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1.
Energy bands, effective mass of carriers, absolute band edge positions and optical properties of tetragonal AgInS2 were calculated using a first-principles approach with the exchange correlation described by B3LYP hybrid functional. The results indicate that tetragonal AgInS2 has a direct band gap of 1.93 eV, which reproduce well experimental value. Calculated effective masses of electrons and holes are both small which are beneficial to separation and migration of electron and hole pairs. This implies that AgInS2 has good photocatalytic performance. The calculated optical characteristics indicate that AgInS2 has a slight anisotropy for both the real and imaginary parts of the dielectric function and exhibits large optical absorption in the visible light region. Furthermore, the calculated band edge positions in (100), (010) and (001) surfaces indicate that tetragonal AgInS2 is beneficial to the reduction and oxidation of water to hydrogen and oxygen under visible light irradiation.  相似文献   
2.
Thermography represents an important tool to study fatigue behaviour of materials.In this work, the fatigue limit of martensitic and precipitation hardening stainless steels has been determined with thermographic methods. Despite their use in corrosive and cryogenic environments, there is a data lack in literature concerning the study of fatigue behaviour.The peculiarity of these materials is the brittle behaviour: therefore, during fatigue tests the characteristic small deformations determine small changes of temperature. Thus, to properly determine the fatigue limit of aforementioned stainless steels, a more accurate setup is necessary in order to correctly detect surface temperature of specimens due to dissipation heat sources.In literature, different procedures have already been proposed to evaluate the fatigue limit from thermal data but very few works lead to an early detection of dissipation process which can obtain a further reduction of overall testing time. The aim of the paper is to propose a new robust thermal data analysis procedure for estimating fatigue limit of stainless steels in automatable way.  相似文献   
3.
This paper investigates the differential geometry of 3D MAT (medial axis transform) using the moving frame and differential form. After constructing the mapping relation and moving frames around both the MA (medial axis) point and the associated boundary points, various curves are defined to serve as carriers for the study. Based on analysis of the infinitesimal translation and rotation of the moving frames, the relations of distance differentials, rotation vectors and differential invariants are derived. Furthermore, a special case in the 3D MAT, the normal form, is defined for the moulding surfaces, where the 3D problem can be converted into a 2D one.  相似文献   
4.
This paper discusses the effects of the grinding-induced cyclic heating on the properties of the hardened layer in a plunge cylindrical grinding process on the high strength steel EN26. It was found that a multi-pass grinding brings about a uniform and continuous hardened layer along the circumference of the cylindrical workpiece. An increase of the number of grinding passes, leads to a thicker layer of hardening, a larger compressive residual stress and a deeper plastic deformation zone. Within the plastic deformation zone, the martensitic grains are refined by the thermo-mechanical loading, giving rise to a hardness of 12.5% higher than that from a conventional martensitic transformation. The coupled effects of heat accumulation and wheel wear in the multi-pass grinding are the main causes for the thickening of the hardened layer. A too small infeed per workpiece revolution would result in insufficient grinding heat, and in turn, bring about an undesirable tempered hardened layer and a reduction of its hardness.  相似文献   
5.
单微乳液中制备Ag/TS-1及丙烯气相环氧化   总被引:2,自引:0,他引:2  
采用N2H4还原含AgNO3的单微乳液制备了Ag/TS-1催化剂。TEM表征结果表明,Ag高度分散于TS-1之上。以H2、O2存在下的丙烯气相环氧化为探针反应,考察了Ag/TS-1的催化性能。结果表明,采用Ag/TS-1为催化剂,Ag的负载量为1%(质量分数,下同),823 K焙烧后,373 K下反应30 min时,丙烯转化率为1.69%,环氧丙烷(Propylene oxide,PO)选择性为93.2%。当Ag的负载量超过2%时,反应过程中生成大量的热,造成PO的选择性下降。采用Ag的负载量为8%的Ag/TS-1催化剂,消除热效应后,丙烯的转化率为2.46%.PO的选择性为79.2%。  相似文献   
6.
The effect of the charge fluctuation of dust particles on ion acoustic wave (IAW) excited through ionization instability was investigated. The hydrodynamic equations and linear time-dependent perturbation theory served as the starting point of theory, by which the dispersion relation and growth rate of the IAW were given. By comparing the results with the case of constant dust charges, it was found that the charge fluctuation of dust particles reduces the instability of the wave mode.  相似文献   
7.
The relatively simple to measure ‘time constant’ is presented as an index for characterizing the level of corrosion experienced by steel in concrete. This communication, largely in the form of a technical note, explicitly illustrates that the time constant determined from electrochemical testing has significant merit for monitoring corrosion of steel in concrete, and appears to be insensitive to the area of electrode being probed. In this work, the time constant, κ, is determined following a galvanostatic excitation signal, revealing a good correlation between the value of κ and corrosion status across specimens of widely varying geometry. Although this notion has been suggested in the past, this work presents both a survey and consolidated review to indicate the utility of the parameter as an index to corrosion rate on-site.  相似文献   
8.
Traditional flood forecasting and operation of reservoirs in China are based on manual calculations by hydrologists or through standalone computer programs. The main drawbacks of these methods are long forecasting time due to time-consuming nature, individual knowledge, lack of communication, absence of experts, etc. A Web-based flood forecasting system (WFFS), which includes five main modules: real-time rainfall data conversion, model-driven hydrologic forecasting, model calibration, precipitation forecasting, and flood analysis, is presented in this paper. The WFFS brings significant convenience to personnel engaged in flood forecasting and control and allows real-time contribution of a wide range of experts at other spatial locations in times of emergency. The conceptual framework and detailed components of the proposed WFFS, which employs a multi-tiered architecture, are illustrated. Multi-tiered architecture offers great flexibility, portability, reusability and reliability. The prototype WFFS has been developed in Java programming language and applied in Shuangpai region with a satisfactory result.  相似文献   
9.
Extended Graetz problem in microchannel is analyzed by using eigenfunction expansion to solve the energy equation. The hydrodynamically developed flow is assumed to enter the microchannel with uniform temperature or uniform heat flux boundary condition. The effects of velocity and temperature jump boundary condition on the microchannel wall, streamwise conduction and viscous dissipation are all included. From the temperature field obtained, the local Nusselt number distributions are shown as the dimensionless parameters (Peclet number, Knudsen number, Brinkman number) vary. The fully developed Nusselt number for each boundary condition is obtained also in terms of these parameters.  相似文献   
10.
The growth of Li1+xMn2O4 via detonation reaction was investigated with respect to the presence of an energetic precursor, such as the metallic nitrate and the degree of confinement of the explosive charge. The detonation products were characterized by scanning electron microscopy. Powder X-ray diffraction and transmission electron microscopy were used to characterize the products. Li1+xMn2O4 with 1-2 μm spherical morphology and more uniform secondary particles, but with smaller primary particles of diameters from 20 to 60 nm and a variety of morphologies were found. The oxides produced by this cheap method affirmed the validity of detonation synthesis of nano-size powders.  相似文献   
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