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1.
In this work, we designed a magnetically-separable Fe3O4-rGO-ZnO ternary catalyst, ZnO anchored on the surface of reduced graphene oxide (rGO)-wrapped Fe3O4 magnetic nanoparticles, where rGO, as an effective interlayer, can enhance the synergistic effect between ZnO and Fe3O4. The effects of three operational parameters, namely irradiation time, hydrogen peroxide dosage, and the catalyst dosage, on the photo-Fenton degradation of methylene blue and methyl orange were investigated. The results showed that the Fe3O4-rGO-ZnO had great potential for the destruction of organic compounds from wastewater using the Fenton chemical oxidation method at neutral pH. Repeatability of the photocatalytic activity after 5 cycles showed only a tiny drop in the catalytic efficiency.  相似文献   
2.
The heterogeneous catalysis of transesterification of gmelina seed oil to biodiesel is evaluated. The oil was extracted from the seeds with n‐hexane by solvent extraction and characterized to determine its physiochemical properties. Response surface methodology was applied to optimize the effect of process variables on the biodiesel yield. The base‐activated clay catalyst performed as montmorillonite clay with the characteristic property of a Brønsted acid. It has an improved surface area after activation that enhanced its catalytic activity on transesterification reaction. Under optimal conditions, the biodiesel yield was 70.1 %, thus demonstrating that the model predicted well the biodiesel production.  相似文献   
3.
反应堆堆芯先进中子学模拟软件SCAP-N研发   总被引:2,自引:1,他引:1       下载免费PDF全文
堆芯中子学计算是反应堆设计分析的基础,为提高堆芯中子学计算的模拟分辨率与计算精度,开发了反应堆堆芯先进中子学模拟软件(SCAP-N)。该程序首先根据轴向特征对堆芯进行分层,并逐层进行二维堆芯非均匀输运计算,再采用超级均匀化方法(SPH)获得栅元等效均匀化截面,最后进行三维堆芯逐棒(pin-by-pin)输运计算,获得堆芯有效增殖因子与精细棒功率分布。为提高程序计算效率,采用分布式/共享式(MPI/OPENMP)混合并行方式对程序进行了并行化开发。利用虚拟反应堆(VERA)系列基准例题及美国先进非能动压水堆(AP1000)启动物理试验实测数据对程序进行了测试验证。结果表明,相比于商用核设计程序系统,SCAP-N程序采用的逐棒输运技术能够提高堆芯中子学的计算精度。与同类型高精度中子学程序相比,SCAP-N具有更高的计算效率,可进一步提高核电厂的经济性及运行灵活性。   相似文献   
4.
A novel CdS/CaFe2O4 (CS/CFO) heterogeneous p-n junction was created by thermal deposition of CaFe2O4 nanoparticles on CdS rods. The CS/CFO hetero-structured photocatalysts exhibited increasingly efficient visible light harvesting compared to the bare CdS. The CS/CFO composites also presented higher photocurrent and slower decay of photoluminescence, suggesting a better separation of the photo-generated electrons and holes. The photocatalytic H2 evolution quantity on the optimized CS/CFO composite from water in the presence of ethanol was up to 2200 μmol after 3-h visible light illumination, which is more than twice that of the pristine CdS. The chemical interaction between CdS and CaFe2O4 was confirmed by the shifts in the XPS peaks, which made it possible for the charge carriers to transfer across the p-n junction interface. This research highlights the importance of forming an interfacial p-n heterojunction between two semiconductors for efficient charge separation and improved photocatalytic performance.  相似文献   
5.
A carbon-containing CoCrFeNi high entropy alloy (HEA) with heterogeneous structures was obtained through thermome-chanical treatments,which induced concurrent recrystallization and carbide precipitation in the alloy.A combination of high yield strength (556 MPa) and large uniform elongation (45%) was achieved in the investigated alloy.The enhancement of the strength is attributed to the combined effects of grain refinement,precipitation strengthening and microstructural het-erogeneity.Our work demonstrated that the heterogeneity design could be realized by thermomechanical processes,which provided a practical strategy for producing HEAs with high performance.  相似文献   
6.
Formic acid (HCOOH, FA), a common liquid hydrogen storage material, has attracted tremendous research interest. However, the development of efficient, low-cost and high-stable heterogeneous catalyst for selective dehydrogenation of FA remains a major challenge. In this paper, a simple co-reduction method is proposed to synthesize nitrogen-phosphorus co-functionalized rGO (NPG) supported ultrafine NiCoPd-CeOx nanoparticles (NPs) with a mean size of 1.2 nm. Remarkably, the as-prepared Ni0.2Co0.2Pd0.6-CeOx/NPG shows outstanding catalytic activity for FA dehydrogenation, affording a high TOF value of 6506.8 mol H2 mol Pd?1 h?1 at 303 K and a low activation energy of 17.7 kJ mol?1, which is better than most of the reported heterogeneous catalysts, and can be ascribed to the combined effect of well-dispersed ultrafine NiCoPd-CeOx NPs, modified Pd electronic structure, and abundant active sites. The reaction mechanism of dehydrogenation of FA is also discussed. Furthermore, the optimized Ni0.2Co0.2Pd0.6-CeOx/NPG shows excellent stability over 10th run with 100% conversion and 100% H2 selectivity, which may provide more possibilities for practical application of FA system on fuel cells.  相似文献   
7.
