%峰值应力;③岩石加载后期,红外与声发射前兆具有递进性,即声发射前兆早于红外前兆,两者的时间分界线在92%~95%峰值应力;④红外和声发射变化特征的关系与岩石的损伤破裂演化以及两种监测技术 的特点有密切关系。根据试验结果,提出了岩巷岩体失稳破坏的红外和声发射联合监测预警技术,讨论了两种技术的互补性,并给出了联合监测预警的技术流程,供相关研究和现场监测参考。  相似文献   
4.
Herein, a new mechanism involving Lewis acid-oxygen vacancy interfacial synergistic catalysis for aniline N,N-diethylation with ethanol was proposed, and the SO42−/Ce0.84Zr0.16O2–WO3–ZrO2 catalyst (SCWZ) with both Lewis acid sites and oxygen vacancies was synthesized by the hydrothermal method, which shows better catalytic activity than the reported solid acidic catalysts. Besides, the SO42−/ZrO2 (SZ) and SO42−/WO3–ZrO2 (SWZ) catalysts were also prepared and compared with SCWZ to investigate the synergistic effect of each component. The SO42− and WO3 mainly generate Lewis acid by bonding with ZrO2, which is beneficial for the fracture of the N–H bond in aniline. The Ce0.84Zr0.16O2 solid solution mainly plays a vital role in generating the oxygen vacancies as the interface active species, which can participate in stripping –OH from ethanol, then the carbocation will also be released, which only needs 1.3805 kcal/mol energy, calculated by density functional theory (DFT), to be input. In comparison, the traditional reaction mechanism needs the Brønsted acidic sites to promote the protonation of ethanol, then dehydration and subsequent formation of carbocation followed, and 108.6846 kcal/mol energy needs to be input, which is far higher than that of the new mechanism. The apparent activation energy (Ea) over SCWZ was measured by experiment to be 34.09 kJ/mol, which is much lower than that of SWZ (47.10 kJ/mol) and SZ (54.37 kJ/mol), illustrating comparatively preferable kinetics for SCWZ than that of SWZ and SZ. Besides, the conversion of aniline and selectivity to N,N-diethylaniline over SCWZ reach almost 100% and 73%, respectively. The SCWZ can be renewed for 4 times without rapid deactivation, and the longevity of SCWZ is longer than that of SWZ and SZ, as the loaded SO42− and tetragonal ZrO2 are stabilized by Ce0.84Zr0.16O2 and WO3, respectively.  相似文献   
5.
该文筛选能够应用在桑叶多糖提取中可形成双水相现象较好的离子液体和无机盐体系,并研究含离子液体萃取体系中桑叶多糖的最佳提取工艺。研究1-丁基-3-甲基咪唑四氟硼酸盐、1-辛基-3-甲基咪唑六氟磷酸盐、谷氨酸双三氟甲磺酰亚胺盐等15种离子液体分别加入磷酸二氢钾、无水碳酸钠、硫代硫酸钠等13种无机盐中形成双水相现象的难易程度,筛选出形成双水相现象较好的离子液体。采用溶剂浸提法对桑叶进行提取,采用单因素试验研究离子液体浓度、提取温度、提取时间和料液比对桑叶中多糖化合物提取的影响,并根据响应面设计试验和验证试验获得桑叶多糖的最优提取工艺条件为离子液体浓度0.000 3 mol/L、提取温度76℃、料液比1∶20(g/mL)、提取时间109 min。  相似文献   
6.
Aiming at the problem of residual inter-relay interference (IRI) caused by the channel estimation error in amplify-and-forward two-path MIMO relay networks, a blind interference suppression scheme based on row space precoding under unknown channel state information (CSI) is proposed. In the new scheme, the desired received signal and IRI signal are mapped to an orthogonal subspace independent of CSI by alternating the row space precoding of the transmitted signal, so that the blind interference suppression of the IRI signal and relay noise under unknown channel state information is realized, and the optimal precoding design is given from the angle of the maximizing signal-to-noise ratio. Simulation results show that the proposed scheme can effectively avoid the impact of the link channel estimation error on the IRI suppression algorithm, and is superior to the traditional CSI-based interference suppression scheme in system performance and capacity.  相似文献   
7.
