全文获取类型
收费全文 | 978篇 |
免费 | 149篇 |
国内免费 | 91篇 |
专业分类
电工技术 | 13篇 |
综合类 | 45篇 |
化学工业 | 186篇 |
金属工艺 | 18篇 |
机械仪表 | 56篇 |
建筑科学 | 28篇 |
矿业工程 | 8篇 |
能源动力 | 49篇 |
轻工业 | 171篇 |
水利工程 | 8篇 |
石油天然气 | 5篇 |
武器工业 | 2篇 |
无线电 | 117篇 |
一般工业技术 | 74篇 |
冶金工业 | 15篇 |
原子能技术 | 4篇 |
自动化技术 | 419篇 |
出版年
2024年 | 2篇 |
2023年 | 30篇 |
2022年 | 22篇 |
2021年 | 34篇 |
2020年 | 28篇 |
2019年 | 31篇 |
2018年 | 30篇 |
2017年 | 36篇 |
2016年 | 49篇 |
2015年 | 46篇 |
2014年 | 40篇 |
2013年 | 65篇 |
2012年 | 123篇 |
2011年 | 98篇 |
2010年 | 116篇 |
2009年 | 147篇 |
2008年 | 82篇 |
2007年 | 99篇 |
2006年 | 71篇 |
2005年 | 37篇 |
2004年 | 5篇 |
2003年 | 3篇 |
2002年 | 7篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 6篇 |
1997年 | 1篇 |
1994年 | 1篇 |
排序方式: 共有1218条查询结果,搜索用时 15 毫秒
1.
Yuguang Chao Peng Zhou Jianping Lai Weiyu Zhang Huawei Yang Shiyu Lu Hui Chen Kun Yin Menggang Li Lu Tao Changshuai Shang Meiping Tong Shaojun Guo 《Advanced functional materials》2021,31(24):2100923
Designing a semiconductor-based heterostructure photocatalyst for achieving the efficient separation of photogenerated electron-hole pairs is highly important for enhancing H2 releasing photocatalysis. Here, a new class of Ni1−xCoxSe2–C/ZnIn2S4 hierarchical nanocages with abundant and compact ZnIn2S4 nanosheets/Ni1−xCoxSe2 C nanosheets 2D/2D hetero–interfaces, is designed and synthesized. The constructed heterostructure photocatalyst exposes rich hetero-junctions, supplying the broad and short transfer paths for charge carriers. The close contacts of these two kinds of nanosheets induce a strong interaction between ZnIn2S4 and Ni1−xCoxSe2 C, improving the separation and transfer of photo-generated electron-hole pairs. As a consequence, the distinctive Ni1−xCoxSe2 C/ZnIn2S4 hierarchical nanocages without using additional noble-metal cocatalysts, display remarkable H2-relaesing photocatalytic activity with a rate of 5.10 mmol g−1 h−1 under visible light irradiation, which is 6.2 and 30 times higher than those of fresh ZnIn2S4 nanosheets and bare Ni1−xCoxSe2 C nanocages, respectively. Spectroscopic characterizations and theory calculations reveal that the strong interaction between ZnIn2S4 and Ni1−xCoxSe2 C 2D/2D hetero-interfaces can powerfully promote the separation of photo-generated charge carriers and the electrons transfer from ZnIn2S4 to Ni1−xCoxSe2 C. 相似文献
2.
Sun Yehan Su Qingtang Wang Huanying Wang Gang 《Multimedia Tools and Applications》2022,81(5):6091-6113
Multimedia Tools and Applications - With the rapid development of the Internet, the color digital image copyright protection is facing severe challenges. Simultaneously, the color digital images... 相似文献
3.
以从自然腐败的樱桃上分离的链格孢霉(Alternaria sp.)LD3.0086为指示菌,研究苯乳酸对链格孢霉的主要抑制作用靶位。应用分光光度法测定苯乳酸对链格孢霉的最小抑菌浓度,通过卡尔科弗卢尔荧光增白剂染液(calcofluor white,CFW)染色观察苯乳酸对菌丝顶端生长的破坏作用,利用扫描电子显微镜和透射电子显微镜观察链格孢霉的超微结构变化,通过测定苯乳酸作用前后链格孢霉上清液中N-乙酰葡萄糖胺质量浓度变化研究苯乳酸对菌丝细胞壁的破坏作用,应用荧光双染色法观察苯乳酸对链格孢霉菌丝细胞膜的损伤作用。结果表明,12.5 mmol/L的苯乳酸能有效抑制链格孢霉的生长;与对照组(无菌水处理)相比,苯乳酸处理后链格孢霉顶端生长细胞无明显形变,经12.5 mmol/L苯乳酸处理的链格孢霉上清液中N-乙酰葡萄糖胺质量浓度基本不变;苯乳酸处理24 h,链格孢霉菌丝细胞壁表面无明显损伤,细胞内结构发生明显变化;苯乳酸短时间(4 h)处理链格孢霉,菌丝细胞膜仍较为完整,加入苯乳酸较长时间(8 h)后细胞膜发生破裂。综合分析可知,苯乳酸对链格孢霉的主要作用靶位应不是菌丝体的细胞壁和细胞膜,而是在菌丝体内部,通过破坏菌丝内部细胞器结构或引起细胞内的生化反应,从而抑制链格孢霉的生长和繁殖,发挥抑菌活性。 相似文献
4.
