The draft Long-Term 2 Enhanced Surface Water Treatment Rule (LT2ESWTR) contains Cryptosporidium log-inactivation CT tables (ozone-in-water concentration [residual], “C” times contact time, T). Depending on water temperature, Cryptosporidium CT values that are listed are 15 to 25 times greater than CT values for equivalent Giardia log-inactivation credit. The elevated operating dose required for Cryptosporidium log-inactivation credit has the potential to increase disinfection by-product (DBP) formation (e.g., bromate). Calculating CT value accurately will minimize ozone dose, which will decrease operating cost and lower DBP formation, and at the same time maintain disinfection protection through implementation of scientifically based safety factors. Various methods are available for calculating CT value. The method chosen depends largely on the available information concerning ozone residual characteristics and hydrodynamic features of the ozone contactor, plus local regulatory requirements. Four methods are discussed in this paper. Each method can be used to calculate Giardia, virus, and Cryptosporidium log-inactivation credit. 相似文献
Testing kinetic models against a “true” and detailed kinetic expression was the aim of the Workshop on Kinetic Model Development at the Denver AIChE Meeting in August, 1983. For this purpose an artificial reaction mechanism was created, based on the known thermodynamics of the methanol synthesis as a framework. The kinetic rate laws, that were derived from this mechanism, were made thermodynamically consistent by achieving agreement between equilibrium constants calculated at various temperatures from the given, real original thermodynamic relationship and those calculated from the detailed reversible kinetic expressions.
Using the artificial kinetics as the "true" one, CSTR experiments were simulated. The results of a statistically designed set of experiments were published after 5% random error was added to the data. Participation was invited for all interested to correlate the data, develop kinetic models and to calculate the performance of the specified reactor.
The results of 19 submitted entries are summarized with the conclusion that the models had more differences than were expected, but their predictive values were not as different as was anticipated, if the extreme high production rates due to thermal runaways are not considered. This in turn points out the necessity to check models experimentally, in pilot plant, not only for predicted optimum, but also for calculated runaway conditions. Models which did not capture the true character of this reaction failed to predict the onset of runaway reactions. 相似文献
This brief paper demonstrates the concept of linear feedback equivalence for an exothermic eontinu-ous stirred tank reactor with first order kinetics. Feedback control is achieved by finding a transformation for the nonlinear system which carries this system into a linear controllable system in Brunovsky canonical form. A linear state feedback controller is then designed which achieves control over a broad range of operating conditions. This example demonstrates how recent developments in nonlinear control theory can be applied to chemical systems without relying on the usual methods of local linearization. 相似文献
In this paper, the control problem of continuous stirred tank reactors (CSTR) is studied. The considered CSTR are required to contain unknown functions and unknown dead zone input. An adaptive controller that uses the neural networks (NNs) is provided to solve the unknown terms. The proposed approach overcomes the effect of the dead zone input. The dead zone input in the systems is compensated for by introducing a new Lyapunov form and Young's inequality. The backstepping procedure is exploited to implement controller design with adaptation laws. The stability is analyzed using Lyapunov method. The performance is examined for CSTR to confirm the effectiveness of the proposed approach based on computer simulation. 相似文献
Model predictive control (MPC) schemes are now widely used in process industries for the control of key unit operations. Linear model predictive control (LMPC) schemes which make use of linear dynamic model for prediction, limit their applicability to a narrow range of operation (or) to systems which exhibit mildly nonlinear dynamics.
In this paper, a nonlinear observer based model predictive controller (NMPC) for nonlinear system has been proposed. An approach to design NMPC based on fuzzy Kalman filter (FKF) and augmented state fuzzy Kalman filter (ASFKF) has been presented. The efficacy of the proposed NMPC schemes have been demonstrated by conducting simulation studies on the continuous stirred tank reactor (CSTR). The analysis of the extensive dynamic simulation studies revealed that, the NMPC schemes formulated produces satisfactory performance for both servo and regulatory problems. Simulation results also include an inferential control case, where the reactor concentration is not measured but estimated from temperature measurement and used in the NMPC based on FKF and ASFKF formulations. 相似文献