微反应器中的苯硝化反应

探究了以苯硝化为代表的液-液非均相体系的过程工艺,并分析对比了选择性和转化率的变化状况。结果表明:在温度为40℃、流量为55.8 mL·min-1、停留时间10 s条件下,苯的转化率可达99.5%,产物选择性高达99.5%。与传统工艺相比大大减少反应时间,提高效率,为硝基苯安全生产工艺提供了新思路。     

Novel design to improve band to band tunneling and gate induced drain leakages (GIDL) in cylindrical gate all around (GAA) MOSFET

Microsystem Technologies - In this paper a cylindrical Dual Metal (DM) Dielectric Engineered (DE) Gate All Around (GAA) MOSFET has been proposed to resolve a big issue of Gate Inducted Drain...     

Carbon-sensitive meta-productivity growth and technological gap: An empirical analysis of Indian thermal power sector

This paper measures carbon-sensitive efficiency and productivity growth in technologically heterogeneous coal-fired thermal power plants in India for the period of 2000 to 2013. It uses a unique data set of 56 plants, obtained petitioning the Right to Information Act 2005. We apply ‘within-MLE’ fixed effects stochastic frontier model to get consistent estimates of meta-directional output distance function. The thermal power plants are grouped into two categories: central sector and state sector. We find that the state sector plants have higher potential to simultaneously increase electricity generation and reduce carbon emissions than the central sector plants. If all the state and central sectors plants were made to operate on the meta-frontier, reduction of 98 million tonnes of CO₂ could have been achieved. Carbon-sensitive productivity growth in the central sector plants is higher than the plants in state sector, though in both the sectors productivity growth is governed by carbon-sensitive innovation effect. Commercialisation or autonomy in electricity generation also induces carbon-sensitive productivity growth and reduces carbon-sensitive productivity growth gap.     

Tunable structure and intensive upconversion photoluminescence for Ho3+-Yb3+ codoped bismuth titanate composite synthesized by sol-gel-combustion (SGC) method

Ho³⁺ and Yb³⁺ codoped bismuth titanate (BTO) composite powders with infrared to visible upconversion luminescence (UCL) function were prepared by SGC method. The effects of Ho³⁺ and Yb³⁺ doping content on the structure and property were investigated for BTO: xHo, 0.2 Yb (x = 0, 0.02, 0.04, 0.06, 0.08, 0.1) and BTO: 0.02Ho, yYb (y = 0.1, 0.2, 0.3, 0.5, 0.7, 0.9) samples. All the samples include three bismuth titanate phases (Bi₄Ti₃O₁₂, Bi₂Ti₂O₇, and Bi₂₀TiO₃₂), and the phase proportion can be tuned by changing Ho³⁺ and Yb³⁺ doping content. These powders are well crystalized with honeycomb-like microscopic structure, and with good absorption for 233 nm, 310 nm and 975 nm wavelength. The band gap can be tuned from 3.53 eV to 4.03 eV when increasing Yb³⁺ content from y = 0 to y = 0.9. A strong 530–580 nm green emission band and a relative weak 630–690 nm red one corresponding to Ho³⁺: ⁵S₂ → ⁵I₈ and ⁵F₅ → ⁵I₈ transitions appear in the UCL spectra for all the BTO: Ho, Yb samples when pumped at 980 nm. The emission intensities can well be tuned with various Ho³⁺ and Yb³⁺ content. The optimal UCL was obtained in BTO: 0.02Ho, 0.5 Yb for all the prepared samples. The energy transfer mechanism is analyzed by building a two-photon energy transfer model, which is proved by the relationship between emission intensities and pumping power measurement. The concentration quenching of Ho³⁺ is caused by cross relaxation of CR₁ and CR₂ (Ho: ⁵F₄, ⁵S₂ + ⁵I₈ → ⁵I₄ + ⁵I₇) and by CR₃ (Ho: ⁵F₄, ⁵S₂ + Yb: ²F_7/2 → Ho: ⁵I₆ + Yb: ²F_5/2) for Yb³⁺ quenching. The mean luminescence lifetime (τ_m) from Ho: ⁵S₂ decreases monotonously with the increase of Ho³⁺ and Yb³⁺ content.     