《Ceramics International》2020,46(1):17-22
Au/SnO2 quantum dots (AuSQDs) were synthesized, and the effects of annealing on their structural and optical properties were examined. Significant changes were observed in the bandgap and surface plasmon resonance (SPR) of the AuSQDs after thermal treatment at different temperatures (400, 500, and 600 °C). The properties of the as-prepared and annealed samples were characterized via X-ray diffraction analysis, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy, and diffuse reflectance spectroscopy. Annealing reduced the bandgap from 3.03 to 2.33 eV and increased the crystallinity while maintaining an average crystallite size below 10 nm. XPS valence band (VB) profiles provided information regarding the VB edge potentials, which helped to determine the conduction band edge potentials. An enhancement in the SPR of the Au nanoparticles was observed for AuSQD-500, which had the smallest bandgap among the samples investigated. 相似文献
5.
Both silane and multiwall carbon nanotubes (CNTs) were grafted successfully onto carbon fibers (CFs) to enhance the interfacial strength of CFs reinforced methylphenylsilicone resin (MPSR) composites. The microstructure, interfacial properties, impact toughness and heat resistance of CFs before and after modification were investigated. Experimental results revealed that CNTs were grafted uniformly onto CFs using 3-aminopropyltriethoxysilane (APS) as the bridging agent. The wettability and surface energy of the obtained hybrid fiber (CF-APS-CNT) were increased obviously in comparison with those of the untreated-CF. The CF-APS-CNT composites showed simultaneously remarkable enhancement in interlaminar shear strength (ILSS) and impact toughness. Moreover, the interfacial reinforcing and toughening mechanisms were also discussed. In addition, Thermogravimetric analysis and thermal oxygen aging experiments indicated a remarkable improvement in the thermal stability and heat oxidation resistance of composites by the introduction of APS and CNTs. We believe the facile and effective method may provide a novel interface design strategy for developing multifunctional fibers. 相似文献
6.
Wu Wenqing Zhu Zhenfang Zhang Guangyuan Kang Shiyong Liu Peiyu 《Applied Intelligence》2021,51(7):4515-4524
Applied Intelligence - Multi-relation Question Answering is an important task of knowledge base over question answering (KBQA), multi-relation means that the question contains multiple relations... 相似文献
8.
As well-known disturbance rejection methods, active disturbance rejection control and disturbance observer-based control can effectively improve the control performances of complex systems in the presence of disturbances. However, the accurate rejection of multiple disturbances for control systems of practical engineering, for example, the attitude control system of flexible spacecraft, is still a bottleneck problem. In order to further improve the anti-disturbance capability and reduce the conservativeness, this paper proposes a novel enhanced anti-disturbance control law for the attitude control system of flexible spacecraft by combining active disturbance rejection control and disturbance observer-based control in a unified framework. More specifically, the disturbance from flexible vibration is described by an uncertain exogenous system based on the partially known information including elastic damping ratios and modal frequencies. The disturbance observer-based control is utilized to estimate and thereby reject this disturbance. On the other hand, the other disturbances such as external environmental disturbance and complex model nonlinearity are merged into a equivalent disturbance with bounded derivative, which is compensated by using the active disturbance rejection control law. Stability and robustness analysis are carried out for the disturbance observer and extended state observer. Finally, simulation results of low-earth-orbit flexible satellite are presented to verify the effectiveness of proposed methods. 相似文献
9.
The multi-index hashing (MIH) is the state-of-the-art method for indexing binary codes. However, it is based on the dataset codes uniform distribution assumption, and will lower efficiency in dealing with non-uniformly distributed codes. In this paper, we propose a data-oriented multi-index hashing method. We first compute the correlations between bits and learn adaptive projection vector for each binary substring. Then, instead of using substrings as direct indices into hash tables, we project them with corresponding projection vectors to generate new indices. With adaptive projection, the indices in each hash table are nearly uniformly distributed. Besides, we put forward an entropy based measurement to evaluate the distribution of data items in each hash table. Experiments conducted on reference large scale datasets show that compared to the MIH the time performance of our method can be 36.9%~87.4% better . 相似文献
10.
《International Journal of Hydrogen Energy》2021,46(73):36314-36322
Reasonable structural design is significant to enable the performance in advanced energy storage devices. Herein, a 3D honeycomb-like CoMn2O4 nanoarchitecture (CMO) on nitrogen-doped graphene (NG) coating Ni foam (denoted as Ni/NG/CMO) flexible battery-type electrode was prepared by a facile two-step hydrothermal strategy. The honeycomb-like CoMn2O4 arrays not only provide abundant active sites but can also be closely combined with the Ni foam/NG substrate, which enables high reversible capacity and good cycle stability during the long cycles. Benefiting from the compositional features and 3D honeycomb-like nanoarchitecture, the Ni/NG/CMO composite electrode displays improved electrochemical performance with remarkable specific capacity of 527.0C g−1 at a current density of 1 A g−1, outstanding rate capability (338.6C g−1 even at 20 A g−1). In addition, a flexible binder-free supercapattery device has been assembled with Ni/NG/CMO as positive electrode and 3D Ni/NG as negative electrode. Such a supercapattery delivers a high energy density of 44.1 Wh·kg−1 at 992.6 W kg−1, 20.3 Wh·kg−1 at 12430.0 W kg−1 as well as excellent cycling durability. The 3D honeycomb-like Ni/NG/CMO could be considered as an advanced flexible battery-type material for high capacity and energy density fields. 相似文献