Suzuki-Miyaura (S-M) is regarded the most powerful way for synthesis biaryls, triaryls, or incorporating of substituted aryl moieties in organic preparation by the cross-coupling of aryl boronic acid with aryl halides using the Pd catalyst. This work reports the combining of the hydrothermal and microwave-assisted protocol to convert the glucose to magnetic carbon spheres (Fe3O4-CSPs) decorated with Pd nanoparticles (NPs) as the catalyst for Suzuki-Miyaura cross-coupling reactions. The physicochemical properties in the produced composite were examined using FESEM, HRTEM, nitrogen isotherms, Raman spectroscopy, FTIR, XPS, and XRD. The as-fabricated composite Pd/Fe3O4-CSPs is mostly spherical with a core–shell structure and possesses a great surface area of 253.2 m2·g-1. Its catalytic performance demonstrates that the composite has excellent stability and high tolerance Suzuki-Miyaura cross-coupling reactions in 30 min at 80 ℃. Both activated and deactivated aryl halides provided excellent yield. The as-fabricated catalyst was recycled for up to four catalytic cycles without a substantial decline in performance. Moreover, this research offers a facile roadmap for synthesizing Pd/Fe3O4-CSPs composites and promoting the practical implementation of Pd/Fe3O4-CSPs catalysts for organic transformation processes.  相似文献   
8.
In this study the constructional modification of Graphitic carbon nitride nanosheet (GCN-ns) has been made with the aid of ZnCr layered double hydroxide (ZC-LDH) in a unique 2D-2D structure to enhance its visible light absorption. Optical and morphological study presents successful incorporation of ZC-LDH on the surface of GCN-ns. Through adjusting of GCN-ns by ZC-LDH lower recombination rate of e?/h+ pairs, longer lifetimes and an increase in contamination reduction was brought out. The binary nanocomposite was employed to effectively degrade Rhodamine B under UV/vis light irradiation. The improvement in photocatalytic abilities was proven to be related to in situ self-production of H2O2 on GCN-ns/ZC-LDH surface by Xe light irradiation which in return accounts for additional hydroxide radical generation. Radical quenching experiments specified the main active species involved while the consequent step-scheme (S-scheme) charge transfer mechanism was proposed.  相似文献   
9.
The precise control of active pharmaceutical ingredient (API) crystal nucleation and polymorphism is a key consideration in pharmaceutical manufacturing. In this study, tunable nanoparticles were developed to regulate the nucleation process of coumarin. Magnetic silica nanoparticles with four different functional groups (—NH2, —COOH, —SH, —NCO) were prepared and coated on the substrate for inducing the crystallization of coumarin. Confined melt crystallization and microspacing sublimation crystallization methods were used to investigate the regulation mechanism. The results indicated that three metastable forms of coumarin can be obtained as pure components based on the combined influence of crystallization methods and functionalized nanoparticles. Form II could be selectively obtained by microspacing sublimation crystallization on Fe3O4@SiO2—SH substrates, and Form IV could be obtained by confined melt crystallization on Fe3O4@SiO2—NCO substrates. Form III could be obtained by further heating Form IV crystals to 52 ℃ on Fe3O4@SiO2—NCO substrates. Moreover, the polarized light microscopy results also indicated that the introduction of nanoparticles could also increase the stability of the metastable crystalline forms of coumarin. Finally, the diffusion and surface dynamics during nanoparticle induced crystallization were comparatively investigated and the corresponding polymorphic selectivity mechanism was proposed.  相似文献   
10.
为解决当前激光选区熔化成型过程难以按需在零件任意位置自由布置不同材料的难题,基于多漏斗供粉+柔性清扫回收粉末原理,对异质材料零件激光选区熔化增材制造技术展开了研究,详细探讨了成型机理、粉尘污染防范机制及异质材料数据处理方法。采用CuSn10、4340两种不同的合金材料进了工艺实验验证。实验表明该方法可以较有效解决激光选区熔化成型过程异质材料布置难题,实现异质材料零件成型:(1)能自由地在不同层间或同层内不同区域按需布置不同的材料;(2)所得块状异质材料零件的铜合金材料区域Fe元素平均质量百分含量可控制在2%以下,钢材料区域Cu元素平均质量百分含量可控制在1%以下;(3)成功成型了一个具有复杂外形及微细材料区域特征的异质材料齿轮零件,零件异质材料区域不受零件复杂外形限制,可自由按需布置材料,0.5mm宽的层内异质材料区域也能被较好地表达出来,尺寸误差不超过±0.1mm。  相似文献   
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