Study of Thermally Activated Phase-Slip and Scaling of Magneto-Resistance Near TC in YBa2Cu3O7−δ/Ag bulk composites

Journal of Superconductivity and Novel Magnetism - Dissipation in YBCO polycrystalline bulk samples added with nominally different amounts of silver (0, 5, 15, 25 wt%) has been studied through...     

Impact of crystal structure and microstructure on electrical properties of Ho doped lead-free BCST piezoceramics

Conventional solid state sintering method was used to synthesize lead-free (Ba_0.91Ca_0.09Sn_0.07Ti_0.93)O₃-xHo₂O₃ (x?=?0, 1.2,1.4,1.6,1.8 and 2.0?mol%) ceramics. The influence on electrical properties of the system as a result of the structural and microstructural changes introduced by the incorporation of rare earth Ho³⁺ ions has been investigated. The X-ray diffraction analysis reveals that Ho³⁺ ions completely diffuse into the (Ba_0.91Ca_0.09Sn_0.07Ti_0.93)O₃ lattice to form a homogeneous solid solution with a pure perovskite structure having tetragonal symmetry. Evidence of Ho³⁺ substituting Ti⁴⁺ via the oxygen vacancy compensation mechanism exists in the range of 0–1.6?mol % Ho content, while the self-compensation mode is the preferred mechanism beyond 1.6?mol %. The average grain size exhibits a drastic reduction from 16?μm to 0.7?μm as the Ho content increases from 0 to 1.6?mol%, followed by a slight increase at higher Ho concentration. It suggests that addition of Ho³⁺ inhibits grain growth in the ceramics. In the composition range studied, increasing Ho³⁺ content produces a gradual decrease in the relative density from 93% to 81%, room temperature dielectric constant (ε_rt) from 3997 to 807, electromechanical coupling factor (k_p) from 0.23 to 0.06, and piezoelectric charge constant (d₃₃) from 102 to 38?pC/N. This degradation in the properties is attributed to the crystalline and microstructural changes driven by the increasing presence of Ho content in the ceramics.     

建筑用红外反射隔热涂料的研究进展

本文详述了红外反射隔热涂料的国内外研究进展,指出了该领域全色系、多功能、智能变色三个研发切入点,提出彩色及深色建筑涂料市场存在巨大缺口,并认为红外反射隔热填料与红外反射颜料、色浆等技术的结合是建筑涂料未来的发展趋势。     

15%炔草酯WP防除冬小麦田杂草田间药效试验

为了明确15%炔草酯WP(沈阳化工研究院有限公司)对冬小麦田杂草的防除效果、对冬小麦的安全性及使用技术,进行了田间小区试验。结果表明:15%炔草酯WP对小麦田禾本科杂草具有很好的防效,并对小麦生长发育无明显影响。田间应用以45~60 g/hm2的有效成分用量于冬小麦5~6叶期、禾本科杂草3~5叶期茎叶喷雾处理效果较好。     

液相色谱法分析2-甲氧基苯胺甲烷磺酸含量

本文建立了利用高效液相色谱法定量分析2-甲氧基苯胺甲烷磺酸的方法。通过对流动相等色谱条件的优化,确定了本方法的实验条件,采用峰面积外标法进行了定量。对该方法的准确度、精密度及响应值的线性范围进行了测定,验证了该方法的可行性。     

2,6-二氯-3-氰基-4-甲基吡啶的合成及应用

2,6-二氯-3-氰基-4-甲基吡啶是制备染料的重要中间体,本文对2,6-二氯-3-氰基-4-甲基吡啶合成路线及其优缺点进行评述,并对其应用进行了介绍。