基于NTRU的全同态加密方案   总被引:3,自引:0,他引:3       下载免费PDF全文
本文提出一种基于公钥密码体制(Number Theory Research Unit,NTRU)选择明文攻击(Chosen Plaintext Attack,CPA)可证明安全的全同态加密方案.首先,对NTRU的密钥生成算法进行改进,通过格上的高斯抽象算法生成密钥对,避免了有效的格攻击,同时,没有改变密钥的分布.然后,基于改进的NTRU加密算法,利用Flattening技术,构造了一个全同态加密体制,并在标准模型下证明方案是选择明文攻击不可区分性IND-CPA安全的.  相似文献   
8.
粉末涂料在贮存期间可发生物理及化学变化,高温贮存会造成粉末涂料因化学变化而产生不可逆的性能劣化。为找到粉末涂料的贮存稳定性与配方、生产以及贮存条件的关系,本研究通过分析粉末涂料的 Tg、原材料、生产工艺等因素,发现粉末涂料的贮存稳定性以及性能劣化与粉末涂料的 Tg、固化剂 TGIC(异氰尿酸三缩水甘油酯)的品质、聚酯 /TGIC的配比、固化促进剂的使用以及生产加工工艺等因素密切相关。可以用差示扫描量热仪( DSC)检测粉末涂料的热性能变化、通过测定粉末涂料胶化时间以及倾斜板流动值的变化大致判断粉末涂料的性能劣化程度,有必要出库前再次喷板检验重新评价粉末涂料质量,从而避免将性能劣化严重的粉末涂料发往客户,造成严重后果。  相似文献   
9.
The flat micro heat pipe array photovoltaic-thermal module was retrofitted into a photovoltaic-thermal evaporator, and then a novel solar energy and air dual-heat-source heat pump system was developed. The operation performance of the system operating in the solar energy mode (S) as well as the solar energy and air dual-heat-source mode (SA) was studied in detail. Studies have shown that: affected by solar radiation and ambient temperature, the role of ambient air in the dual heat source heating mode will switch between heat release and heat absorption, and the temperature difference between ambient temperature and backplane temperature fluctuates between -3.1—3.5℃; the SA mode was suitable for low solar radiation condition, and its thermal efficiency, comprehensive performance efficiency and COP were 56.7%, 81.7% and 2.38 respectively, which were 20.3%, 25.0% and 6.7% higher than that of the S mode; under the high solar radiation condition, the SA mode would accelerate the heat dissipation of the system, but it could improve the electrical performance of the system. According to the above characteristics, it would get the better operation performance operating in SA mode when the backplane temperature was lower than the ambient temperature as well as operating in S mode when the backplane temperature was higher than the ambient temperature.  相似文献   
10.
Al coated NdFeB magnets obtained by vacuum evaporation technique were densified by high energy ball milling method.The surface morphology,metal composition and micro structure of the coatings were characterized by scanning electron microscopy,X-ray diffraction and X-ray photoelectron spectroscopy,respectively.The anticorrosive properties were investigated by potentiodynamic polarization curves and neutral salt spray test.The pores in the Al coatings of columnar crystals(Al) induced by the evaporation technique,were apparently filled in the following ball milling process,leading to the densification of Al coatings and the evident improvement of the anticorrosive performances.When treated with ball milling for 30 min,the sample achieves the best anticorrosive performances with the self-corrosion potential of-0.87 V,self-corrosion current density of 1.65 μA/cm~2 and the neutral salt spray(NSS) time of 144 h(red rust).The improvement of the anticorro sive performances of vacuum evaporated Al coating mainly lies in the densification effect of the coating,which depends on different loading conditions of ball milling process.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号