Structure and phase-composition of Ti-doped gas atomized Raney-type Ni catalyst precursor alloys

Raney-type Ni precursor alloys containing 75 at.% Al and doped with 0, 0.75, 1.5 and 3.0 at.% Ti have been produced by a gas atomization process. The resulting powders have been classified by size fraction with subsequent investigation by powder XRD, SEM and EDX analysis. The undoped powders contain, as expected, the phases Ni₂Al₃, NiAl₃ and an Al-eutectic. The Ti-doped powders contain an additional phase with the TiAl₃ DO₂₂ crystal structure. However, quantitative analysis of the XRD results indicate a far greater fraction of the TiAl₃ phase is present than could be accounted for by a simple mass balance on Ti. This appears to be a (Ti_xNi_1−x)Al₃ phase in which higher cooling rates favour small x (low Ti-site occupancy by Ti atoms). SEM and EDX analysis reveal that virtually all the available Ti is contained within the TiAl₃ phase, with negligible Ti dissolved in either the Ni₂Al₃ or NiAl₃ phases.     

Electromagnetism-like algorithms for optimized tool path planning in 5-axis flank machining

Optimization of tool path planning using metaheuristic algorithms such as ant colony systems (ACS) and particle swarm optimization (PSO) provides a feasible approach to reduce geometrical machining errors in 5-axis flank machining of ruled surfaces. The optimal solutions of these algorithms exhibit an unsatisfactory quality in a high-dimensional search space. In this study, various algorithms derived from the electromagnetism-like mechanism (EM) were applied. The test results of representative surfaces showed that all EM-based methods yield more effective optimal solutions than does PSO, despite a longer search time. A new EM-MSS (electromagnetism-like mechanism with move solution screening) algorithm produces the most favorable results by ensuring the continuous improvement of new searches. Incorporating an SPSA (simultaneous perturbation stochastic approximation) technique further improves the search results with effective initial solutions. This work enhances the practical values of tool path planning by providing a satisfactory machining quality.     

Linear friction welding of Ti6Al4V: experiments and modelling

Linear friction welding of the Ti6Al4V alloy is studied. A new definition of the energy input rate is proposed, based on an integration over time of the in-plane force and velocity; a strong correlation with the upset rate is then found. The effective friction coefficient is estimated to be 0·5±0·1 for varying frequencies and amplitudes, with only a weak dependence on the processing conditions displayed. A model is proposed that accounts for both the conditioning and equilibrium stages of the process, which is shown to be in good agreement with the experimental data. The model is used to study the mechanism by which the flash is formed. A criterion is proposed by which the rippled nature of its morphology can be predicted.     

Robot learning through task identification

The operation of an autonomous mobile robot in a semi-structured environment is a complex, usually non-linear and partly unpredictable process. Lacking a theory of robot–environment interaction that allows the design of robot control code based on theoretical analysis, roboticists still have to resort to trial-and-error methods in mobile robotics.The RobotMODIC project aims to develop a theoretical understanding of a robot’s interaction with its environment, and uses system identification techniques to identify the system robot–task–environment. In this paper, we present two practical examples of the RobotMODIC process: mobile robot self-localisation and mobile robot training to achieve door traversal.In both examples, a transparent mathematical function is obtained that maps inputs–sensory perception in both cases–to output — location and steering velocity respectively. Analysis of the obtained models reveals further information about the way in which a task is achieved, the relevance of individual sensors, possible ways of obtaining more parsimonious models, etc.     

Finite element analysis of the effects of radial expansion of corroded reinforcement

A finite element (FE) model of the effects of corroding reinforcement on the surrounding concrete was validated against the results of simulated corrosion tests in which internal pressure was applied to holes cast in concrete. The model was then used to explore the effects of bar radial expansion, due to the formation of corrosion products, on the cracking of cover concrete. The predictions were compared with test results from reinforced concrete accelerated corrosion specimens. The aim of the analytical investigation was to reveal the mechanism for the development of concrete cracking due to the corrosion of reinforcement. The three-dimensional physical specimens were idealised as two-dimensional analytical models under a plane strain assumption. Corrosion of reinforcement was modelled as either an internal pressure or a radial expansion to analyse the results of simulated and accelerated corrosion specimens, respectively. The FE analytical results indicate that the radial expansion of corroded reinforcement causes concrete cover to crack in four different stages: internal cracking, external cracking, penetration cracking and ultimate-cracking. It was also found that the FE analytical results could be used to explain qualitatively the experimentally determined relationship between amount of corrosion for concrete cracking and ratio of concrete cover to bar diameter, as well as that between reinforcement bond strength and amount of corrosion.     

Construction and performance of a multiparameter focal plane detector for use on a QMG/2 magnetic spectrometer

The design, construction and performance of a modular, two pressure focal plane detector, 550 mm long, 1000 mm deep and with an active height of 60 mm are described. The detector has been operated with ions ranging from 50 MeV ¹H to 200 MeV ³⁶S. Typical results achieved are 0.5 mm and 0.3° for the spatial and angular resolutions, and 0.7% and 3% for the total energy and energy loss measurements. A height signal is also provided.